The silicon-cerium-oxynitride Ce5 (SiO4)3N with fluorapatite structure

1980 ◽  
Vol 15 (2) ◽  
pp. 521-522 ◽  
Author(s):  
J. P. Guha
2019 ◽  
Vol 83 (4) ◽  
pp. 595-606 ◽  
Author(s):  
Felipe Emerson André Alves ◽  
Reiner Neumann ◽  
Ciro Alexandre Ávila ◽  
Fabiano Richard Leite Faulstich

AbstractFluorapatite with monazite-(Ce) and xenotime-(Y) microinclusions occurs in the lithium–caesium–tantalum pegmatite body A of the Volta Grande mine, Minas Gerais state, Southeast Brazil. The fluorapatite displays faint zoning, detected mainly by cathodoluminescence. Electron probe and laser ablation analyses indicate that zoning in the fluorapatite corresponds to variation in Mn and rare-earth element (REE) content. Such compositional variation is attributed to partial removal of the REE from the fluorapatite structure during a dissolution–reprecipitation process, forming monazite-(Ce) and xenotime-(Y) microinclusions in the REE-depleted zones of the fluorapatite. These inclusions exhibit an inherited geochemical signature, manifested by low Th and U concentrations when compared to monazite and xenotime crystallised from melts. Rhodochrosite and calcite inclusions are also associated with monazite-(Ce) and xenotime-(Y) and are probably products of the same process, recycling Ca, Mn, and CO32− from the fluorapatite through the following reaction: [Ca(5–2a–b–½x),Naa,(Y + REE)a,Mnb][(PO4)3–x(CO3)x(F)] + Fluid[a(2Ca2+ + P5+) + (x–b)(Ca2+) + H2O)] → [Ca5(PO4)3(F,OH)] + a[(Y + REE)PO4] + b[Mn(CO3)] + (x–b)[Ca(CO3)] + Fluid a[Na+].On the basis of new fluid-inclusion analyses, we propose that a hot (T > 204.5°C), salty (16 wt.% eq. NaCl, attributed to LiCl), hydrous fluid mediated the dissolution–reprecipitation of the fluorapatite. This fluid corresponds to similarly described Li-rich fluids which were suggested to have re-equilibrated the mineralogical assemblage at the Volta Grande mine.


1977 ◽  
Vol 12 (1) ◽  
pp. 208-210 ◽  
Author(s):  
R. R. Wills ◽  
J. A. Cunningham
Keyword(s):  

1980 ◽  
Vol 15 (1) ◽  
pp. 264-265 ◽  
Author(s):  
A. W. J. M. Rae ◽  
K. B. Buang ◽  
D. P. Thompson

Vacuum ◽  
1998 ◽  
Vol 49 (3) ◽  
pp. 175-179 ◽  
Author(s):  
M Goshtasbi Rad ◽  
B Hirschauer ◽  
M Göthelid ◽  
UO Karlsson

Alloy Digest ◽  
2004 ◽  
Vol 53 (11) ◽  

Abstract Sirius S15 is a high-temperature stainless steel with the elements silicon, cerium, and lanthanum added for an oxidation resistance that is better than AISI Type 310. Applications are in burners, recuperators, and ducts. This datasheet provides information on composition, physical properties, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming and joining. Filing Code: SS-913. Producer or source: Industeel USA, LLC.


1977 ◽  
Vol 12 (11) ◽  
pp. 2344-2345 ◽  
Author(s):  
D. P. Thompson ◽  
R. R. Wills ◽  
J. A. Cunningham
Keyword(s):  

2010 ◽  
Vol 28 (5) ◽  
pp. 721-726 ◽  
Author(s):  
Haitao XU ◽  
Yuesong SHEN ◽  
Chenghua SHAO ◽  
Fuwen LIN ◽  
Shemin ZHU ◽  
...  

Alloy Digest ◽  
2005 ◽  
Vol 54 (8) ◽  

Abstract Sirius 314 is a high-temperature stainless steel with the elements of silicon, cerium, and lanthanum added for better oxidation resistance compared to AISI Type 310. Applications are in burners, recuperators, and ducts. This datasheet provides information on composition, physical properties, elasticity, tensile properties, and shear strength as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming and joining. Filing Code: SS-937. Producer or source: Industeel USA, LLC.


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