Large single-crystal growth of RBa2Cu3O7−x by the flux method (R=Y and rare earths)

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G. L. Olcese
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We have prepared two kinds of single crystals in Bi-Sr-Ca-Cu oxides by flux method;plate-like single crystals which exhibit metal to superconductor at 93 K, being the high-Tclayered compound BiSr (Ca 0.35 Sr 0.25 Bi 0.40)2 Cu 2Oy with orthorhombic structure with a=5.42 Å, b=5.44 Å and c=30.78 Å respectively, and another kind of bar-shapedbismuth-poor single crystals which is superconducting at the temperature below 82K whilebeing semiconducting above this temperature.


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