X-ray determination of the thermal expansion coefficients of manganese and cobalt monosilicides

Atomic Energy ◽  
1963 ◽  
Vol 13 (2) ◽  
pp. 784-785 ◽  
Author(s):  
N. N. Zhuravlev ◽  
A. A. Stepanova
Keyword(s):  
Thermal Expansion ◽  
X Ray ◽  
Thermal Expansion Coefficients ◽  
Expansion Coefficients

An X-ray determination of the thermal expansion of the intermetallic compound Ni3Zr

1983 ◽  
Vol 16 (6) ◽  
pp. 645-646 ◽  
Author(s):  
S. K. Shadangi ◽  
S. C. Panda ◽  
S. Bhan
Keyword(s):  
Thermal Expansion ◽  
Intermetallic Compound ◽  
Least Squares ◽  
Temperature Interval ◽  
X Ray ◽  
Least Squares Fitting ◽  
Thermal Expansion Coefficients ◽  
Expansion Coefficients ◽  
Ray Methods

The lattice spacings of the intermetallic compound Ni3Zr have been measured by X-ray methods in the temperature interval 298–1033 K using a Debye–Scherrer camera. In all the cases the measured lattice spacings have been found to increase non-linearly with temperature and the dependence has been expressed by a polynomial of second degree from the least-squares fitting of the data. The thermal expansion coefficients for both parameters have been found to decrease with increase in temperature.

Determination of the melting temperature of spherical nanoparticles in dilute solution as a function of their radius by exclusively using the small-angle X-ray scattering technique

2020 ◽  
Vol 53 (2) ◽  
pp. 455-463
Author(s):  
Guinther Kellermann ◽  
Felipe L. C. Pereira ◽  
Aldo F. Craievich
Keyword(s):  
Thermal Expansion ◽  
Melting Temperature ◽  
Glass Matrix ◽  
X Ray ◽  
Thermal Expansion Coefficients ◽  
X Ray Scattering ◽  
Saxs Intensity ◽  
Expansion Coefficients ◽  
Bi Nanoparticles

In this investigation the dependence on radius of the melting temperature of dilute sets of spherical nanocrystals with wide radius distributions was determined by a novel procedure exclusively using the results of small-angle X-ray scattering (SAXS) measurements. This procedure is based on the sensitivity of the SAXS function to small and rather sharp variations in the size and electron density of nanocrystals at their melting temperature. The input for this procedure is a set of experimental SAXS intensity functions at selected q values for varying sample temperatures. In practice, the sample is heated from a minimum temperature, lower than the melting temperature of the smallest nanocrystals, up to a temperature higher than the melting temperature of the largest nanocrystals. The SAXS intensity is recorded in situ at different temperatures during the heating process. This novel procedure was applied to three samples composed of dilute sets of spherical Bi nanocrystals with wide radius distributions embedded in a sodium borate glass. The function relating the melting temperature of Bi nanocrystals with their radius – determined by using the procedure proposed here – agrees very well with the results reported in previous experimental studies using different methods. The results reported here also evidence the predicted size-dependent contraction of Bi nanocrystals induced by the large surface-to-volume ratio of small nanocrystals and an additional size-independent compressive stress caused by the solid glass matrix in which liquid Bi nanodroplets are initially formed. This last effect is a consequence of the increase in the volume of Bi nanoparticles upon crystallization and also of differences in the thermal expansion coefficients of the crystalline phase of Bi and the glass matrix. This additional stress leads to a depression of about 10 K in the melting temperature of the Bi nanocrystals confined in the glass. The procedure described here also allowed the determination of the specific masses and thermal expansion coefficients of Bi nanoparticles in both liquid and crystalline phases.

The crystal structure and thermal expansion of the CCl4 adduct of Dianin's compound

1990 ◽  
Vol 68 (8) ◽  
pp. 1352-1356 ◽  
Author(s):  
Walter Abriel ◽  
André Du Bois ◽  
Marek Zakrzewski ◽  
Mary Anne White
Keyword(s):  
Crystal Structure ◽  
Thermal Expansion ◽  
Powder Diffraction ◽  
Diffraction Data ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
X Ray ◽  
Thermal Expansion Coefficients ◽  
Expansion Coefficients ◽  
Dianin's Compound

The crystal structure of the title compound has been determined by single crystal X-ray diffraction data collected at 293 K, and refined to a final Rw of 0.057. The crystals are rhombohedral, space group [Formula: see text], with a = 27.134(8) Å, c = 10.933(2) Å, and Z = 18. The mole ratio of Dianin's compound (4-p-hydroxyphenyl-2,2,4-trimethylchroman) to CCl4 is 6:1. The guest molecules are disordered. X-ray powder diffraction was carried out in the temperature range from 10 to 300 K. From this, the thermal expansion coefficients for the a- and c-axes and the volume have been determined. Keywords: thermal expansion, crystal structure, clathrate.

Structure and Thermal Expansion Behavior of Dy2-xGdxMo4O15 Solid Solution

2008 ◽  
Vol 368-372 ◽  
pp. 1665-1667
Author(s):  
M.M. Wu ◽  
X.L. Xiao ◽  
Y.Z. Cheng ◽  
J. Peng ◽  
D.F. Chen ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solid Solution ◽  
Thermal Expansion ◽  
Monoclinic Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Thermal Expansion Coefficients ◽  
Expansion Behavior ◽  
Expansion Coefficients ◽  
Cell Volumes

A new series of solid solutions Dy2-xGdxMo4O15 (x = 0.0-0.9) were prepared. These compounds all crystallize in monoclinic structure with space group P21/c. The lattice parameters a, b, c and unit cell volumes V increase almost linearly with increasing gadolinium content. The intrinsic thermal expansion coefficients of Dy2-xGdxMo4O15 (x = 0.0 and 0.25) were obtained in the temperature range of 25 to 500°C with high-temperature X-ray diffraction. The correlation between thermal expansion and crystal structure was discussed.

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