High temperature fracture of boron carbide: experiments and simple theoretical models

1984 ◽  
Vol 19 (2) ◽  
pp. 457-466 ◽  
Author(s):  
G. De With
2020 ◽  
Vol 22 (4) ◽  
pp. 1031-1046
Author(s):  
X. Canute ◽  
M. C. Majumder

AbstractThe need for development of high temperature wear resistant composite materials with superior mechanical properties and tribological properties is increasing significantly. The high temperature wear properties of aluminium boron carbide composites was evaluated in this investigation. The effect of load, sliding velocity, temperature and reinforcement percentage on wear rate was determined by the pin heating method using pin heating arrangement. The size and structure of base alloy particles change considerably with an increase of boron carbide particles. The wettability and interface bonding between the matrix and reinforcement enhanced by the addition of potassium flurotitanate. ANOVA technique was used to study the effect of input parameters on wear rate. The investigation reveals that the load had higher significance than sliding velocity, temperature and weight fraction. The pin surface was studied with a high-resolution scanning electron microscope. Regression analysis revealed an extensive association between control parameters and response. The developed composites can be used in the production of automobile parts requiring high wear, frictional and thermal resistance.


2021 ◽  
Vol 10 (1) ◽  
pp. 586-595
Author(s):  
Ruzhuan Wang ◽  
Dingyu Li ◽  
Weiguo Li

Abstract Hardness is one of the important mechanical properties of high-temperature structural ceramics and their composites. In spite of the extensive use of the materials in high-temperature applications, there are few theoretical models for analyzing their temperature-dependent hardness. To fill this gap in the available literature, this work is focused on developing novel theoretical models for the temperature dependence of the hardness of the ceramics and their composites. The proposed model is just expressed in terms of some basic material parameters including Young’s modulus, melting points, and critical damage size corresponding to plastic deformation, which has no fitting parameters, thereby being simple for materials scientists and engineers to use in the material design. The model predictions for the temperature dependence of hardness of some oxide ceramics, non-oxide ceramics, ceramic–ceramic composites, diamond–ceramic composites, and ceramic-based cermet are presented, and excellent agreements with the experimental measurements are shown. Compared with the experimental measurements, the developed model can effectively save the cost when applied in the material design, which could be used to predict at any targeted temperature. Furthermore, the models could be used to determine the underlying control mechanisms of the temperature dependence of the hardness of the materials.


Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5835
Author(s):  
Malefane Joele ◽  
Wallace Rwisayi Matizamhuka

The studies following HEA inceptions were apparently motivated to search for single-phase solid solution over intermetallic phases, accordingly made possible by the concept of high configurational entropy. However, it was realised that the formation of intermetallic phases in HEAs is prevalent due to other criterions that determine stable phases. Nonetheless, recent efforts have been directed towards attributes of microstructural combinations. In this viewpoint, the techniques used to predict microstructural features and methods of microstructural characterisation are elucidated in HESA fields. The study further analyses shortcomings regarding the design approaches of HESAs. A brief history is given into how HESAs were developed since their birth, to emphasize the evaluation techniques used to elucidate high temperature properties of HESAs, and the incentive thereof that enabled further pursuit of HESAs in the direction of optimal microstructure and composition. The theoretical models of strengthening mechanisms in HEAs are explained. The impact of processing route on the HESAs performance is analysed from previous studies. Thereafter, the future of HESAs in the market is conveyed from scientific opinion. Previous designs of HEAs/HESAs were more based on evaluation experiments, which lead to an extended period of research and considerable use of resources; currently, more effort is directed towards computational and theoretical methods to accelerate the exploration of huge HEA composition space.


2004 ◽  
Vol 10 (4) ◽  
pp. 470-480 ◽  
Author(s):  
B.P. Bewlay ◽  
S.D. Sitzman ◽  
L.N. Brewer ◽  
M.R. Jackson

Nb–silicide in situ composites have great potential for high-temperature turbine applications. Nb–silicide composites consist of a ductile Nb-based solid solution together with high-strength silicides, such as Nb5Si3and Nb3Si. With the appropriate addition of alloying elements, such as Ti, Hf, Cr, and Al, it is possible to achieve a promising balance of room-temperature fracture toughness, high-temperature creep performance, and oxidation resistance. In Nb–silicide composites generated from metal-rich binary Nb-Si alloys, Nb3Si is unstable and experiences eutectoid decomposition to Nb and Nb5Si3. At high Ti concentrations, Nb3Si is stabilized to room temperature, and the eutectoid decomposition is suppressed. However, the effect of both Ti and Hf additions in quaternary alloys has not been investigated previously. The present article describes the discovery of a low-temperature eutectoid phase transformation during which (Nb)3Si decomposes into (Nb) and (Nb)5Si3, where the (Nb)5Si3possesses the hP16 crystal structure, as opposed to the tI32 crystal structure observed in binary Nb5Si3. The Ti and Hf concentrations were adjusted over the ranges of 21 to 33 (at.%) and 7.5 to 33 (at.%) to understand the effect of bulk composition on the phases present and the eutectoid phase transformation.


Author(s):  
Jumari A. Robinson ◽  
Adrian Brügger ◽  
Raimondo Betti

<p>The performance of suspension bridges exposed to fire hazards is severely under-studied – so much so that no experimental data exists to quantify the safety of a suspension bridge during or after a major fire event. Bridge performance and safety rely on the integrity of the main cable and its constituent high-strength steel wires. Due to the current lack of experimental high temperature data for wires, the theoretical models use properties and coefficients from data for other types of structural steel. No other structural steel undergoes the amount of cold-working that bridge wire does, and plastic strains from cold-working can be relieved at high temperature, drastically weakening the steel. As such, this work determines the elastic modulus, ultimate strength, and general thermo-mechanical profile of the high-strength steel wires in a range of elevated temperature environments. Specifically, these tests are conducted on a bundle of 61-wires (transient), and at the single wire level (steady-state) at a temperature range of approximately 20-700°C. The test results show an alarmingly high reduction in the elastic modulus and ultimate strength with increased temperature. The degradation shown by experiments is higher than predicted by current theoretical models, indicating that use of high-temperature properties of other types of steel is not sufficient. The test results also show scaling agreement between the single wire and the 61-wire bundle, implying that a full material work up at the single- wire level will accurately inform the failure characterization of the full cable.</p>


2012 ◽  
pp. 415-459

Abstract This chapter compares and contrasts the high-temperature behaviors of metals and composites. It describes the use of creep curves and stress-rupture testing along with the underlying mechanisms in creep deformation and elevated-temperature fracture. It also discusses creep-life prediction and related design methods and some of the factors involved in high-temperature fatigue, including creep-fatigue interaction and thermomechanical damage.


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