Geochemical characteristics of Archaean and Late Proterozoic to Palaeozoic fine-grained sediments from Southern Africa and significance for the evolution of the continental crust

1985 ◽  
Vol 74 (1) ◽  
pp. 1-9 ◽  
Author(s):  
N. Laskowski ◽  
A. Kröner
Keyword(s):  
Continental Crust ◽  
Southern Africa ◽  
Geochemical Characteristics ◽  
Fine Grained ◽  
Late Proterozoic

Geochemistry and geochronology of alkaline dykes from the Finero Phlogopite Peridotite (Ivrea-Verbano Zone): insights into the Triassic-Jurassic tectono-magmatic events of the Southern Alps

2021 ◽  
Author(s):  
Abimbola Chris Ogunyele ◽  
Tommaso Giovanardi ◽  
Mattia Bonazzi ◽  
Maurizio Mazzucchelli ◽  
Alberto Zanetti
Keyword(s):  
Continental Crust ◽  
Southern Alps ◽  
Coarse Grained ◽  
Dyke Swarm ◽  
Fine Grained ◽  
Sector Zoning ◽  
Magmatic Stage ◽  
Late Magmatic Stage ◽  
Mesozoic Magmatism ◽  
Peridotite Mantle

<p>The Ivrea-Verbano Zone (IVZ, westernmost sector of the Southern Alps) represents a unique opportunity to investigate the Paleozoic to Mesozoic geodynamic evolution of the Gondwana and Laurasia boundary from the perspective of the lower continental crust. Only recently, the petrochemical record of Triassic-Jurassic magmatism has been recognized. It mainly affected the northernmost tip, the Finero Complex, where the continental crust was tectonically thinned before opening of Alpine Tethys. However, the Mesozoic magmatism in the Finero Complex is still poorly-constrained. Firstly, its extent is largely unknown, because the mantle and crustal intrusives were already enriched by Paleozoic processes. Secondly, Mesozoic melts migration started when the Finero Complex was still placed at P-T conditions typical of a continental crust-mantle transition (1 GPa): this has promoted the reopening of the geochronological clocks in both Paleozoic and Mesozoic rocks, which usually provides wide time intervals. Lastly, the finding of Mesozoic magmatism as composite veins/pods and metasomatised layers has not allowed an exhaustive reconstruction of the primitive melts geochemistry. To place further constraints on such issue, a new dyke swarm cropping out in the Finero Phlogopite Peridotite mantle unit has been investigated. Dykes usually cut at high angle the mantle foliation and are up to 60 cm thick. They are composed by coarse-grained hornblendite to anorthosite, both phlogopite/biotite-bearing. Many dykes are composite, showing variable proportions of hornblendite and anorthosite. In places, the dyke swam was affected by volatiles overpressure as late magmatic stage, which produced plastic flow and development of a porphyroclastic structure by deformation of the early cumulates, with widespread segregation of a fine-grained mica matrix.</p><p>Dykes mainly consist of pargasite, phlogopite/biotite, albite (An 8-10), in association with apatite, monazite, ilmenite, zircon, Nb-rich oxides, carbonates. Enrichments in Fe (amphibole and biotite) and Na (plagioclase) suggest segregation from evolved melts, strongly enriched in H<sub>2</sub>O, P, C. The large LILE and LREE contents in amphiboles, sometimes associated to high Nb, Ta, Zr and Hf concentrations, as well as the mineral assemblage, support an alkaline affinity of the melts. The strongly positive εHf<sub>t </sub>(+10) of zircons and the isotopic Sr composition of amphiboles (0.7042) point to a derivation of the melts from mildly enriched sources, possibly located at the crust-mantle interface.</p><p>Zircons from anorthosite layers are mostly anhedral fragments. They show homogenous internal structure or sector zoning. Concordant <sup>206</sup>Pb/<sup>238</sup>U zircon ages vary from 221 ± 9 Ma to 192 ± 8 Ma. The results of this study confirm that mantle input to the Southern Alps magmatism was of alkaline affinity from Norian to Sinemurian. A widespread fluids circulation induced by such magmatism at high P-T conditions was likely the main cause of the diffuse geochronological reset towards Mesozoic ages of the northern IVZ.</p>

scholarly journals The Metallogenic Mechanism of Skarn Sn-Polymetallic Deposits in the Southern Great Khingan Range, China: Constraints on the Geological and Geochemical Characteristics of Damogutu Sn–Fe and Dashishan Sn–Pb–Zn Deposits

Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 418 ◽  
Author(s):  
Shangsong Yang ◽  
Heng Wang ◽  
Xinyou Zhu ◽  
Tao Zou ◽  
Chaolei Yang ◽  
...  
Keyword(s):  
Oxygen Fugacity ◽  
Late Stage ◽  
Early Stage ◽  
Geochemical Characteristics ◽  
Evolution Process ◽  
Fine Grained ◽  
Period 2 ◽  
Hydrothermal Stage ◽  
Metallogenic Mechanism ◽  
Reducing Environment

Skarn Sn-polymetallic deposits, located in the southern Great Khingan Range, can be divided into Sn–Fe and Sn–Pb–Zn deposits. By systematically studying the geochemical characteristics of source granitoid and deposits, the ore-forming mechanisms were established, and the differences in ore-forming processes between Sn–Fe and Sn–Pb–Zn deposits are discussed. The main findings are as follows: (1) these two deposits were formed in the Late-Yanshanian period; (2) the source granitoid evolved at an early stage in a reducing environment, while the oxygen fugacity increased at a late stage through the influence of a deep-seated fault; (3) fine-grained syenogranite from Dashishan showed a higher degree of evolution than the syenogranite from Damogutu; (4) the Damogutu Sn–Fe and Dashishan Sn–Pb–Zn deposits shared a source of ore-forming fluid, and Fe, Sn, Pb, and Zn all derived from Late-Yanshanian granitoids; and (5) the ore-forming fluid experienced a continuous evolution process from the magmatic to hydrothermal stage, and the magmatic–hydrothermal transitional fluid played a very important role in skarnization and mineralization.

Pb–Zn occurrences and their Pb-isotopic signatures bearing on metallogeny and mineral exploration—Paleozoic sedimentary rocks, northern Appalachians, Quebec

1988 ◽  
Vol 25 (11) ◽  
pp. 1777-1790 ◽  
Author(s):  
K. Schrijver ◽  
E. Marcoux ◽  
G. Beaudoin ◽  
J. Y. Calvez
Keyword(s):  
Continental Crust ◽  
Mineral Exploration ◽  
Sedimentary Rocks ◽  
Isotope Ratios ◽  
Isotopic Signature ◽  
Coarse Grained ◽  
Pb Isotope ◽  
Isotopic Signatures ◽  
Fine Grained ◽  
Quartz Veins

Galena Pb-isotope ratios of epithermal vein and disseminated sulfide occurrences in the Taconian Orogen and Siluro-Devonian basin cluster around 17.90–18.05 for 206Pb/204Pb and 37.70–38.00 for 208Pb/204Pb. The major source of Pb in most, if not all, occurrences is a fairly common continental crust, a characteristic found in published analyses of Grenville feldspar Pb. A southwest to northeast increase in galena 206Pb/204Pb ratios is ascribed to the supply of several types of detritus from Grenville basement during the Cambro-Ordovician: coarse-grained, K-feldspar-bearing in the southwest, grading into fine-grained phyllitic, and relatively more highly radiogenic in the northeast.Emplacement (i) of Pb–Zn–barite veins and disseminations, commonly of homogeneous crustal Pb-isotopic signature, was late Taconian; (ii) of Pb–Zn–quartz veins, of less homogeneous signature, was post-Taconian; and (iii) of Pb–Zn–carbonate veins, relatively highly radiogenic and commonly homogeneous, was late or post-Acadian. Signatures of the first-mentioned group seem to be most useful in exploration.

scholarly journals Chemical compositions of amphiboles and their references to formation conditions of granitoids from Nam Rom and Song Ma massifs, Northwest Vietnam

2020 ◽  
Vol 42 (1) ◽  
pp. 80-92
Author(s):  
Pham Ngoc Can ◽  
Tran Tuan Anh ◽  
Tran Trong Hoa ◽  
Vu Hoang Ly ◽  
Pham Thi Phuong Lien ◽  
...  
Keyword(s):  
Geochemical Characteristics ◽  
The Other ◽  
Chemical Compositions ◽  
Formula Unit ◽  
Fine Grained ◽  
Basic Stage ◽  
Other Hand ◽  
Formation Conditions ◽  
Similar Formation

In this paper, the mineralogical and geochemical characteristics of amphiboles and plagioclases of granitoids from the Nam Rom and Song Ma massifs have been investigated to understand their formation conditions. The Nam Rom amphibole and plagioclase are subhedral to euhedral fine- to medium-grained crystals. Whereas, the Song Ma amphibole and plagioclase are anhedral to subhedral fine-grained crystals. Geochemical compositions of amphiboles suggest that Nam Rom and Song Ma amphiboles are edenite and ferro-edenite, respectively. Nam Rom edenite has higher contents of basic constituents (Mg and Ca) and lower contents of felsic constituents (Na and K) compared with the Song Ma ferro-edenite. On the other hand, Si-(Na+K) and Si-Ca apfu ratios of the Nam Rom edenite and the Song Ma ferro-edenite and Al/(Na+K)-Al/(Ca+Na+K) atom per formula unit (apfu) ratios of the Nam Rom edenite and andesine and the Song Ma ferro-edenite, andesine and oligoclase are similar. Formation conditions of the Nam Rom and Song Ma granitoids were calculated using amphibole-plagioclase geobarometer. The Nam Rom granitoid was formed at 3.07-5.32 kbar (10.1-17.6 km under paleo-surface) and 750-785°C. The Song Ma granitoid was formed at 1.04-3.08 kbar (3.4-10.2 km under paleo-surface) and 715-745°C. Therefore, Nam Rom and Song Ma granitoids are thought to be crystallized from the same magma. The former was formed from the immature and more basic stage of magma; the latter was formed from the mature and more felsic stage of magma.

scholarly journals Petrology and geochemistry of granitoids and their mafic micogranular enclaves (MME) in marginal part of the Małopolska Block (S Poland)

Mineralogia ◽  
2012 ◽  
Vol 43 (1-2) ◽  
pp. 3-127 ◽  
Author(s):  
Anna Wolska
Keyword(s):  
Trace Elements ◽  
Continental Crust ◽  
Coarse Grained ◽  
Granitic Rocks ◽  
Mixing Process ◽  
Na2o Content ◽  
Fine Grained ◽  
Małopolska Block ◽  
First Time ◽  
Different Sources

AbstractGranitic plutons (the Dolina Będkowska valley and Pilica area) were found in a few boreholes in the Małopolska Block (MB). These granitic rocks may represent apical parts (apophyses) of a great magmatic bodies (batholiths) located in deeper level of the Ediacaran/Paleozoic basement. They are described as ‘stitching intrusions’, generated during/after collision in Carboniferous/Permian period (~300 Ma) between the Upper Silesian Block (USB) and the Małopolska Block (MB).These rocks are fresh, unaltered granodiorites that are pale grey in colour. They have holocrystalline, medium- to coarse-grained structure and massive texture. For the first time, several mafic microgranular enclaves (MME), varying in size and colour, were found in the granodioritic host (HG). The occurrence of MME in the host granodioritic rocks is evidence of a mingling process between mafic and felsic magmas.The MME are pale/dark grey in colour, fine-grained rocks with ‘porphyritic’ textures. They consist of large megacrysts/xenocrysts of plagioclase, quartz, alkali feldspars and the fine-grained groundmass of pseudo-doleritic textures (lath-shaped plagioclases, blade-shaped amphiboles/biotites). According to their modal/mineral composition, they represent Q-diorites and tonalites.The MME, similar to the host granodiorites (HG), are I-type rocks, exhibit high Na2O content >3.2 wt%; normative diopside or normative corundum occurs (mainly <1%). They are metaluminous to slightly peraluminous (ASI <1.1) and have calc-alkaline, medium-K to high-K character. They generally belong to magnesian series (#Mg=0.20-0.40) and have low agpaitic index (<0.87). They are low evolved magmatic rocks. The rocks studied are enriched in LREEs (La, Ce, Sm) compared to HREEs. The Eu* negative anomaly and high Sr contents point to varying degrees of plagioclase fractionation connected to the mixing process rather than simple fractional crystallization. Both rocks studied (HG and MME) are characterized by a high content of LILEs (K, Ba, Rb) in normalized patterns and a low HFS/LIL elements ratio (Ta, Nb)/(K, Rb, La). The projection points of the rocks studied plot in different fields of various petrochemical diagrams: mainly in the arc granites that are rare in the pre-collisional granites as well as the syn-subductional to post-collisional granites fields.For the first time, inner textures in rock-forming minerals related to mixing processes are described both in the granodioritic host (HG) and in the MME. Mantled boxy cellular plagioclase megacrysts with ‘old cores’ of labradorite composition, and amphibole aggregates with titanite and opaque minerals, represent peritectic rather than primary residual minerals. The plagioclase, quartz and alkali feldspar megacrysts/xenocrysts were mechanically transferred from the granodioritic host (HG) to MME. The presence of lath-shaped plagioclases, blade-shaped amphiboles/biotites and acicular-shaped apatites in the groundmass of the MME is evidence of undercooling of hot mafic blobs in a relatively cold granodioritic magma chamber. The MME were hybridized by leucocratic melt squeezed from the granodioritic magma in a later stage of the mixing process (quartz and alkali crystals in the interstices in the MME groundmass). In the granodiorites (HG), the spike and spongy cellular zones as well as biotite/amphibole zones in plagioclase megacrysts are connected to the mixing process.Both of the rocks studied are characterized by different amounts of major elements (SiO2, Na2O and K2O), trace elements (Ni, Cr, V, Ti and P), #Mg and modified alkali-lime index (MALI) that is related to their origins from different sources. On the other hand, they have similar chondrite-normalized patterns (for trace elements and REE), LILEs contents (Sr, Ba, Rb), aluminum saturation index (ASI) and isotopic signatures (high 86Sr/87Sr (0.079-0.713) and low 143Nd/144Nd (0.512) values but lower than in continental crust), which are evidence of the strong hybridisation of mafic enclaves by the granodioritic host magma. The parental rocks of both rocks studied have a similar mafic signature but were generated in different sources: the host granodiorites (HG) magma in lower continental crust rocks, and the MME magma in enriched upper mantle. The MME crystallized from strongly hybridized magma of intermediate compositions (Q-diorite, tonalite) rather than from primary mafic magma. The host granodiorites (HG) originated from completely homogenized crustal granodioritic magma which inherited its geochemical signature from ancient arc-rocks in a subduction-related setting

scholarly journals PETROGRAPHIC, MINERAL, GEOCHEMICAL CHARACTERISTICS OF BA NA GRANITOID

2009 ◽  
Vol 12 (7) ◽  
pp. 58-71
Author(s):  
Phuc Duc Le
Keyword(s):  
Mantle Source ◽  
Source Region ◽  
Isotopic Analysis ◽  
Biotite Granite ◽  
Geochemical Characteristics ◽  
Second Phase ◽  
Granite Sample ◽  
Petrographic Composition ◽  
Fine Grained ◽  
Mantle Source Region

Ba Na granitoid is isometric shape, with exposure of 30 sqa km area. Petrographic composition is mainly coarse - medium grained biotite granite, included in the first phase. The fine grained leuco rock of the second phase is small massif in shape, distributed along fault in NE-SW direction. SiO, content of Bana granitoid is variation from 73.74% to 76.24%. Total of K2O +Na2O is from 7.32% to 8.33%. Ratio of K2O/Na2O: 1.66 - 2.07. This is S-Granite. Value of 147Sm/144Nd = 0,1249 is nearly stable crust material. Ratio of Sm/Nd is low. ena has negative value and very small proved that Ba Na granitoid must derive from crust source or mantle source which rich (EM). The age of source regional forming calculated from isotopic of Sm, Nd is 1.06 Ba (according to model of chondrite mantle source region) or 1.74 Ba (according to model of poor mantle source). The prospects of related mineralization of Ba Na granitoid is Sn (W, Nb, Ta) with amsemblage of topaz - cassiterite - tourmaline - quartz (sometime is Ta - Nb). The result of isotopic analysis of U Pb in zircon of Ba Na biotite granite sample at lab of Tasmania University, Australia, age of Ba Na is 242.9 +1.5 Ma and 240.6 2.2 Ma.

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