Nucleophilic rearrangement with 1,2-halide migration

1968 ◽  
Vol 17 (8) ◽  
pp. 1837-1837
Author(s):  
O. A. Reutov ◽  
A. S. Gudkova ◽  
G. M. Ostapchuk ◽  
V. G. Akimova
Keyword(s):  
Nucleophilic Rearrangement

Nucleophilic rearrangement with 1,2-migration of a hydroxyl group

1969 ◽  
Vol 18 (10) ◽  
pp. 2195-2195 ◽  
Author(s):  
O. A. Reutov ◽  
A. S. Gudkova ◽  
G. M. Ostapchuk ◽  
G. P. Kulikova
Keyword(s):  
Hydroxyl Group ◽  
Nucleophilic Rearrangement

New nucleophilic rearrangement in the mechanism of the three-component domino cyclisation affording fluoroalkylated (pyrrolo)quinazolines

2014 ◽  
Vol 157 ◽  
pp. 1-11 ◽  
Author(s):  
Oldřich Paleta ◽  
Bohumil Dolenský ◽  
Jiří Paleček ◽  
Jaroslav Kvíčala
Keyword(s):  
Nucleophilic Rearrangement

Unusual Strain-Releasing Nucleophilic Rearrangement of a Bicyclo[2.2.1]heptane System to a Cyclohexenyl Derivative

2012 ◽  
Vol 77 (21) ◽  
pp. 9747-9755 ◽  
Author(s):  
Mansoureh Karimiahmadabadi ◽  
Andras Földesi ◽  
Jyoti Chattopadhyaya
Keyword(s):  
Nucleophilic Rearrangement ◽  
Unusual Strain

ChemInform Abstract: Nucleophilic Rearrangement of Functionally-Substituted 2-Ethylpyridines.

ChemInform ◽  
2010 ◽  
Vol 32 (29) ◽  
pp. no-no
Author(s):  
V. I. Terenin ◽  
O. A. Maloshitskaya
Keyword(s):  
Nucleophilic Rearrangement

Enantioselective Preparation of Alcohols and Amines: The Lam Synthesis of (+)-Tanikolide

2013 ◽  
Author(s):  
Douglass F. Taber
Keyword(s):  
Amino Acids ◽  
Conjugate Addition ◽  
Allylic Alcohol ◽  
University Of Virginia ◽  
Chiral Amine ◽  
Aliphatic Aldehydes ◽  
Nucleophilic Rearrangement ◽  
Silyl Acetals ◽  
Institute Of Technology ◽  
The University

Takashi Ooi of Nagoya University effected (J. Am. Chem. Soc. 2010, 132, 12240) the enantioselective protonation of ketene silyl acetals such as 1 to give 2 in high ee. Hyeon-Kyu Lee of the Korean Research Institute of Chemical Technology achieved (Org. Lett. 2010, 12, 4184) high ee in the hydrogenation of the cyclic sulfamidate 3 to 4. Doo Ok Jang of Yonsei University combined (J. Am. Chem. Soc. 2010, 132, 12168) the nucleophilic allyl indium with a protonated chiral amine to effect homologation of 5 to 6. Ryo Shintani and Tamio Hayashi of Kyoto University reported (Org. Lett. 2010, 12, 4106) a related advance with tetraarylborates. Kazuaki Ishihara, also of Nagoya University (Org. Lett. 2010, 12, 3502) and Yoshihiro Sohtome and Kazuo Nagasawa of the Tokyo University of Agriculture and Technology (Angew. Chem. Int. Ed. 2010, 49, 9254) devised conditions for adding malonate to imines such as 7. Professors Shintani and Hayashi also employed (J. Am. Chem. Soc. 2010, 132, 13168) tetraarylborates to convert 9 to the α-quaternary amine 10. Professor Ooi (Angew. Chem. Int. Ed. 2010, 49, 5567) and Wanbin Zhang of Shanghai Jiao Tong University (J. Am. Chem. Soc. 2010, 132, 15939) prepared α-quaternary amino acids such as 12 by nucleophilic rearrangement of 11. Keiji Maruoka, also of Kyoto University, reported (J. Am. Chem. Soc. 2010, 132, 17074; not illustrated) a catalytic enantioselective conjugate addition approach to α-quaternary amines. Shuji Akai of the University of Shizuoka converted (Org. Lett. 2010, 12, 4900) the racemic allylic alcohol 13 to the enantiomerically enriched acetate 14 by combining V-catalyzed equilibration with lipase-catalyzed acylation. Toshiro Harada of the Kyoto Institute of Technology added (Org. Lett. 2010, 12, 5270) the alkenylboron 16 to the aldehyde 15 with high ee. Xiang Zhou of Wuhan University and Lin Pu of the University of Virginia significantly improved (Tetrahedron Lett . 2010, 51, 5024) a protocol for the enantioselective addition of aliphatic alkynes to aliphatic aldehydes. For other enantioselective additions to aldehydes (not illustrated), see J. Org. Chem. 2010, 75 , 5326 and Org. Lett. 2010, 12, 5088.

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