Adduct formation constant in the synergic extraction of several rare earth elements with acetylacetone and 1,10-phenanthroline in nonpolar organic solvents

1986 ◽  
Vol 99 (1) ◽  
pp. 145-152 ◽  
Author(s):  
S. Nakamura ◽  
N. Suzuki
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Organic Solvents ◽  
Formation Constant ◽  
Adduct Formation ◽  
Synergic Extraction ◽  
Adduct Formation Constant ◽  
Nonpolar Organic

scholarly journals Extraction of Eu(III), Gd(III), and Tb(III) in aqueous two-phase systems based on polyethylene glycol 1500-NaNO3-H2O with the addition of extractants (D2EHPA, TBP, TOMAN)

2022 ◽  
Vol 1212 (1) ◽  
pp. 012012
Author(s):  
A Ya Fedorov ◽  
A V Levina ◽  
M I Fedorova
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Organic Solvents ◽  
Point Of View ◽  
Water Soluble ◽  
Rational Approach ◽  
Two Phase ◽  
Waste Products ◽  
Aqueous Two Phase Systems ◽  
Phase Systems

Abstract Luminophores that used, for example, in fluorescent lamps, contain a large number of rare earth elements. Therefore, the processing of waste equipment containing luminophores is a rational approach to the obtaining of rare-earth metals, firstly, from the economics point of view, since they have a high cost, and secondly, from the ecological point of view, since environmental pollution will not occur. The cheapest way to extract rare earth elements from waste products is to dissolve them in strong acids and the following reprocessing by liquid extraction methods. In this case, neutral or ion exchange extractants (tributyl phosphate, di(2-ethylhexyl)phosphoric acid and quaternary ammonium salts) are used, which show high extraction ability and, in some cases, selectivity. Their applying is associated with the use of non-polar organic solvents, which contradicts the principles of «green» chemistry. A good and promising alternative to organic solvents can be aqueous two-phase systems, which have already proved themselves as low-toxic, but highly effective systems for the separation of a number of metals. Thus, in this work, we performed an experimental study of the interphase distribution of Eu(III), Gd(III), and Tb(III) in two-phase systems based on water-soluble polymers with or without the introduction of traditional organic extractants as an additive. The possibility of using such ATPS as a «green» solvent for traditional extragents for Eu(III), Gd(III), and Tb(III) extraction has been shown.

Flame spectra of the rare-earth elements*

1962 ◽  
Vol 18 (4) ◽  
pp. 1127-1153
Author(s):  
V FASSEL ◽  
R CURRY ◽  
R KNISELEY
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
The Rare Earth

ESTIMATION OF THE ABUNDANCE AND DISTRIBUTION OF RARE EARTH ELEMENTS IN SOIL AROUND KADUNA REFINING AND PETROCHEMICAL COMPANY USING NUCLEAR TECHNIQUE

2020 ◽  
Vol 4 (2) ◽  
pp. 599-604
Author(s):  
Michael A. Onoja ◽  
P. H. Bukar ◽  
C. U. Omeje ◽  
A. M. Adamu
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Nuclear Technique ◽  
Flood Plains ◽  
Economic Exploitation ◽  
Rare Elements ◽  
Petrochemical Company ◽  
The Moment ◽  
Abundance And Distribution ◽  
Natural Pattern

Instrumental neutron activation analysis (INAA) technique was used to investigate the abundance and distribution of rare earth elements (REE) in soil around Kaduna Refinery. The aim of the study is to assess the rare elements potential of Nigeria for economic exploitation. Five REEs (La, Dy, Eu, Yb, and Lu) were detected in varying concentrations ranging from a minimum of 0.6 µg/g (Lu) to a maximum of 249.0 µg/g (La). The elements existed with trends consistent with the natural pattern of REEs in soil, showing significant Eu and Dy anomalies which characterize upper plains and flood plains. The levels of REEs in soil in the study area were generally slightly above background levels, with minimal (La, Dy, and Eu), moderate (Yb), and significant (Lu) enrichments and trending: Lu ˃Yb ˃ Eu ˃ Dy ˃ La. The abundance of the REEs investigated cannot establish a potential of Nigeria for economic exploitation of the mineral, hence, rare earth project in the study area is not viable at the moment.

Sc, Y, La-Lu Rare Earth Elements

1986 ◽  
Author(s):  
Ingeborg Hinz ◽  
Peter Kuhn ◽  
Ursula Vetter ◽  
Eberhard Warkentin
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements

Sc, Y, La-Lu, Rare Earth Elements

1989 ◽  
Author(s):  
Hiltrud Hein ◽  
Claus Koeppel ◽  
Ursula Vetter ◽  
Eberhard Warkentin
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements
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