Second order retention effects in reversed-phase liquid chromatography. 1. Influence of solute size

1993 ◽  
Vol 37 (3-4) ◽  
pp. 179-184 ◽  
Author(s):  
H. J. Möckel ◽  
U. Dreyer
Keyword(s):  
Liquid Chromatography ◽  
Reversed Phase ◽  
Second Order ◽  
Reversed Phase Liquid Chromatography ◽  
Phase Liquid

Kinetics of the reaction between hexamethylenediisocyanate and 1-pentanol

1983 ◽  
Vol 48 (11) ◽  
pp. 3279-3286
Author(s):  
Slavko Hudeček ◽  
Miloslav Bohdanecký ◽  
Ivana Hudečková ◽  
Pavel Špaček ◽  
Pavel Čefelín
Keyword(s):  
Liquid Chromatography ◽  
Rate Constants ◽  
Reversed Phase ◽  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
Reversed Phase Liquid Chromatography ◽  
Consecutive Reactions ◽  
Phase Liquid ◽  
Kinetics Of

The reaction between hexamethylenediisocyanate and 1-pentanol in toluene was studied by means of reversed-phase liquid chromatography. By employing this method, it was possible to determine all components of the reaction mixture including both products, i.e. N-(6-isocyanate hexyl)pentylcarbamate and N,N'-bis(pentyloxycarbonyl)hexamethylenediamine. Relations for the calculation of kinetic constants were derived assuming a competitive consecutive second-order reaction. It was demonstrated that the reaction involved in this case is indeed a second-order reaction, and the rate constants of the first and second consecutive reactions were determined.

Study on Retention Equation for Protein in Reversed Phase Liquid Chromatography

2013 ◽  
Vol 41 (2) ◽  
pp. 181
Author(s):  
Ling DING ◽  
Jun DONG ◽  
Yuan-Sheng XIAO ◽  
Xiu-Li ZHANG ◽  
Xing-Ya XUE ◽  
...  
Keyword(s):  
Liquid Chromatography ◽  
Reversed Phase ◽  
Reversed Phase Liquid Chromatography ◽  
Retention Equation ◽  
Phase Liquid

Interpretive Approaches to Optimize Serially-Coupled Columns in Reversed-Phase Liquid Chromatography

2015 ◽  
Vol 2 (2) ◽  
pp. 110-121 ◽  
Author(s):  
Tamara Alvarez-Segura ◽  
María García-Alvarez-Coque ◽  
Casandra Ortiz-Bolsico ◽  
José Torres-Lapasió
Keyword(s):  
Liquid Chromatography ◽  
Reversed Phase ◽  
Reversed Phase Liquid Chromatography ◽  
Coupled Columns ◽  
Phase Liquid ◽  
Serially Coupled Columns
Sign in / Sign up

Export Citation Format

Share Document