Specific surface area of carbon materials based on hydrated cellulose and polyacrylonitrile fibres calculated by sorption and electrochemical methods

2000 ◽  
Vol 32 (5) ◽  
pp. 365-371
Author(s):  
A. V. Skolunov ◽  
M. E. Kazakov
2015 ◽  
Vol 749 ◽  
pp. 17-21 ◽  
Author(s):  
Joanna Sreńscek Nazzal ◽  
Karolina Glonek ◽  
Jacek Młodzik ◽  
Urszula Narkiewicz ◽  
Antoni W. Morawski ◽  
...  

Microporous carbons prepared from commercial activated carbon WG12 by KOH and/or ZnCl2 treatment were examined as adsorbents for CO2 capture. The micropore volume and specific surface area of the resulting carbons varied from 0.52 cm3/g (1374 m2/g) to 0.70 cm3/g (1800 m2/g), respectively. The obtained microporous carbon materials showed high CO2 adsorption capacities at 40 bar pressure reaching 16.4 mmol/g.


2015 ◽  
Vol 59 (2) ◽  
pp. 225-230 ◽  
Author(s):  
Yanhong Lu ◽  
Guankui Long ◽  
Long Zhang ◽  
Tengfei Zhang ◽  
Mingtao Zhang ◽  
...  

2013 ◽  
Vol 804 ◽  
pp. 89-93
Author(s):  
Jing Yi Yang ◽  
Yu Qiong Chen ◽  
Ying Chuan Ma ◽  
Xin Zhang ◽  
Ling Ling Luo ◽  
...  

Graphene is a fascinating new member of carbon materials with honeycomb and one-atom-thick structure, consisting of 2D hexagonal lattices of sp2 carbon atoms covalently bonded. Graphene has a huge theory specific surface area (over 2600 m2 g1), good thermal conductivity, high values of Youngs modulus and fracture strength, high thermal stability and chemical stability and fast mobility of charge carriers, etc.. In recent years, many researchers found graphene have outstanding adsorption capacity of dyes in aqueous solution due to its high specific surface area. This paper summarized the graphene, graphene oxide and functionalized graphene removing various dyes in wastewater.


2020 ◽  
Vol 49 (16) ◽  
pp. 5006-5014 ◽  
Author(s):  
Yuanyuan Li ◽  
Nan Chen ◽  
Zengling Li ◽  
Huibo Shao ◽  
Liangti Qu

Carbon materials are widely used as capacitive deionization (CDI) electrodes due to their high specific surface area (SSA), superior conductivity, and better stability, including activated carbon, carbon aerogels, carbon nanotubes and graphene.


2020 ◽  
Author(s):  
Sebastijan Kovačič ◽  
Nadejda B. Matsko ◽  
Katharina Gruber ◽  
Stefan Koller ◽  
Christian Slugovc

Monolithic open macroporous carbons of 80-85 % porosity are obtained from pyrolyzing oxidized high internal phase templated poly(dicyclopentadiene) foams. The macropores void diameters of the resulting carbon foams can be ajusted between 87 and 2.5 mikrometer simply by changing the surfactant amount used in the preparation of the precursor foams. The resulting porous carbon materials are charcterized by a carbon content >97%, an electronic conductivity of up to 2800 S/m, a Young's modulus of up to 2.1 GPa and a specific surface area of up to 1200 m<sup>2</sup>/g. <br>


Author(s):  
Fangzhou Wang ◽  
P. K. Kahol ◽  
Ram Gupta ◽  
Xianglin Li

Li−O2 batteries with carbon electrodes made from three commercial carbons and carbon made from waste tea leaves are investigated in this study. The waste tea leaves are recycled from household tea leaves and activated using KOH. The carbon materials have various specific surface areas, and porous structures are characterized by the N2 adsorption/desorption. Vulcan XC 72 carbon shows a higher specific surface area (264.1 m2/g) than the acetylene black (76.5 m2/g) and Super P (60.9 m2/g). The activated tea leaves have an extremely high specific surface area of 2868.4 m2/g. First, we find that the commercial carbons achieve similar discharge capacities of ∼2.50 Ah/g at 0.5 mA/cm2. The micropores in carbon materials result in a high specific surface area but cannot help to achieve higher discharge capacity because it cannot accommodate the solid discharge product (Li2O2). Mixing the acetylene black and the Vulcan XC 72 improves the discharge capacity due to the optimized porous structure. The discharge capacity increases by 42% (from 2.73 ± 0.46 to 3.88 ± 0.22 Ah/g) at 0.5 mA/cm2 when the mass fraction of Vulcan XC 72 changes from 0 to 0.3. Second, the electrode made from activated tea leaves is demonstrated for the first time in Li−O2 batteries. Mixtures of activated tea leaves and acetylene black confirm that mixtures of carbon material with different specific surface areas can increase the discharge capacity. Moreover, carbon made from recycled tea leaves can reduce the cost of the electrode, making electrodes more economically achievable. This study practically enhances the discharge capacity of Li−O2 batteries using mixed carbons and provides a method for fabricating carbon electrodes with lower cost and better environmental friendliness.


Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 496
Author(s):  
Krzysztof Kuśmierek ◽  
Andrzej Świątkowski ◽  
Katarzyna Skrzypczyńska ◽  
Lidia Dąbek

Three carbon materials with a highly diversified structure and at the same time much less different porosity were selected for the study: single-walled carbon nanotubes, heat-treated activated carbon, and reduced graphene oxide. These materials were used for the adsorption of 2,4-D herbicide from aqueous solutions and in its electroanalytical determination. Both the detection of this type of contamination and its removal from the water are important environmental issues. It is important to identify which properties of carbon materials play a significant role. The specific surface area is the major factor. On the other hand, the presence of oxygen bound to the carbon surface in the case of contact with an organochlorine compound had a negative effect. The observed regularities concerned both adsorption and electroanalysis with the use of the carbon materials applied.


Materials ◽  
2019 ◽  
Vol 12 (7) ◽  
pp. 1111 ◽  
Author(s):  
Ling-Yan Meng ◽  
Ming-Guo Ma ◽  
Xing-Xiang Ji

The purpose of this article was to explore the influences of synthetic methods on the lignin-based carbon materials. In this paper, the lignin-based activated carbon materials were comparatively researched in ZnCl2 solution using various methods, including the microwave-assisted method, ultrasound method, and UV irradiation method, respectively. Scanning electron microscopy (SEM), Fourier transform infrared spectrometry (FT-IR), thermogravimetric analysis (TGA), and differential thermal analysis (DTA) were used to characterize the as-prepared samples. The effects of the synthetic parameters including the types of lignin, activated solution concentration, types of activated solution, and synthetic methods on the morphologies, thermal stability, and specific surface area of samples were comparatively investigated in detail. The specific surface area of lignin-based activated carbon increased to 473.8, 765.3, and 211.2 m2∙g−1 using the microwave-assisted method, ultrasound method, and UV irradiation method, respectively, compared with that of the control (113.4 m2∙g−1). The lignin-based carbon materials displayed the enhanced absorptive capacity, compared with that of the control. These novel synthetic methods reported here maybe have a guiding significance for the synthesis of carbon materials using the lignin as precursors.


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