Kinetics and mechanism of phosphorylation of monoethanolamine in reversed micelles of a cationic surfactant

1998 ◽  
Vol 47 (2) ◽  
pp. 273-276 ◽  
Author(s):  
E. P. Tishkova ◽  
L. A. Kudryavtseva
Keyword(s):  
Cationic Surfactant ◽  
Reversed Micelles ◽  
Kinetics And Mechanism

Kinetics and Mechanism of 2,2′-bipyridine Catalysed Chromium(VI) Oxidation of Dimethyl Sulfoxide in the Presence and Absence of Surfactants†

2005 ◽  
Vol 2005 (7) ◽  
pp. 471-474 ◽  
Author(s):  
Bidyut Saha ◽  
Monirul Islam ◽  
Asim K. Das
Keyword(s):  
Dimethyl Sulfoxide ◽  
Cationic Surfactant ◽  
Anionic Surfactant ◽  
Oxygen Transfer ◽  
Kinetics And Mechanism ◽  
Nucleophilic Attack ◽  
Reactive Intermediate ◽  
Chromium Vi ◽  
Equilibrium Step ◽  
Positively Charged

In the 2,2′-bipyridine (bipy) catalysed CrVI oxidation of dimethyl sulfoxide (DMSO) to dimethyl sulfone, the CrVI–bipy complex formed at the pre - equilibrium step undergoes a nucleophilic attack by the S or O of DMSO to form a positively charged reactive intermediate. This intermediate experiences an oxygen transfer or a ligand coupling to give the products. The anionic surfactant (SDS) accelerates the process while the cationic surfactant (CPC) retards the reaction.

Kinetics and mechanism for oxime formation from 2-quinolinecarboxaldehyde

10.1002/kin.7 ◽  
1996 ◽  
Vol 28 (9) ◽  
pp. 687-691 ◽  
Author(s):  
M. Calzadilla ◽  
A. Malpica ◽  
P. M. Diaz
Keyword(s):  
Kinetics And Mechanism ◽  
Oxime Formation

Kinetics and mechanism of the reduction of selenium (IV) by iron (II) in presence of sodium fluoride

1973 ◽  
Vol 70 ◽  
pp. 918-922 ◽  
Author(s):  
R. K. Srivastava ◽  
V. K. Srivastava ◽  
M. N. Srivastava ◽  
B. B. L. Saxena
Keyword(s):  
Sodium Fluoride ◽  
Kinetics And Mechanism

Kinetics and mechanism of photoinduced orientation of bisazodioksodibenzothiophene in thin films

2016 ◽  
Vol 2 (4) ◽  
pp. 39-45 ◽  
Author(s):  
J.D Chaplanova ◽  
S.N. Larykava ◽  
V.E Agabekov ◽  
I.N. Kukhta
Keyword(s):  
Thin Films ◽  
Kinetics And Mechanism

Kinetics and Mechanism of Oxidation of Labetalol by Hexacyanoferrate(III) in Alkaline Medium

2012 ◽  
Vol 3 (2) ◽  
pp. 131-133
Author(s):  
ANNAPURNA NOWDURI ◽  
◽  
Apparao Babu Duggada ◽  
Vijaya Raju Kurimella
Keyword(s):  
Alkaline Medium ◽  
Kinetics And Mechanism ◽  
Mechanism Of Oxidation
Sign in / Sign up

Export Citation Format

Share Document