Separation of inorganic anions and cations on titania by use of acetic acid-sodium acetate and bicine-sodium hydroxide buffers

1998 ◽  
Vol 47 (11-12) ◽  
pp. 655-658 ◽  
Author(s):  
K. Tani ◽  
H. Kubojima
Keyword(s):  
Acetic Acid ◽  
Sodium Hydroxide ◽  
Sodium Acetate ◽  
Inorganic Anions ◽  
Anions And Cations

scholarly journals Treating kraft mill extract using bipolar membrane electrodialysis for the production of acetic acid

TAPPI Journal ◽  
2016 ◽  
Vol 15 (3) ◽  
pp. 215-226 ◽  
Author(s):  
RAVIKAT PATIL ◽  
JOSEPH GENCO ◽  
HEMANT PENDSE ◽  
ADRIAAN VAN HEININGEN
Keyword(s):  
Acetic Acid ◽  
Energy Consumption ◽  
Sodium Hydroxide ◽  
Current Density ◽  
Salt Solution ◽  
Sodium Acetate ◽  
Process Conditions ◽  
Sodium Acetate Solution ◽  
Bipolar Membrane ◽  
Bipolar Membrane Electrodialysis

The objective of this work was to determine the process conditions for converting sodium acetate, the major component of alkaline hardwood extract, into acetic acid and sodium hydroxide using bipolar membrane electrodialysis (BPMED). The effects of current density and sodium acetate concentration in the feed-salt solution were evaluated using synthetic sodium acetate solution in a feed and bleed mode. This mode of operation represents semibatch processing and was useful for determining the current efficiencies, energy consumption, and other system parameters for the production of about 160 g/L of acetic acid; maximum achievable concentration of acetic acid in electrodialysis; and 30 g/L of sodium hydroxide, which is the concentration sufficient for the extraction of sodium acetate from hardwood. The feed and bleed mode experiments performed at 60 mA/cm2 using 130 and 85 g/L sodium acetate as feed-salt solutions produced similar results, except for a small change in the amount of water transported into the acid and base compartments. The feed and bleed mode experiment performed at low current density of 40 mA/cm2 using 50 g/L sodium acetate as feed-salt solution produced almost similar quantities of acetic acid and sodium hydroxide as those in the other feed and bleed mode experiments. However, the energy consumption and current efficiencies were lower than those for the experiments performed at the current density of 60 mA/cm2.

Studies on bipolar membranes. Part II — Conversion of sodium acetate to acetic acid and sodium hydroxide

1997 ◽  
Vol 32 (2) ◽  
pp. 209-215 ◽  
Author(s):  
G.S. Trivedi ◽  
B.G. Shah ◽  
S.K. Adhikary ◽  
V.K. Indusekhar ◽  
R. Rangarajan
Keyword(s):  
Acetic Acid ◽  
Sodium Hydroxide ◽  
Sodium Acetate ◽  
Bipolar Membranes

scholarly journals Reactions of 4-hydroxycoumarin with heterocyclic aldehydes

2021 ◽  
Vol 9 (3) ◽  
Author(s):  
Renáta Gašparová ◽  
Katarína Kotlebová ◽  
Margita Lácová
Keyword(s):  
Acetic Acid ◽  
Acetic Anhydride ◽  
Microwave Irradiation ◽  
Sodium Hydroxide ◽  
Acid Medium ◽  
Sodium Acetate ◽  
Toluenesulfonic Acid ◽  
Heterocyclic Aldehydes

Reactions of 4-hydroxycoumarin 1 with heterocyclic aldehydes 2-4 led to bis-4-hydroxycoumarin derivatives 5-7 under microwave irradiation as well as under the classical heating. The subsequent reactions of products 5-7 are described. 4,4’-Epoxydicoumarins 8, 9 were prepared by the reaction of 5-7 in acetic acid / p-toluenesulfonic acid medium. Compound 10 was prepared by the reaction of 5 in acetic anhydride in the presence sodium acetate. Dioxocine-1,15-dione 11 was prepared by the reaction of 6 with dichloromethane in sodium hydroxide-toluene.

Synthesis and Caracterization of some New 1H-3-aryl-7-etoxycarbonyl-6-methyl-pyrazolo[5,1-c][1,2,4]triazoles

2008 ◽  
Vol 59 (1) ◽  
pp. 41-44
Author(s):  
Maria-Daniela Sofei ◽  
Maria Ilici ◽  
Valentin Badea ◽  
Carol Csunderlik ◽  
Vasile-Nicolae Bercean
Keyword(s):  
Mass Spectrometry ◽  
Acetic Acid ◽  
Nmr Spectroscopy ◽  
Sodium Acetate ◽  
Glacial Acetic Acid ◽  
Ir And Nmr Spectroscopy

The synthesis of 1H-3-aryl-7-ethoxycarbonyl-6-methyl-pyrazolo[5,1-c][1,2,4]triazoles (2) was carried out by cyclization of 1H-5-arylidenehydrazino-4-ethoxycarbonyl-3-methyl-pyrazoles (1) in the presence of bromine using glacial acetic acid as solvent and sodium acetate as base. The new nine obtained compounds were characterized by IR and NMR spectroscopy and mass spectrometry.

Novel Synthesis of 4-Benzylidene-2-((1-phenyl-3,4-dihydroisoquinoline-2(1H)-yl)methyl) oxazol-5(4H)-one Derivatives Using 1,2,3,Tetrahydroisoquinoline and their Antimicrobial Activity

2020 ◽  
Vol 17 (5) ◽  
pp. 396-403
Author(s):  
Nalla Krishna Rao ◽  
Tentu Nageswara Rao ◽  
Botsa Parvatamma ◽  
Y. Prashanthi ◽  
Ravi Kumar Cheedarala
Keyword(s):  
Antimicrobial Activity ◽  
Antibacterial Activity ◽  
Acetic Acid ◽  
Sodium Acetate ◽  
Good Activity ◽  
Activity Profile ◽  
Aryl Aldehydes ◽  
Chemical Structures ◽  
Novel Synthesis ◽  
Target Molecules

Aims: A series of six 4-benzylidene-2-((1-phenyl-3,4-dihydro isoquinoline-2(1H)-yl)methyloxazol- 5(4H)-one derivatives were synthesized by condensation of substituted aryl aldehydes with 2-(2-(1-phenyl-3,4- dihydro isoquinoline-2(1H)-acetamido)acetic acid in the presence of sodium acetate, acetic anhydride and zinc oxide as catalysts. Background: Novel Synthesis of 4-Benzylidene-2-((1-phenyl-3,4-dihy droisoquinoline-2(1H)-yl)methyl)oxazol- 5(4H)-one derivatives using 1,2,3,Tetrahydroisoquinoline and their antimicrobial activity. Objective: The title compounds can be synthesized from 1,2,3,4-tetrahydroisoquinoline. Methods: The target molecules, i.e., 4-benzylidene-2-((1-phenyl-3, 4-dihydro isoquinoline-2(1H)-yl) methyl) oxazol-5(4H)-one derivatives (8a-8f) have been synthesized from 1,2,3,4-tetrahydroisoquinoline which was prepared from benzoic acid in few steps. Results: All the six compounds were evaluated based on advanced spectral data (1H NMR, 13C NMR & LCMS), and the chemical structures of all compounds were determined by elemental analysis. Conclusion: Antibacterial activity of the derivatives was examined for the synthesized compounds and results indicate that compound with bromine substitution has a good activity profile.

Modification of activated carbon using sodium acetate and its regeneration using sodium hydroxide for the adsorption of copper from aqueous solution

Carbon ◽  
2007 ◽  
Vol 45 (5) ◽  
pp. 1081-1084 ◽  
Author(s):  
Dan Mugisidi ◽  
Aria Ranaldo ◽  
Johny W. Soedarsono ◽  
Muhammad Hikam
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Sodium Hydroxide ◽  
Sodium Acetate

Production of monosaccharides from poplar by a two-step hydrogen peroxide-acetic acid and sodium hydroxide pretreatment

2021 ◽  
Vol 170 ◽  
pp. 113820
Author(s):  
Hong Liao ◽  
Jiaxin You ◽  
Peiyao Wen ◽  
Wenjun Ying ◽  
Qianqian Yang ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Acetic Acid ◽  
Sodium Hydroxide

scholarly journals Kinetics and Mechanism of the Change of the 4-Nitrobenzylthio-System into 4,4′-Diformylazoxybenzene in Alkaline Dioxane-Water Media

1985 ◽  
Vol 40 (11) ◽  
pp. 1128-1132
Author(s):  
Y. Riad ◽  
Adel N. Asaad ◽  
G.-A. S. Gohar ◽  
A. A. Abdallah
Keyword(s):  
Acetic Acid ◽  
Sodium Hydroxide ◽  
Rate Constants ◽  
Main Product ◽  
Reaction Medium ◽  
Aqueous Dioxane ◽  
Proton Abstraction ◽  
First Order ◽  
Water Media ◽  
Different Temperatures

Sodium hydroxide reacts with α -(4-nitrobenzylthio)-acetic acid in aqueous-dioxane media to give 4,4'-diformylazoxybenzene as the main product besides 4,4'-dicarboxyazoxybenzene and a nitrone acid. This reaction was kinetically studied in presence of excess of alkali in different dioxane-water media at different temperatures. It started by a fast reversible a-proton abstraction step followed by two consecutive irreversible first-order steps forming two intermediates (α -hydroxy, 4-nitrosobenzylthio)-acetic acid and 4-nitrosobenzaldehyde. The latter underwent a Cannizzaro's reaction, the products of which changed in the reaction medium into 4,4'-diformylazoxybenzene and 4,4'-dicarboxyazoxybenzene. The rate constants and the thermodynamic parameters of the two consecutive steps were calculated and discussed. A mechanism was put forward for the formation of the nitrone acid.Other six 4-nitrobenzyl, aryl sulphides were qualitatively studied and they gave mainly 4,4'-diformylazoxybenzene beside 4,4'-dicarboxyazoxybenzene or its corresponding azo acid.

EUROPIUM OXALATE ION ASSOCIATION IN WATER

1966 ◽  
Vol 44 (24) ◽  
pp. 3057-3062 ◽  
Author(s):  
P. G. Manning
Keyword(s):  
Acetic Acid ◽  
Ionic Strength ◽  
Stability Constant ◽  
Stability Constants ◽  
Aqueous Phase ◽  
Sodium Acetate ◽  
Ion Association ◽  
Sodium Oxalate ◽  
Aqueous Sodium ◽  
Oxalate Ion

The partitioning of radiotracer 152/151Eu between aqueous sodium oxalate (Na2L) solutions and toluene solutions of thenoyltrifluoroacetone (HTTA) has been studied as a function of the oxalate concentration. The pH of the aqueous phase was controlled by means of sodium acetate – acetic acid mixtures and the ionic strength (I) by NaCl or NaClO4.At low ionic strengths (~0.05) and [L] ~10−4 M EuL+ formed, but at I = 0.95 and [L] ~10−3 M EuL2− also formed. Stability constants for the 1:1 and 1:2 (metal:ligand) complexes are reported.The magnitudes of the stepwise stability constant ratios are discussed.

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