Synthesis and characterization of rhodium(III), iridium(III), ruthenium(III) and osmium(III) complexes containing sterically hindered heterocyclic ligands

1978 ◽  
Vol 3 (1) ◽  
pp. 17-25 ◽  
Author(s):  
Carlo Preti ◽  
Giuseppe Tosi
2003 ◽  
Vol 11 (6) ◽  
pp. 471-475 ◽  
Author(s):  
Yun-Hi Kim ◽  
Hyun-Ouk Lee ◽  
Ki-Suk Lee ◽  
Soon-Ki Kwon

2006 ◽  
Vol 359 (13) ◽  
pp. 4326-4334 ◽  
Author(s):  
Cornelia Vetter ◽  
Christoph Wagner ◽  
Jürgen Schmidt ◽  
Dirk Steinborn

2016 ◽  
Vol 15 (2) ◽  
pp. 190-199 ◽  
Author(s):  
Jozef Miklovič ◽  
Dušan Valigura ◽  
Ingrid Svoboda ◽  
Ján Moncol ◽  
Milan Mazúr

Abstract The synthesis and characterization of nine new copper(II) complexes [Cu(2-Clnic)2L2] (where 2-Clnic is 2-chloronicotinate anion, L is imidazole – Im, benzimidazole – Bim, furo[3,2-c]pyridine – FP, 2-methylfuro[3,2-c]pyridine – MFP, or [1]benzofuro[3,2-c]pyridine – BFP), [Cu(2-Clnic)2(INA)] (where INA is isonicotinamide), [Cu(2-Clnic)2(4-py)]·H2O (where 4-py is 4-methylpyridine) and [Cu2(2-Clnic)4(IQ)2] (where IQ is isoquinoline) are reported. The characterizations were based on elemental analysis, infrared, electronic and EPR spectra. The dimeric character of [Cu2(2-Clnic)4(IQ)2] is assumed on the EPR spectrum and the other spectral methods. The crystal structure of the [Cu(2-Clnic)2(Bim)2] and [Cu(2-Clnic)2(FP)2] complexes have been determined by X-ray crystal structure analysis. Both complexes exhibit the hexacoordination coordination polyhedra around copper atom that lies in the crystallographic center of symmetry. The distorted tetragonal-bipyramidal (4+2) arrangement is in good agreement with spectral data that have suggested an asymmetric chelate coordination of the carboxylic group.


1999 ◽  
Vol 18 (3) ◽  
pp. 404-412 ◽  
Author(s):  
Brian J. Grimmond ◽  
Joyce Y. Corey ◽  
Nigam P. Rath

2007 ◽  
Vol 360 (10) ◽  
pp. 3335-3340 ◽  
Author(s):  
David J. Harding ◽  
Phimphaka Harding ◽  
Harry Adams ◽  
Thawatchai Tuntulani

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