Steric selectivity of the catalytic phosphorylation of phenols by aryl ?-polyfluoroalkylbenzyl chlorophosphates

1986 ◽  
Vol 35 (12) ◽  
pp. 2601-2601
Author(s):  
M. I. Kabachnik ◽  
L. S. Zakharov ◽  
P. V. Petrovskii ◽  
E. I. Goryunov
Keyword(s):  
Catalytic Phosphorylation ◽  
Steric Selectivity

ChemInform Abstract: PREPARATION OF O-(POLYFLUOROALKYL) ALKYLCHLOROPHOSPHONATES AND O-(POLYFLUOROALKYL) ARYL CHLOROPHOSPHATES BY CATALYTIC PHOSPHORYLATION OF POLYFLUOROALKANOLS

1979 ◽  
Vol 10 (38) ◽  
Author(s):  
M. I. KABACHNIK ◽  
L. S. ZAKHAROV ◽  
E. I. GORYUNOV ◽  
A. P. KHARCHENKO ◽  
V. F. ZABOLOTSKIKH ◽  
...  
Keyword(s):  
Catalytic Phosphorylation

Catalytic phosphorylation of polyfluoroalkanols. 15. Catalytic phosphorylation of ?-polyfluoroalkylbenzyl alcohols by bis(polyfluoroalkyl) chlorophosphates

1990 ◽  
Vol 39 (4) ◽  
pp. 787-795 ◽  
Author(s):  
E. I. Goryunov ◽  
P. V. Petrovskii ◽  
T. M. Shcherbina ◽  
A. P. Laretina ◽  
L. S. Zakharov ◽  
...  
Keyword(s):  
Catalytic Phosphorylation

scholarly journals Controlled steric selectivity in molecular doping towards closest-packed supramolecular conductors

2020 ◽  
Vol 1 (1) ◽  
Author(s):  
Shinya Kohno ◽  
Yu Yamashita ◽  
Naotaka Kasuya ◽  
Tsubasa Mikie ◽  
Itaru Osaka ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Steric Effects ◽  
Side Chain ◽  
Side Chains ◽  
Void Space ◽  
Alkyl Side Chains ◽  
Recent Developments ◽  
High Carrier ◽  
Molecular Doping ◽  
Steric Selectivity

Abstract Recent developments in molecular doping technologies allow extremely high carrier densities in polymeric semiconductors, exhibiting great diversity because of the unique size, conformation, and steric effect of molecular dopants. However, it is controversial how steric effects can limit the doping efficiency and to what extent dopants can be accommodated in polymers. Here, we employ two distinct conjugated polymers with different alkyl side-chain densities, where polymers are doped via anion-change, allowing greater variation in the incorporation of molecular dopants having different electrostatic potentials and shapes. We characterize the doping efficiency with regard to steric effects, considering the unique void space in the conjugated polymers. Our study reveals that doping efficiency of polymers with sparse alkyl side-chains is significantly greater than that with dense side-chains. A closest-packed supramolecule is realized with a particular combination of a sparse polymer and a large dopant, giving rise to high conductivity, air stability, and remarkably high work function. This work provides a critical insight into overcoming steric effects in molecular doping.

ChemInform Abstract: THE USE OF CATALYTIC PHOSPHORYLATION OF POLYFLUOROALKANOLS FOR PREPARATION OF POLYFLUOROALKYL ESTERS OF DIALKYL- AND DIARYLPHOSPHINIC ACIDS

1975 ◽  
Vol 6 (27) ◽  
pp. no-no
Author(s):  
L. S. ZAKHAROV ◽  
S. V. DOBROKHOTOVA ◽  
V. V. PISARENKO ◽  
N. N. GODOVIKOV ◽  
M. I. KABACHNIK
Keyword(s):  
Catalytic Phosphorylation

Synthesis of carborane-containing phosphates by catalytic phosphorylation

1995 ◽  
Vol 44 (1) ◽  
pp. 140-144 ◽  
Author(s):  
M. I. Kabachnik ◽  
L. S. Zakharov ◽  
E. L. Gefter ◽  
G. N. Molchanova ◽  
Yu. T. Struchkov ◽  
...  
Keyword(s):  
Catalytic Phosphorylation

ChemInform Abstract: Catalytic Phosphorylation of Polyfluoroalkanols. Part 16. Synthesis and Stereochemistry of O-(α-Polyfluoroalkylbenzyl) Phenylphosphonochloridates.

ChemInform ◽  
2010 ◽  
Vol 29 (52) ◽  
pp. no-no
Author(s):  
E. I. GORYUNOV ◽  
G. N. MOLCHANOVA ◽  
P. V. PETROVSKII ◽  
L. S. ZAKHAROV ◽  
M. I. KABACHNIK
Keyword(s):  
Catalytic Phosphorylation
Sign in / Sign up

Export Citation Format

Share Document