Rhodium phosphine complexes as homogeneous catalysts, part 5. Hydrogenation catalysts with low phosphorous: Rhodium ratio

1978 ◽  
Vol 3 (1) ◽  
pp. 123-124 ◽  
Author(s):  
Zsuzsa Nagy-Magos ◽  
S�ndor Vastag ◽  
B�lint Heil ◽  
L�szlb Mark�
1975 ◽  
Vol 3 (4) ◽  
pp. 361-369 ◽  
Author(s):  
V. L. Kuznetsov ◽  
M. R. MacLaury ◽  
B. N. Kuznetsov ◽  
J. P. Collman ◽  
Yu. I. Yermakov

1977 ◽  
Vol 2 (1) ◽  
pp. 58-59 ◽  
Author(s):  
Sándor Vastag ◽  
Bálint Heil ◽  
Szilárd Tőrös ◽  
László Markó

1984 ◽  
Vol 22 (3) ◽  
pp. 283-287 ◽  
Author(s):  
Sándor Vastag ◽  
József Bakos ◽  
Szilárd Tórös ◽  
Nicholas E. Takach ◽  
R. Bruce King ◽  
...  

1972 ◽  
Vol 50 (22) ◽  
pp. 3714-3718 ◽  
Author(s):  
David G. Holah ◽  
Alan N. Hughes ◽  
Benjamin C. Hui

Reactions between rhodium(III) chloride hydrate and certain phospholes are described; these result in the formation of both Rh (III) and Rh (I) complexes. The phospholes also react with Rh (I) carbonyl and ethylene complexes. The products of these reactions were investigated as homogeneous catalysts in the hydrogenation of 1-hexene, and some show relative rates of hydrogenation comparable with that of hydridocarbonyltris(triphenylphosphine)rhodium(I) but slower than that of tris(triphenylphosphine)rhodium (I) chloride.


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