Structure of a turbulent bore in a homogeneous liquid

1999 ◽  
Vol 40 (2) ◽  
pp. 238-248 ◽  
Author(s):  
V. Yu. Liapidevskii
Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2277
Author(s):  
Piotr M. Kuś ◽  
Igor Jerković

Recently, we proposed a new sample preparation method involving reduced solvent and sample usage, based on dehydration homogeneous liquid–liquid extraction (DHLLE) for the screening of volatiles and semi-volatiles from honey. In the present research, the method was applied to a wide range of honeys (21 different representative unifloral samples) to determine its suitability for detecting characteristic honey compounds from different chemical classes. GC-FID/MS disclosed 130 compounds from different structural and chemical groups. The DHLLE method allowed the extraction and identification of a wide range of previously reported specific and nonspecific marker compounds belonging to different chemical groups (including monoterpenes, norisoprenoids, benzene derivatives, or nitrogen compounds). For example, DHLLE allowed the detection of cornflower honey chemical markers: 3-oxo-retro-α-ionols, 3,4-dihydro-3-oxoedulan, phenyllactic acid; coffee honey markers: theobromine and caffeine; linden honey markers: 4-isopropenylcyclohexa-1,3-diene-1-carboxylic acid and 4-(2-hydroxy-2-propanyl)cyclohexa-1,3-diene-1-carboxylic acid, as well as furan derivatives from buckwheat honey. The obtained results were comparable with the previously reported data on markers of various honey varieties. Considering the application of much lower volumes of very common reagents, DHLLE may provide economical and ecological advantages as an alternative sample preparation method for routine purposes.


1845 ◽  
Vol 135 ◽  
pp. 147-153 ◽  

In reasoning on the peculiar coloured dispersion operated on a portion of a beam of white light intromitted into a solution of sulphate of quinine, it occurred to me as a subject well worthy of inquiry whether the rays so selected for dispersion and thus singularly separated from the rest, were distinguished by any other peculiarity; whether in effect an analysis of the incident light into two distinct species qualitatively different had been performed, or merely a simple subdivision , such as takes place, for instance, in partial reflexion, as in the phenomena of the colours of thin plates. Another interesting subject of inquiry presents itself in the laws which regulate this singular mode of dispersion itself, which, for brevity, I shall venture to call (at least provisionally) epipölic ,from ϵπ'πo⋋ἠ , a surface, the seat of the dispersion being at or very near the intromitting surface. As regards the question of analysis, two modes of examination present themselves, viz. either,—1, by subjecting the dispersed portion of the light to experiment, or, 2, the residual portion, which, having escaped dispersion, preserves the unity of its direction; and on that account, as well as by reason of its vastly superior intensity, offers itself more readily to experimental inquiry.


2009 ◽  
Vol 6 (4) ◽  
pp. 1077-1084 ◽  
Author(s):  
Mohammad Reza Jamali ◽  
Yaghoub Assadi ◽  
Reyhaneh Rahnama Kozani ◽  
Farzaneh Shemirani

A simple and effective homogeneous liquid-liquid extraction method for selective separation, preconcentration and spectrophotometric determination of palladium(II) ion was developed by using a ternary component system (water / tetrabutylammonium ion (TBA+) / chloroform). The phase separation phenomenon occurred by an ion–pair formation of TBA+and perchlorate ion. Thio-Michler’s ketone (TMK), 4, 4ˊ-bis (dimethylamino) thiobenzophenone, was used as a complexing agent. After optimization of complexation and extraction conditions ([TMK]=5.0x10-2mol L-1, [TBA+] = 2.0×10-2mol L-1, [CHCl3] = 60.0 µL, [ClO4-] = 2.5×10-2mol L-1and pH= 3.0), a preconcentration factor 10 was obtained for 10 mL of sample. The analytical curve was linear in the range of 2-100 ng mL-1and the limit of detection was 0.4 ng mL-1. The relative standard deviation was 3.2% (n=10). Accuracy and application of the method was estimated by using test samples of natural and synthetic water spiked with different amounts of palladium(II) ion. The method is very simple and inexpensive.


2018 ◽  
Vol 40 (5) ◽  
pp. 291-296
Author(s):  
Bahareh Moavenian ◽  
Majid Haji Hosseini ◽  
Masoud Arabieh ◽  
Mohammad Reza Pourjavid ◽  
Mahmoud Reza Sohrabi

The author observed that a solution of sulphate of quinine in tartaric acid, largely diluted, although perfectly transparent and colourless when held between the eye and the light, or a white object, yet exhibits in certain aspects, and under certain incidences of the light, an extremely vivid and beautiful celestial blue colour, apparently resulting from the action of the strata which the light first penetrates on entering the liquid ; and which, if not strictly superficial, at least exert their peculiar power of analysing the incident rays, and dispersing those producing the observed tint, only through a very small depth within the medium. The thinnest film of the liquid seems quite as effective in producing this superficial colour as a considerable thickness.


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