Application of the principles of homogeneous catalysis to the synthesis and mechanistic study of heterogeneous catalysts of olefin conversion

1987 ◽  
Vol 35 (1-2) ◽  
pp. 153-161 ◽  
Author(s):  
V. A. Likholobov ◽  
V. A. Zakharov
Keyword(s):  
Homogeneous Catalysis ◽  
Heterogeneous Catalysts ◽  
Mechanistic Study ◽  
Olefin Conversion

Phosphorus Containing Porous Organic Polymers: Synthetic Techniques and Applications in Organic Synthesis and Catalysis

2021 ◽  
Author(s):  
Pramod Kumar ◽  
Animesh Das ◽  
Biplab Maji
Keyword(s):  
Organic Synthesis ◽  
Homogeneous Catalysis ◽  
Heterogeneous Catalysts ◽  
Organic Polymer ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Porous Organic Polymer ◽  
Phosphorus Containing

The phosphorous-containing porous organic polymer is a trending material for the synthesis of heterogeneous catalysts. Decades of investigations have established phosphines as versatile ligands in homogeneous catalysis. Recently, phosphine-based heterogeneous...

scholarly journals Ionic Pd/NHC Catalytic System Enables Recoverable Homogeneous Catalysis: Mechanistic Study and Application in the Mizoroki–Heck Reaction

2019 ◽  
Vol 25 (72) ◽  
pp. 16439-16439
Author(s):  
Dmitry B. Eremin ◽  
Ekaterina A. Denisova ◽  
Alexander Yu. Kostyukovich ◽  
Jonathan Martens ◽  
Giel Berden ◽  
...  
Keyword(s):  
Homogeneous Catalysis ◽  
Catalytic System ◽  
Heck Reaction ◽  
Mechanistic Study

scholarly journals Linear scaling relationships and volcano plots in homogeneous catalysis – revisiting the Suzuki reaction

2015 ◽  
Vol 6 (12) ◽  
pp. 6754-6761 ◽  
Author(s):  
Michael Busch ◽  
Matthew D. Wodrich ◽  
Clémence Corminboeuf
Keyword(s):  
Homogeneous Catalysis ◽  
Heterogeneous Catalysts ◽  
Suzuki Reaction ◽  
Homogeneous System ◽  
Linear Scaling ◽  
Scaling Relationships ◽  
Volcano Plots ◽  
System P ◽  
First Time

Volcano plots, commonly used to identify attractive heterogeneous catalysts are applied, for the first time, to a prototypical homogeneous system.

scholarly journals Front Cover: Ionic Pd/NHC Catalytic System Enables Recoverable Homogeneous Catalysis: Mechanistic Study and Application in the Mizoroki–Heck Reaction (Chem. Eur. J. 72/2019)

2019 ◽  
Vol 25 (72) ◽  
pp. 16435-16435
Author(s):  
Dmitry B. Eremin ◽  
Ekaterina A. Denisova ◽  
Alexander Yu. Kostyukovich ◽  
Jonathan Martens ◽  
Giel Berden ◽  
...  
Keyword(s):  
Homogeneous Catalysis ◽  
Catalytic System ◽  
Heck Reaction ◽  
Mechanistic Study ◽  
Front Cover

Mechanistic study and catalyst development for selective carbon monoxide methanation

2015 ◽  
Vol 5 (6) ◽  
pp. 3061-3070 ◽  
Author(s):  
S. Tada ◽  
R. Kikuchi
Keyword(s):  
Carbon Monoxide ◽  
Reaction Mechanism ◽  
Heterogeneous Catalysts ◽  
Mechanistic Study ◽  
Co Methanation ◽  
Catalyst Development ◽  
Selective Co Methanation

As for selective CO methanation over heterogeneous catalysts, numerous investigations of the reaction mechanism and catalyst development are reviewed.

Ionic Pd/NHC Catalytic System Enables Recoverable Homogeneous Catalysis: Mechanistic Study and Application in the Mizoroki–Heck Reaction

2019 ◽  
Vol 25 (72) ◽  
pp. 16564-16572 ◽  
Author(s):  
Dmitry B. Eremin ◽  
Ekaterina A. Denisova ◽  
Alexander Yu. Kostyukovich ◽  
Jonathan Martens ◽  
Giel Berden ◽  
...  
Keyword(s):  
Homogeneous Catalysis ◽  
Catalytic System ◽  
Heck Reaction ◽  
Mechanistic Study

scholarly journals Glass Surface as Strong Base, ‘Green’ Heterogeneous Catalyst and Degradation Reagent

2021 ◽  
Author(s):  
Yangjie Li ◽  
Kai-Hung Huang ◽  
Nicolás Morato ◽  
R. Graham Cooks
Keyword(s):  
Chemical Reactions ◽  
Heterogeneous Catalysts ◽  
Desorption Electrospray Ionization ◽  
Mechanistic Study ◽  
Ionization Mass ◽  
Systematic Screening ◽  
Strong Base ◽  
Low Concentrations ◽  
Conjugate Bases ◽  
Glass Surfaces

Systematic screening of accelerated chemical reactions at solid/solution interfaces has been carried out in high-throughput fashion using desorption electrospray ionization mass spectrometry and it provides evidence that glass surfaces accelerate various base-catalyzed chemical reactions. The reaction types include elimination, solvolysis, condensation and oxidation, whether or not the substrates are pre-charged. In a detailed mechanistic study, we provide evidence using nanoESI showing that glass surfaces can act as strong bases and convert protic solvents into their conjugate bases which then act as bases/nucleophiles when participating in chemical reactions. In aprotic solvents such as acetonitrile, glass surfaces act as ‘green’ heterogeneous catalysts that can be recovered and reused after simple rinsing. Besides their use in organic reaction catalysis, glass surfaces are also found to act as degradation reagents for phospholipids with increasing extents of degradation occuring at low concentrations. This finding suggests that the storage of base/nucleophile-labile compounds or lipids in glass containers should be avoided. <br>

Sign in / Sign up

Export Citation Format

Share Document