An oxovanadium(IV) complex containing a pentacoordinate Schiff-base ligand: synthesis and crystal and molecular structure of N,N?-(3,3?-dipropylamine)bis (3-methoxysalicylideneiminato)oxovanadium(IV) dihydrate

1985 ◽  
Vol 15 (1) ◽  
pp. 29-38 ◽  
Author(s):  
Elmer C. Alyea ◽  
Terence D. Dee ◽  
George Ferguson
Keyword(s):  
Molecular Structure ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Crystal And Molecular Structure ◽  
Ligand Synthesis

scholarly journals Structural Characterization of Heterodinuclear ZnII-LnIII Complexes (Ln = Pr, Nd) with a Ring-Contracted H2valdien-Derived Schiff Base Ligand

2021 ◽  
Author(s):  
Shabana Noor ◽  
Richard Goddard ◽  
Fehmeeda Khatoon ◽  
Sarvendra Kumar ◽  
Rüdiger W. Seidel
Keyword(s):  
Molecular Structure ◽  
Schiff Base ◽  
Structural Characterization ◽  
Schiff Base Ligand ◽  
Crystal And Molecular Structure ◽  
X Ray ◽  
X Ray Crystallography ◽  
Imidazoline Ring

AbstractSynthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes with the formula [ZnLn(HL)(µ-OAc)(NO3)2(H2O)x(MeOH)1-x]NO3 · n H2O · n MeOH [Ln = Pr (1), Nd (2)] and the crystal and molecular structure of [ZnNd(HL)(µ-OAc)(NO3)2(H2O)] [ZnNd(HL)(OAc)(NO3)2(H2O)](NO3)2 · n H2O · n MeOH (3) are reported. The asymmetrical compartmental ligand (E)-2-(1-(2-((2-hydroxy-3-methoxybenzylidene)amino)-ethyl)imidazolidin-2-yl)-6-methoxyphenol (H2L) is formed from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation, resulting in a peripheral imidazoline ring. The structures of 1–3 were revealed by X-ray crystallography. The smaller ZnII ion occupies the inner N2O2 compartment of the ligand, whereas the larger and more oxophilic LnIII ions are found in the outer O2O2’ site. Graphic Abstract Synthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes (Ln = Pr, Nd) bearing an asymmetrical compartmental ligand formed in situ from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation are reported.

scholarly journals Interactions of Trivalent Lanthanide Cations with a New Hexadentate Di-Schiff Base: New Lanthanide(III) Complexes from (NE,N′E)-2,2′-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)

2010 ◽  
Vol 2010 ◽  
pp. 1-7 ◽  
Author(s):  
Mantha Tsiouri ◽  
Konstantina Skorda ◽  
Christos Papadimitriou ◽  
Yang Li ◽  
J. Derek Woollins ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Direct Reaction ◽  
The Novel ◽  
Trivalent Lanthanide ◽  
Lanthanide Cations ◽  
Oxygen Atoms

The novel lanthanide(III) complexes[Ln(NO3)2L](NO3)⋅3MeOH (Ln = La1, Pr2) and[Ln(NO3)3L](NO3)⋅2MeOH (Ln = Gd3, Yb4), where L = (NE,N′E)-2,2′-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine), have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol. All complexes were characterized spectroscopically and thermogravimetrically. Complex4was also characterized with crystallographic studies: orthorhombic P212121,a=10.6683(14),b=13.4752(15),c=19.3320(26) Å. In the molecular structure of4, Yb(III) is surrounded by all donor atoms of the Schiff base (four nitrogen and two oxygen atoms) and four oxygen atoms belonging to two bidentate chelating nitrato ligands.

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