Liquid properties of oligomers. Comparison of relaxational properties of propylene glycol oligomers with those of ethylene glycol oligomers

1986 ◽  
Vol 264 (7) ◽  
pp. 602-610 ◽  
Author(s):  
E. Ikada ◽  
M. Ashida
Keyword(s):  
Ethylene Glycol ◽  
Propylene Glycol ◽  
Glycol Oligomers

Hydrogenolysis of glucose and fructose in glycol solutions over CuO-MgO-ZrO2 catalyst

2020 ◽  
pp. 48-55
Author(s):  
M.E. Sharanda ◽  
◽  
E.A. Bondarenko ◽  
Keyword(s):  
Ethylene Glycol ◽  
Propylene Glycol ◽  
Flow Reactor ◽  
General Trend ◽  
Raw Materials ◽  
Reaction Products ◽  
Renewable Raw Materials ◽  
High Partial Pressure ◽  
Zro2 Catalyst ◽  
Phase Process

Ethylene glycol and propylene glycol are important representatives of polyols. On an industrial scale, they are obtained from petrochemical raw materials. Within a decade, significant efforts were made for the producing of polyols from biologically renewable raw materials - carbohydrates. The general trend for carbohydrate hydrogenolysis includes application of liquid-phase process with the use of modified metal-oxide catalysts, at 120-120 ° C and pressure of 3MPa or above. So high pressure is used for the reason to increase hydrogen solubility, and also due to the high partial pressure of low boiling solvents. We supposed that usage of high boiling solvents could allow hydrogenolysis to be performed at the lower pressure. Ethylene glycol and propylene glycol are of particular interest as such kind of solvent since they are both the main products of glucose hydrogenolysis. In this work, the process of hydrogenolysis of glucose and fructose over Cu / MgO-ZrO2 catalyst have been studied at temperature range of 160-200 °C and a pressure of 0.1-0.3 MPa in a flow reactor. The solvents were simultaneously the target products of the reaction - ethylene glycol and / or propylene glycol. Gas chromatography and 13C NMR were used for the reaction products identification. It was found that the solubility of glucose in propylene glycol is 21 % by weight, and in ethylene glycol 62% by weight. It was pointed out that the process of hydrogenolysis can take place at a pressure close to atmospheric. Under these conditions, the conversion of hexoses reaches 96-100 %. The reaction products are preferably propylene glycol and ethylene glycol. The total selectivity for C3-2 polyols is 90-94 %, that is higher than in the hydrogenolysis of glucose in aqueous solution.

Determination of Small Amounts of 1,2-Propylene Glycol in Ethylene Glycol

1952 ◽  
Vol 24 (6) ◽  
pp. 1053-1055 ◽  
Author(s):  
W. A. Cannon ◽  
L. C. Jackson
Keyword(s):  
Ethylene Glycol ◽  
Propylene Glycol

Efficient bimetallic NiCu-SiO2 catalysts for selective hydrogenolysis of xylitol to ethylene glycol and propylene glycol

2018 ◽  
Vol 220 ◽  
pp. 251-263 ◽  
Author(s):  
Hailong Liu ◽  
Zhiwei Huang ◽  
Haixiao Kang ◽  
Xuemei Li ◽  
Chungu Xia ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Propylene Glycol ◽  
Selective Hydrogenolysis

Betaine + (Glycerol or Ethylene Glycol or Propylene Glycol) Deep Eutectic Solvents for Extractive Purification of Gasoline

2018 ◽  
Vol 3 (44) ◽  
pp. 12582-12590 ◽  
Author(s):  
Kristina Zagajski Kučan ◽  
Marijana Perković ◽  
Karlo Cmrk ◽  
Dominik Načinović ◽  
Marko Rogošić
Keyword(s):  
Ethylene Glycol ◽  
Propylene Glycol ◽  
Deep Eutectic Solvents

A chitosan/poly(ethylene glycol)-ran-poly(propylene glycol) blend as an eco-benign separator and binder for quasi-solid-state supercapacitor applications

2019 ◽  
Vol 3 (3) ◽  
pp. 760-773 ◽  
Author(s):  
M. Raja ◽  
Balaji Sadhasivam ◽  
Janraj Naik R ◽  
Dhamodharan R ◽  
Kothandaraman Ramanujam
Keyword(s):  
Activated Carbon ◽  
Solid State ◽  
Ethylene Glycol ◽  
Propylene Glycol ◽  
Tamarindus Indica ◽  
Poly Ethylene Glycol ◽  
Active Electrode ◽  
Poly Ethylene ◽  
Poly Propylene ◽  
Supercapacitor Applications

In this study chitosan/poly(ethylene glycol)-ran-poly(propylene glycol) blend was developed as separator and binder for supercapacitor (SC) applications. The activated carbon (ACTS-900) derived fromTamarindus indicaseeds is used as active electrode material.

scholarly journals Suitability of base liquid in a nanofluid-laden solar flat-plate collector with emphasize on bioglycol

2018 ◽  
Vol 225 ◽  
pp. 04014
Author(s):  
Seyed Reza Shamshirgaran ◽  
Hussain H. Al-Kayiem ◽  
Morteza K. Assadi ◽  
K.V. Sharma
Keyword(s):  
Ethylene Glycol ◽  
Flat Plate ◽  
Propylene Glycol ◽  
Energetic Efficiency ◽  
Water Mixture ◽  
Safe Product ◽  
The Stability ◽  
Flat Plate Collector ◽  
Matlab Programming ◽  
Base Liquid

Ethylene glycol and propylene glycol are commonly used as thermal liquids in solar flat-plate collectors (FPCs). They are utilized as base liquid as well as for improving the stability of nanofluids in FPCs. The objective of the present paper is to introduce a renewable-derived bio glycol for use as base liquid in FPCs. The effect of base ratio (BR) of different glycol products on the performance of a conventional FPC and a nanofluidladen FPC is investigated in this paper to determine its suitability. MATLAB programming was employed for modeling the performance of the FPC operating with copper and cerium oxide nanomaterials. The results show that 20:80 bio glycol/water mixture is capable of enhancing the FPC’s energetic efficiency up to 72.1% which is higher than with either ethylene glycol and propylene glycol. The energy efficiency of a glycol-based nanofluid-filled FPC decreases with the base ratio of all three glycol products. Since bio glycol is a non-toxic and safe product, it can be utilized as a safe and environmentally-friend antifreeze and base liquid in nanofluid-filled FPCs.

scholarly journals Self-propagating High-temperature Synthesis of Materials Based on Tungsten Carbide for One-Pot Hydrolysis-Hydrogenolysis of Cellulose Into Ethylene Glycol and 1,2-Propylene Glycol

2019 ◽  
pp. 269-281
Author(s):  
Nikolay V. Gromov ◽  
Тatiana B. Medvedeva ◽  
Ivan А. Lukoyanov ◽  
Alekasandr А. Zhdanok ◽  
Vladimir А. Poluboyarov ◽  
...  
Keyword(s):  
High Temperature ◽  
Ethylene Glycol ◽  
Tungsten Carbide ◽  
Propylene Glycol ◽  
Reaction Rate ◽  
Total Yield ◽  
Temperature Synthesis ◽  
One Pot ◽  
Catalytic Systems ◽  
High Temperature Synthesis

Catalytic systems based on tungsten carbide (WnC) containing mainly W2C were obtained by the method of self-propagating high-temperature synthesis from a mechanochemically activated mixture of tungsten oxide, metallic magnesium, carbon black and CaCO3. The phase composition of the formed materials was shown to depend on the amount of CaCO3. The catalytic properties of the materials were tested in the hydrolysis-hydrogenation of cellulose to ethylene glycol (EG) and 1,2-propylene glycol (PG). It was established that in the presence of WnC the main products of the reaction were EG and PG with a ratio of PG/EG – 1.5-1.8. The deposition of nickel nanoparticles on the WnC surface increased the reaction rate and product yields. The maximum total yield of diols was 47.1 mol. %.

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