Effect of the cellular structure on thermal conductivity of rigid closed-cell foam polymers during long-term aging

1999 ◽  
Vol 35 (2) ◽  
pp. 129-138 ◽  
Author(s):  
A. G. Dementyev ◽  
M. A. Dementyev ◽  
P. A. Zinger ◽  
I. R. Metlyakova
Keyword(s):  
Thermal Conductivity ◽  
Cellular Structure ◽  
Closed Cell ◽  
Cell Foam

Temperature dependency of the long-term thermal conductivity of spray polyurethane foam

2021 ◽  
pp. 174425912110454
Author(s):  
Neal Holcroft
Keyword(s):  
Thermal Conductivity ◽  
Polyurethane Foam ◽  
Cellular Structure ◽  
Gas Diffusion ◽  
Temperature Dependent ◽  
Blowing Agent ◽  
Closed Cell ◽  
Wall Assembly ◽  
Cell Foam

The thermal properties of closed-cell foam insulation display a more complex behaviour than other construction materials due to the properties of the blowing agent captured in their cellular structure. Over time, blowing agent diffuses out from and air into the cellular structure resulting in an increase in thermal conductivity, a process that is temperature dependent. Some blowing agents also condense at temperatures within the in-service range of the insulation, resulting in non-linear temperature dependent relationships. Moreover, diffusion of moisture into the cellular structure increases thermal conductivity. Standards exist to quantify the effect of gas diffusion on thermal conductivity, however only at standard laboratory conditions. In this paper a new test procedure is described that includes calculation methods to determine Temperature Dependent Long-Term Thermal Conductivity (LTTC(T)) functions for closed-cell foam insulation using as a test material, a Medium-Density Spray Polyurethane Foam (MDSPF). Tests results are provided to show the validity of the method and to investigate the effects of both conditioning and mean test temperature on change in thermal conductivity. In addition, testing was conducted to produce a moisture dependent thermal conductivity function. The resulting functions were used in hygrothermal simulations to assess the effect of foam aging, in-service temperature and moisture content on the performance of a typical wall assembly incorporating MDSPF located in four Canadian climate zones. Results show that after 1 year, mean thermal conductivity increased 15%–16% and after 5 years 23%–24%, depending on climate zone. Furthermore, the use of the LTTC(T) function to calculate the wall assembly U-value improved accuracy between 3% and 5%.

scholarly journals Microstructural and Chemical Analysis of Polyurethane and Polyisocyanurate Foam Insulations

2021 ◽  
Author(s):  
Umberto Berardi
Keyword(s):  
Thermal Conductivity ◽  
Thermal Performance ◽  
Cell Structure ◽  
Polymer Degradation ◽  
Chemical Characterization ◽  
Aging Behavior ◽  
Blowing Agent ◽  
Closed Cell ◽  
Physical Attributes ◽  
Cell Foam

For some closed cell foam insulation products, the thermal conductivity increases at low temperatures, contrary to single thermal resistance values provided by manufacturers. This phenomenon has been demonstrated in various polyurethane and polyisocyanurate insulations. The reduction in thermal performance has been attributed to the diffusion of air and blowing agent through the foam and to the condensation of blowing agent. Aging processes such as freeze-thaw cycling, moisture accumulation, and polymer degradation further increase thermal conductivity. The initial cell structure plays a role in dictating the thermal performance. To further understand the loss of thermal performance in closed cell foams, microstructure and chemical characterization was performed in this study. The aging behavior of foam insulations was analyzed by imaging foams with SEM and by measuring foam. Changes in the polymer physical attributes were identified and compared to increases in thermal conductivity. This project also used gas chromatography and quantified changes in pentane concentration in polyisocyanurate foams that have undergone aging

Numerical Prediction of the Effective Thermal Conductivity of Open- and Closed-Cell Foam Structures

2010 ◽  
Vol 297-301 ◽  
pp. 1210-1217 ◽  
Author(s):  
Seyed Mohammad Hossein Hosseini ◽  
Andreas Öchsner ◽  
Thomas Fiedler
Keyword(s):  
Thermal Conductivity ◽  
Thermal Properties ◽  
Relative Density ◽  
Effective Thermal Conductivity ◽  
Linear Trend ◽  
Space Filling ◽  
Open Cell ◽  
Cell Structures ◽  
Closed Cell ◽  
Cell Foam

This paper investigates the thermal properties of metallic open-cell and closed-cell foam structures in space filling and non-space filling configurations. In both, i.e. open-cell and closed-cell structures, a linear trend depending on the relative density has been reported. However the closed-cell structures compared to open-cell ones have a higher thermal conductivity for the same relative density.

scholarly journals Rigid Polyurethane Foams with Various Isocyanate Indices Based on Polyols from Rapeseed Oil and Waste PET

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 738 ◽  
Author(s):  
Aiga Ivdre ◽  
Arnis Abolins ◽  
Irina Sevastyanova ◽  
Mikelis Kirpluks ◽  
Ugis Cabulis ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Rapeseed Oil ◽  
Crosslink Density ◽  
Polyurethane Foams ◽  
Insulation Material ◽  
Cell Content ◽  
Natural Sources ◽  
Isocyanate Index ◽  
Closed Cell

Developing polyols derived from natural sources and recycling materials attracts great interest for use in replacing petroleum-based polyols in polyurethane production. In this study, rigid polyurethane (PUR) foams with various isocyanate indices were obtained from polyols based on rapeseed oil and polyethylene terephthalate (RO/PET). The various properties of the prepared PUR foams were investigated, and the effect of the isocyanate index was evaluated. The closed-cell content and water absorption were not impacted by the change of the isocyanate index. The most significant effect of increasing the isocyanate index was on the dimensional stability of the resulting foams. This is due to the increased crosslink density, as evidenced by the increased formation of isocyanurate and increase of the glass transition temperature. Additionally, the influence on compression strength, modulus, and long-term thermal conductivity were evaluated and compared with reference PUR foams from commercially available polyols. Rigid PUR foams from RO/PET polyol were found to be competitive with reference materials and could be used as thermal insulation material.

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