Some performance characteristics of a solid-state battery composed of Chevrel phase, a copper-ion conductor, and Prussian blue

1992 ◽  
Vol 27 (19) ◽  
pp. 5315-5319 ◽  
Author(s):  
K. Kuwabara ◽  
J. Itoh ◽  
K. Sugiyama
1987 ◽  
Vol 22 (9) ◽  
pp. 1283-1290 ◽  
Author(s):  
R. Kanno ◽  
Y. Takeda ◽  
M. Ohya ◽  
O. Yamamoto

2020 ◽  
Vol 45 (30) ◽  
pp. 15317-15326
Author(s):  
Shabana P.S. Shaikh ◽  
Pramod Bhatt ◽  
S.M. Yusuf ◽  
S.N. Bhange ◽  
Sudhakar Bansod ◽  
...  

1988 ◽  
Vol 135 ◽  
Author(s):  
T.J. Lee ◽  
P.C. Yao ◽  
S.E. Hsu ◽  
D.J. Fray

AbstractThis study reports measurements of electrical properties of the solid state copper ion conductor CuZr2 (PO4)3.


Nature ◽  
1978 ◽  
Vol 272 (5653) ◽  
pp. 522-524 ◽  
Author(s):  
R. H. DAHM ◽  
S. HACKWOOD ◽  
R. G. LINFORD ◽  
J. M. POLLOCK

2019 ◽  
Vol 7 (36) ◽  
pp. 20790-20798 ◽  
Author(s):  
R. Prasada Rao ◽  
Xin Zhang ◽  
Kia Chai Phuah ◽  
Stefan Adams

Fast-ion conducting Na11Sn2PS12 prepared by ball-milling allowed us to realize the first all-solid-state Na–Se battery, which can reach 500 charge–discharge cycles at room temperature.


Author(s):  
hao he ◽  
yuan chai ◽  
Xinlong Zhang ◽  
Penghui Shi ◽  
Jinchen Fan ◽  
...  

The insufficient ionic conductivity and serious interface problems of oxide-based solid electrolytes greatly limit the performance of all solid-state lithium rechargeable batteries. Herein, a new type of lithium ion conductor...


2019 ◽  
Author(s):  
Saneyuki Ohno ◽  
Bianca Helm ◽  
Till Fuchs ◽  
Georg Dewald ◽  
Marvin Kraft ◽  
...  

<p>All-solid-state batteries are promising candidates for next-generation energy storage devices. Although the list of candidate materials for solid electrolytes has grown in the past decade, there are still many open questions concerning the mechanisms behind ionic migration in materials. In particular, the lithium thiophosphate family of materials has shown very promising properties for solid-state battery applications. Recently, the Ge-substituted Li<sub>6</sub>PS<sub>5</sub>I argyrodite was shown to be a very fast Li-ion conductor, despite the poor ionic conductivity of the unsubstituted Li<sub>6</sub>PS<sub>5</sub>I. Therein, the conductivity was enhanced by over three orders of magnitude due to the emergence of I<sup>−</sup>/S<sup>2−</sup>exchange, <i>i.e.</i>site-disorder, which led to a sudden decrease of the activation barrier with a concurrent flattening of the energy landscapes. Inspired by this work, two series of elemental substitutions in Li<sub>6+<i>x</i></sub>P<sub>1−<i>x</i></sub><i>M<sub>x</sub></i>S<sub>5</sub>I (<i>M</i>= Si and Sn) were investigated in this study and compared to the Ge-analogue. A sharp reduction in the activation energy was observed at the same <i>M</i><sup>4+</sup>/P<sup>5+</sup>composition as previously found in the Ge-analogue, suggesting a more general mechanism at play. Furthermore, structural analyses with X-ray and neutron diffraction indicate that similar changes in the Li-sublattice occur despite a significant variation in the size of the substituents, suggesting that in the argyrodites, the lithium substructure is most likely influenced by the occurring Li<sup>+</sup>– Li<sup>+</sup>interactions. This work provides further evidence that the energy landscape of ionic conductors can be tailored by inducing local disorder.</p>


Author(s):  
Ya-Nan Yang ◽  
Fang-Ling Jiang ◽  
Yi-Qiu Li ◽  
Zhao-Xi Wang ◽  
Tao Zhang

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