Determination of enthalpies of formation of organic free radicals from bond dissociation energies

1999 ◽  
Vol 48 (2) ◽  
pp. 285-287 ◽  
Author(s):  
Yu. D. Orlov ◽  
Yu. A. Lebedev
Keyword(s):  
Free Radicals ◽  
Enthalpies Of Formation ◽  
Bond Dissociation Energies ◽  
Bond Dissociation ◽  
Dissociation Energies

Experimental methods for measurement of bond dissociation energies and heats of formation of radicals

1951 ◽  
Vol 207 (1088) ◽  
pp. 5-13 ◽  
Keyword(s):  
Experimental Methods ◽  
Experimental Results ◽  
Heats Of Formation ◽  
Bond Dissociation Energies ◽  
Carrier Gas ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Kinetics Of

The paper describes a pyrolytic method of investigating the kinetics of gaseous reactions in which toluene is used as a carrier gas. It is shown that the method is particularly suitable for the determination of bond dissociation energies. The scope of the method is illustrated by various examples. A list of bond dissociation energies obtained is given. The manner in which the experimental results obtained can be cross-checked, is indicated and illustrated by examples. The effects of various constitutional factors on the bond dissociation energies are discussed.

Sign in / Sign up

Export Citation Format

Share Document