Gas-phase chemical kinetics of small metal clusters: developmen and characterization of a fast-flow reactor for neutral clusters

1993 ◽  
Vol 26 (S1) ◽  
pp. 168-170 ◽  
Author(s):  
L. Lian ◽  
F. Akhtar ◽  
J. M. Parsons ◽  
P. A. Hackett ◽  
D. M. Rayner
Keyword(s):  
Gas Phase ◽  
Chemical Kinetics ◽  
Metal Clusters ◽  
Flow Reactor ◽  
Fast Flow ◽  
Kinetics Of ◽  
Fast Flow Reactor ◽  
Phase Chemical

Gas phase chemical kinetics of sodium in the upper atmosphere

Nature ◽  
1976 ◽  
Vol 263 (5577) ◽  
pp. 488-490 ◽  
Author(s):  
C. E. KOLB ◽  
J. B. ELGIN
Keyword(s):  
Gas Phase ◽  
Chemical Kinetics ◽  
Upper Atmosphere ◽  
Kinetics Of ◽  
Phase Chemical

Tubular fast-flow reactor studies at high temperatures. Kinetics of the reaction

1974 ◽  
Vol 27 (3) ◽  
pp. 365-368 ◽  
Author(s):  
A. Fontijn ◽  
W. Felder ◽  
J.J. Houghton
Keyword(s):  
High Temperatures ◽  
Flow Reactor ◽  
Fast Flow ◽  
Kinetics Of ◽  
Fast Flow Reactor

Reaction Kinetics of Ground State Fluorine, F(2P), Atoms. I. Measurement of Fluorine Atom Concentrations and the Rates of Reactions F + CHF3 and F + Cl2 using Mass Spectrometry

1973 ◽  
Vol 51 (21) ◽  
pp. 3596-3604 ◽  
Author(s):  
Michael A. A. Clyne ◽  
Donald J. McKenney ◽  
Ronald. F. Walker
Keyword(s):  
Mass Spectrometry ◽  
Reaction Kinetics ◽  
Ground State ◽  
Fluorine Atom ◽  
Flow Reactor ◽  
Bimolecular Reaction ◽  
Inlet System ◽  
Fast Flow ◽  
Kinetics Of ◽  
Fast Flow Reactor

Reactions of F(2P) atoms generated by a 2.45 GHz discharge in dilute F2 + He mixtures have been studied mass spectrometrically with a beam inlet system from a fast flow reactor. F atom concentrations have been measured from the consumption of Cl2 in the simple and extremely rapid bimolecular reaction 1[Formula: see text]k1 was determined to be (1.1 ± 0.3) × 10−10 cm3 molecule−1 s−1 at 300 °K.Rate measurements for the reaction 2, which forms CF3 radicals, are reported, over the range 301 to 667 °K,[Formula: see text][Formula: see text]A less detailed survey of the rates at 298 °K of a series of reactions of F with H2, CH4, CH3Cl, CH2Cl2, and CHCl3, is also given; in these cases, the source of F was a discharge in CF4 + Ar, and [F] was measured by titration with ClNO.

Characterization of Carbon Ablation Models Including Effects of Gas-Phase Chemical Kinetics

2017 ◽  
Vol 31 (3) ◽  
pp. 512-526 ◽  
Author(s):  
Graham V. Candler ◽  
Christopher R. Alba ◽  
Robert B. Greendyke
Keyword(s):  
Gas Phase ◽  
Chemical Kinetics ◽  
Phase Chemical
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