Study of the heterogeneous decomposition of tertiary-butyl alcohol and di-tertiary-butyl peroxide on SiO2 by temperature programmed desorption

1985 ◽  
Vol 27 (2) ◽  
pp. 347-349
Author(s):  
R. K. Aliev ◽  
M. T. Chaltykyan ◽  
A. B. Nalbandyan ◽  
N. K. Kotsev ◽  
L. S. Minchev ◽  
...  
1961 ◽  
Vol 39 (7) ◽  
pp. 1424-1433 ◽  
Author(s):  
K. M. Bell ◽  
C. A. McDowell

The mercury-photosensitized oxidation of isobutane has been studied over a wide range of pressures of the hydrocarbon and oxygen, in a conventional static photochemical apparatus at the temperatures of 30 °C and 100 °C. The main products of the reaction are tertiary butyl hydroperoxide, together with tertiary butyl alcohol, acetone, and corresponding small quantities of formaldehyde and methyl alcohol. Isobutyraldehyde was also detected; ditertiary butyl peroxide being notably absent. Peroxide yields suggest that a reaction between an excited isobutane molecule and oxygen is important in the initiation processes and that peroxide is formed in the reaction[Formula: see text]


2006 ◽  
Vol 312 (1-2) ◽  
pp. 131-136 ◽  
Author(s):  
JingXia Cui ◽  
ChunLei Li ◽  
YingJie Deng ◽  
YongLi Wang ◽  
Wei Wang

2010 ◽  
Vol 260 (1) ◽  
pp. 77-83 ◽  
Author(s):  
E.A. Cohen ◽  
B.J. Drouin ◽  
E.A. Valenzuela ◽  
R.C. Woods ◽  
W. Caminati ◽  
...  

1997 ◽  
Vol 92 (3) ◽  
pp. 179-186 ◽  
Author(s):  
Torka S. Poet ◽  
John L. Valentine ◽  
Susan J. Borghoff

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