Temperature effects on selectivity using carbon dioxide-based mobile phases on silica-based packed columns near the mixture critical point

1997 ◽  
Vol 44 (9-10) ◽  
pp. 521-528 ◽  
Author(s):  
J. A. Blackwell ◽  
R. W. Stringham
Keyword(s):  
Carbon Dioxide ◽  
Critical Point ◽  
Temperature Effects ◽  
Packed Columns ◽  
Mobile Phases

The Critical Point Drying Method Applied to Scanning Electron Microscopy of L-929 Cells

1970 ◽  
Vol 28 ◽  
pp. 278-279
Author(s):  
Charles TurnbiLL ◽  
Delbert E. Philpott
Keyword(s):  
Electron Microscopy ◽  
Carbon Dioxide ◽  
Surface Tension ◽  
Critical Point ◽  
Freeze Drying ◽  
Attractive Alternative ◽  
Crystal Formation ◽  
Critical Point Drying ◽  
Time Required ◽  
Scanning Electron

The advent of the scanning electron microscope (SCEM) has renewed interest in preparing specimens by avoiding the forces of surface tension. The present method of freeze drying by Boyde and Barger (1969) and Small and Marszalek (1969) does prevent surface tension but ice crystal formation and time required for pumping out the specimen to dryness has discouraged us. We believe an attractive alternative to freeze drying is the critical point method originated by Anderson (1951; for electron microscopy. He avoided surface tension effects during drying by first exchanging the specimen water with alcohol, amy L acetate and then with carbon dioxide. He then selected a specific temperature (36.5°C) and pressure (72 Atm.) at which carbon dioxide would pass from the liquid to the gaseous phase without the effect of surface tension This combination of temperature and, pressure is known as the "critical point" of the Liquid.

The viscocity of carbon dioxide in the neighbourhood of the critical point

Physica ◽  
1964 ◽  
Vol 30 (1) ◽  
pp. 161-181 ◽  
Author(s):  
J. Kestin ◽  
J.H. Whitelaw ◽  
T.F. Zien
Keyword(s):  
Carbon Dioxide ◽  
Critical Point

Numerical Simulation of the Performance of an Axial Compressor Operating With Supercritical Carbon Dioxide

2018 ◽  
Author(s):  
Jinlan Gou ◽  
Wei Wang ◽  
Can Ma ◽  
Yong Li ◽  
Yuansheng Lin ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Numerical Simulation ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
Mass Flow Rate ◽  
Mass Flow ◽  
Flow Rate ◽  
Axial Compressor ◽  
Brayton Cycle ◽  
Supercritical Carbon

Using supercritical carbon dioxide (SCO2) as the working fluid of a closed Brayton cycle gas turbine is widely recognized nowadays, because of its compact layout and high efficiency for modest turbine inlet temperature. It is an attractive option for geothermal, nuclear and solar energy conversion. Compressor is one of the key components for the supercritical carbon dioxide Brayton cycle. With established or developing small power supercritical carbon dioxide test loop, centrifugal compressor with small mass flow rate is mainly investigated and manufactured in the literature; however, nuclear energy conversion contains more power, and axial compressor is preferred to provide SCO2 compression with larger mass flow rate which is less studied in the literature. The performance of the axial supercritical carbon dioxide compressor is investigated in the current work. An axial supercritical carbon dioxide compressor with mass flow rate of 1000kg/s is designed. The thermodynamic region of the carbon dioxide is slightly above the vapor-liquid critical point with inlet total temperature 310K and total pressure 9MPa. Numerical simulation is then conducted to assess this axial compressor with look-up table adopted to handle the nonlinear variation property of supercritical carbon dioxide near the critical point. The results show that the performance of the design point of the designed axial compressor matches the primary target. Small corner separation occurs near the hub, and the flow motion of the tip leakage fluid is similar with the well-studied air compressor. Violent property variation near the critical point creates troubles for convergence near the stall condition, and the stall mechanism predictions are more difficult for the axial supercritical carbon dioxide compressor.

The Propagation of Sound in Carbon Dioxide Near the Critical Point

1951 ◽  
Vol 23 (4) ◽  
pp. 423-429 ◽  
Author(s):  
N. S. Anderson ◽  
L. P. Delsasso
Keyword(s):  
Carbon Dioxide ◽  
Critical Point

Carbon Dioxide and Temperature Effects on Evapotranspiration and Water Use Efficiency of Soybean

2003 ◽  
Vol 95 (4) ◽  
pp. 1071-1081 ◽  
Author(s):  
L. H. Allen ◽  
Deyun Pan ◽  
K. J. Boote ◽  
N. B. Pickering ◽  
J. W. Jones
Keyword(s):  
Carbon Dioxide ◽  
Water Use Efficiency ◽  
Water Use ◽  
Temperature Effects ◽  
Use Efficiency

Implications of Phase Change on the Aerodynamics of Centrifugal Compressors for Supercritical Carbon Dioxide Applications

2020 ◽  
Author(s):  
Giacomo Persico ◽  
Lorenzo Toni ◽  
Paolo Gaetani ◽  
Ernani Fulvio Bellobuono ◽  
Alessandro Romei ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Power Systems ◽  
Phase Change ◽  
Critical Point ◽  
Fluid Dynamic ◽  
Flow Analysis ◽  
Design Strategy ◽  
Ideal Gas ◽  
New Challenges ◽  
Line Design

Abstract Closed Joule-Bryton cycles operating with carbon dioxide in supercritical conditions (sCO2) are nowadays collecting a significant scientific interest, due to their high potential efficiency, the compactness of their components, and the flexibility that makes them suitable to exploit diverse energy sources. However, the technical implementation of sCO2 power systems introduces new challenges related to the design and operation of the components. The compressor, in particular, operates in a thermodynamic condition close to the critical point, whereby the fluid exhibits significant non-ideal gas effects and is prone to phase change in the intake region of the machine. These new challenges require novel design concepts and strategies, as well as proper tools to achieve reliable predictions. In the present study, we consider an exemplary sCO2 power cycle with main compressor operating in proximity to the critical point, with an intake entropy level of the fluid lower than the critical value. In this condition, the phase change occurs as evaporation/flashing, thus resembling cavitation phenomena observed in liquid pumps, even though with specific issues associated to compressibility effects occurring in both the phases. The flow configuration is therefore highly nonconventional and demands the development of proper tools for fluid and flow modeling, which are instrumental for the compressor design. The paper discusses the modeling issues from the thermodynamic perspective and then highlighting the implications on the compressor aerodynamics. We propose tailored models to account for the effect of the phase change in 0D mean-line design tools as well as in fully 3D computational fluid-dynamic (CFD) simulations. In this way, a design strategy is build-up as a combination of mean-line tools, industrial design experience, and CFD for detailed flow analysis. The application of the design strategy reveals that the potential onset of the phase change might alter significantly the performance and operation of the compressor, both in design and in off-design conditions.

Supercritical Adsorption

2005 ◽  
Author(s):  
Eldred H. Chimowitz
Keyword(s):  
Stationary Phase ◽  
Critical Point ◽  
Dynamic Models ◽  
Molecular Diffusion ◽  
Plug Flow ◽  
Fluid Phase ◽  
Commercial Application ◽  
Critical Systems ◽  
Mobile Phases ◽  
Column Dynamics

In this chapter, we discuss adsorption phenomena in supercritical systems, a situation that occurs in many application areas in chemical-process and materials engineering. An example of a commercial application in this area, which has achieved wide acceptance as a tool in analytical chemistry, is supercritical fluid chromatography (SFC). Not only is SFC a powerful technique for chemical analysis, but it also is a useful method for measuring transportive and thermodynamic properties in the near-critical systems. In the next section, we analyze adsorption-column dynamics using simple dynamic models, and describe how data from a chromatographic column can be used to estimate various thermodynamic and transport properties.We then proceed to discuss the effects of proximity to the critical point on adsorption behavior in these systems. The closer the system is to its critical point, the more interesting is its behavior. For very dilute solute systems, like those considered here, the energy balance is often ignored to a first approximation; this leads to a simple set of mass-balance equations defining transport for each species. These equations can be developed to various levels of complexity, depending upon the treatment of the adsorbent (stationary phase). The conceptual view of these phases can span a wide range of possibilities ranging from completely nonporous solids (fused structures) to porous materials with complicated ill-defined pore structures. Given these considerations, it is customary to make the following assumptions in the development of a simple model of adsorber-bed dynamics: . . .1. The stationary and mobile phases are continuous in the direction of the flow, with the fluid phase possessing a flat velocity profile (“plug” flow).. . . . . . 2. The porosity of the stationary phase is considered constant irrespective of pressure and temperature conditions (i.e., it is incompressible). . . . . . .3. The column is considered to be radially homogeneous, leading to a set of equations with one spatially independent variable, representing distance along the column axis. . . . . . . 4. The dispersion term in the model equation represents the combined effects of molecular diffusion and dispersion due to convective stirring in the bed. These effects are combined into an effective phenomenological dispersion coefficient, considered to be constant throughout the column. . . .

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