Adsorption TLC with binary mobile phases

1981 ◽  
Vol 14 (2) ◽  
pp. 95-99 ◽  
Author(s):  
J. Ościk ◽  
J. K. Różyło ◽  
B. Ościk-Mendyk ◽  
M. Jaroniec
Keyword(s):  
Mobile Phases ◽  
Binary Mobile Phases

scholarly journals Retention behaviour of some estradiol derivatives on alumina in normal phase chromatrography

2003 ◽  
Vol 68 (3) ◽  
pp. 163-170 ◽  
Author(s):  
Marijana Acanski
Keyword(s):  
Mobile Phase ◽  
Volume Fraction ◽  
Retention Behavior ◽  
Relative Retention ◽  
Linear Relationships ◽  
Mobile Phases ◽  
Binary Mobile Phases ◽  
Estradiol Derivatives ◽  
Rf Values ◽  
The Relationship

The retention constants of variously substituted estradiol derivatives were measured as a function of the composition of various binary mobile phases in order to study the relationship between chemical structure and retention behavior in TLC on alumina. The slopes and intercepts of the linear relationships between the retention constant RM and the logarithm of the volume fraction of the polar mobile phase component were calculated and are discussed in relation to the characteristics of the solute and mobile phase. The RF values and relative retention ?RM of the compounds depend largely on the retention behavior of their substituents. The results obtained in this investigation are compared with the results of the same derivatives obtained in previous investigations on silica gel.

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