The viscosity of heavy water at high pressures in the 100?275�C temperature range

1971 ◽  
Vol 30 (6) ◽  
pp. 655-656 ◽  
Author(s):  
N. A. Agaev ◽  
A. M. Kerimov ◽  
Azad Abas-Zade
Keyword(s):  
Heavy Water ◽  
High Pressures ◽  
Temperature Range

ChemInform Abstract: VISCOSITY OF HEAVY WATER AT HIGH PRESSURES

1978 ◽  
Vol 9 (16) ◽  
Author(s):  
H. KINOSHITA ◽  
S. ABE ◽  
A. NAGASHIMA
Keyword(s):  
Heavy Water ◽  
High Pressures

scholarly journals Effect of Temperature, Pressure, and Chemical Composition on the Electrical Conductivity of Schist: Implications for Electrical Structures under the Tibetan Plateau

Materials ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 961 ◽  
Author(s):  
Wenqing Sun ◽  
Lidong Dai ◽  
Heping Li ◽  
Haiying Hu ◽  
Changcai Liu ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
High Pressures ◽  
High Conductivity ◽  
Effect Of Temperature ◽  
The Tibetan Plateau ◽  
Temperature Range ◽  
Electrical Conductivities ◽  
Conductivity Anomalies ◽  
Lower Temperature Range ◽  
Lower Temperature

The experimental study on the electrical conductivities of schists with various contents of alkali ions (CA = K2O + Na2O = 3.94, 5.17, and 5.78 wt.%) were performed at high temperatures (623–1073 K) and high pressures (0.5–2.5 GPa). Experimental results indicated that the conductivities of schist markedly increased with the rise of temperature. Pressure influence on the conductivities of schist was extremely weak at the entire range of experimental temperatures. Alkali ion content has a significant influence on the conductivities of the schist samples in a lower temperature range (623–773 K), and the influence gradually decreases with increasing temperature in a higher temperature range (823–1073 K). In addition, the activation enthalpies for the conductivities of three schist samples were fitted as being 44.16–61.44 kJ/mol. Based on the activation enthalpies and previous studies, impurity alkaline ions (K+ and Na+) were proposed as the charge carriers of schist. Furthermore, electrical conductivities of schist (10−3.5–10−1.5 S/m) were lower than those of high-conductivity layers under the Tibetan Plateau (10−1–100 S/m). It was implied that the presence of schist cannot cause the high-conductivity anomalies in the middle to lower crust beneath the Tibetan Plateau.

scholarly journals Thermophysical Properties of 1-Butanol at High Pressures

Energies ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 5046
Author(s):  
Marzena Dzida
Keyword(s):  
Speed Of Sound ◽  
Thermophysical Properties ◽  
High Pressures ◽  
Fuel Additive ◽  
Temperature Range ◽  
Isobaric Thermal Expansion ◽  
Isentropic And Isothermal Compressibilities ◽  
Overlap Method ◽  
Pulse Echo ◽  
Better Than

1-Butanol can be considered as a good fuel additive, which can be used at high pressures. Therefore, the knowledge of high-pressure thermophysical properties is crucial for this application. In this paper, new experimental data on the speed of sound in 1-butanol in the temperature range from 293 to 318 K and at pressures up to 101 MPa are reported. The speed of sound at a frequency of 2 MHz was measured at atmospheric and high pressures using two measuring sets operating on the principle of the pulse–echo–overlap method. The measurement uncertainties were estimated to be better than ±0.5 m·s−1 and ± 1 m·s−1 at atmospheric and high pressures, respectively. Additionally, the density was measured under atmospheric pressure in the temperature range from 293 to 318 K using a vibrating tube densimeter Anton Paar DMA 5000. Using the experimental results, the density and isobaric and isochoric heat capacities, isentropic and isothermal compressibilities, isobaric thermal expansion, and internal pressure were calculated at temperatures from 293 to 318 K and at pressures up to 100 MPa.

The sorption of krypton and xenon in zeolites at high pressures and temperatures I. Chabazite

1972 ◽  
Vol 326 (1566) ◽  
pp. 315-330 ◽  
Keyword(s):  
Gas Phase ◽  
Thermodynamic Equilibrium ◽  
High Pressures ◽  
Equilibrium Constants ◽  
Standard State ◽  
Temperature Range ◽  
Thermodynamic Relationship ◽  
High Pressures And Temperatures

Isotherms of Kr and Xe in chabazite have been obtained for absolute sorption and for Gibbs excess sorption, in the temperature range 150 to 450 °C and at pressures up to 100 atm. Thermodynamic equilibrium constants for distribution of gas between the crystals and the gas phase, standard state concentrations and heats of sorption have been determined. At the highest pressures differences between absolute sorption and Gibbs excess sorption were large. The change of equilibrium fugacity with temperature for given absolute and Gibbs excess sorptions yielded two differential heats of sorption and two differential entropies of the sorbate. These heats, and the corresponding entropies, differed numerically and in their dependence upon amount sorbed. The thermodynamic relationship between the two heats has been derived and discussed.

THE KINETICS OF THE THERMAL DECOMPOSITIONS OF THE LOWER PARAFFINS: V. THE NITRIC OXIDE INHIBITED DECOMPOSITION OF n-BUTANE

1940 ◽  
Vol 18b (1) ◽  
pp. 1-11 ◽  
Author(s):  
E. W. R. Steacie ◽  
H. O. Folkins
Keyword(s):  
Nitric Oxide ◽  
Thermal Decomposition ◽  
Free Radical ◽  
High Pressures ◽  
Free Radical Processes ◽  
Temperature Range ◽  
Radical Recombination ◽  
Radical Processes ◽  
Kinetics Of ◽  
Good Agreement

A detailed investigation of the inhibition by nitric oxide of the thermal decomposition of n-butane has been carried out over the temperature range 500° to 550 °C.In all cases it was found that inhibition decreased with increasing butane concentration. This suggests that radical recombination occurs in the normal decomposition by ternary collisions with butane molecules acting as third bodies.The activation energies of the normal and inhibited reactions have been determined. For high pressures the two values are in good agreement, viz., 58,200 and 57,200 cal. per mole respectively. The products of the inhibited reaction were also found to be the same as those of the normal reaction.It is concluded that free radical processes predominate, involving comparatively short chains.

The ionization constant of heavy water (D2O) in the temperature range 298 to 523 K

1976 ◽  
Vol 54 (22) ◽  
pp. 3553-3558 ◽  
Author(s):  
David William Shoesmith ◽  
Woon Lee
Keyword(s):  
Heat Capacity ◽  
Free Energy ◽  
Heavy Water ◽  
Electrolyte Concentration ◽  
Aqueous Electrolyte ◽  
Ionization Constant ◽  
Standard Free Energy ◽  
Concentration Cell ◽  
Temperature Range

The ionization constant of liquid D2O has been measured over the temperature range 298 to 523 K using an aqueous electrolyte concentration cell. Values for the standard free energy, enthalpy, entropy, and heat capacity of ionization have been calculated. The results are compared to similar results for liquid H2O

FIRST SOUND IN LIQUID HELIUM AT HIGH PRESSURES

1953 ◽  
Vol 31 (7) ◽  
pp. 1156-1164 ◽  
Author(s):  
K. R. Atkins ◽  
R. A. Stasior
Keyword(s):  
Specific Heat ◽  
Liquid Helium ◽  
Carrier Frequency ◽  
High Pressures ◽  
Constant Pressure ◽  
Constant Density ◽  
Pulse Technique ◽  
Temperature Range ◽  
Specific Heats ◽  
First Sound

The velocity of ordinary sound in liquid helium has been measured in the temperature range from 1.2 °K. to 4.2 °K. at pressures up to 69 atm. A pulse technique was used with a carrier frequency of 12 Mc.p.s. Curves are given for the variation of velocity with temperature at constant pressure and also at constant density. There is no detectable discontinuity along the λ-curve. The results are used to discuss the ratio of the specific heats, the coefficient of expansion below 0.6 °K., and the specific heat above 3 °K.

Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures

2014 ◽  
Vol 141 (1) ◽  
pp. 014501 ◽  
Author(s):  
Zhe Wang ◽  
Kao-Hsiang Liu ◽  
Leland Harriger ◽  
Juscelino B. Leão ◽  
Sow-Hsin Chen
Keyword(s):  
Heavy Water ◽  
High Pressures ◽  
High Density ◽  
Low Density
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