Effect of laser surface melted zirconium alloys on microstructure and corrosion resistance

1992 ◽  
Vol 27 (9) ◽  
pp. 2437-2443 ◽  
Author(s):  
W. Reitz ◽  
J. Rawers
Keyword(s):  
Corrosion Resistance ◽  
Zirconium Alloys ◽  
Laser Surface

Development of Nano-Structured Aluminum Surfaces by LSM

2008 ◽  
Author(s):  
Taha Mattar ◽  
Ehab Abdel Rahman ◽  
Ahmed Abdel-Aziz ◽  
Haytham El-Gazzar
Keyword(s):  
Corrosion Resistance ◽  
Surface Layer ◽  
Surface Structure ◽  
Surface Melting ◽  
Laser Surface ◽  
Laser Surface Melting ◽  
Aluminum Surface ◽  
Yag Laser ◽  
Structured Surface ◽  
Aluminum Surfaces

Aluminum is one of most common metals in all advanced and modern scientific and technological applications including electrical, electronic, chemical, engineering, energy and medical fields. The performance of aluminum alloys determines to large extent the quality and economic status of the different processes. Aluminum surface structure determine its performance where nano sized grains and layer can improve aluminum properties and performance. In this work, the improvement of aluminum surface structure and formation of nano structured surface grains by laser surface melting (LSM) using Nd-YAG laser under argon atmosphere was investigated. Different power and scanning speed were applied. The physical and chemical properties of the produced surfaces were examined. SEM, EDX and XRD analyses were performed and were correlated to hardness results. Corrosion resistance of the treated surface was investigated to evaluate their performance in aggressive media and chemical and medical applications. From the obtained data it can be concluded that Nd-YAG laser surface melting of aluminum results in formation of 750 micron nano-structured surface layer. Adjustment of LSM parameters could produce 100 nm grains or less. The obtained results showed also that LSM under argon can eliminate the formation of Al2O3 surface layer which may deteriorates the performance in certain applications. Surface layer rich in AlN is formed upon LSM. It was concluded also that corrosion resistance of the treated aluminum surfaces was improved to large extent by LSM.

Effect of Bi Addition on the Corrosion Behavior of Zirconium Alloys

2013 ◽  
Author(s):  
M. Y. Yao ◽  
B. X. Zhou ◽  
Q. Li ◽  
W. P. Zhang ◽  
L. Zhu ◽  
...  
Keyword(s):  
Solid Solution ◽  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Mass Fraction ◽  
Zirconium Alloys ◽  
Deionized Water ◽  
Second Phase ◽  
Micro Structure ◽  
Second Phase Particles ◽  
Structure Observation

In order to investigate systematically the effect of Bi addition on the corrosion resistance of zirconium alloys, different zirconium-based alloys, including Zr-4 (Zr-1.5Sn-0.2Fe-0.1Cr), S5 (Zr-0.8Sn-0.35Nb-0.4Fe-0.1Cr), T5 (Zr-0.7Sn-1.0Nb-0.3Fe-0.1Cr) and Zr-1Nb, were adopted to prepare the zirconium alloys containing Bi of 0∼0.5% in mass fraction. These alloys were denoted as Zr-4+xBi, S5+xBi, T5+xBi and Zr-1Nb+xBi, respectively. The corrosion behavior of these specimens was investigated by autoclave testing in lithiated water with 0.01 M LiOH or deionized water at 360°C/18.6 MPa and in superheated steam at 400 °C/10.3 MPa. The micro structure of the alloys was examined by TEM and the second phase particles (SPPs) were analyzed by EDS. Micro structure observation shows that the addition of Bi promotes the precipitation of Sn as second phase particles (SPPs) because Sn is in solid solution in α-Zr matrix in Zr-4, S5 and T5 alloys. The concentration of Bi dissolved in α-Zr matrix increase with the increase of Nb in the alloys, and the excess Bi precipitates as Bi-containing SPPs. The corrosion results show that the effect of Bi addition on the corrosion behavior of different zirconium-based alloys is very complicated, depending on their compositions and corrosion conditions. In the case of higher Bi concentration in α-Zr, the zirconium alloys exhibit better corrosion resistance. However, in the case of precipitation of Bi-containing SPPs, the corrosion resistance gets worse. This indicates that the solid solution of Bi in α-Zr matrix can improve the corrosion resistance, while the precipitation of the Bi-containing SPPs is harmful to the corrosion resistance.

Effects of Laser Processing Parameters on Grain Boundary Character Distribution and Corrosion Resistance of Austenite Stainless Steel

2007 ◽  
Vol 561-565 ◽  
pp. 2473-2476 ◽  
Author(s):  
Sen Yang ◽  
Hiroyuki Kokawa ◽  
Zhan Jie Wang
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Laser Processing ◽  
Processing Parameters ◽  
Laser Surface ◽  
304 Stainless Steel ◽  
Grain Boundary Character Distribution ◽  
Grain Boundary Character ◽  
Laser Surface Remelting ◽  
Character Distribution

In order to modify grain boundary character distribution (GBCD) and to improve intergranualr corrosion (IGC) resistance of 304 stainless steel, laser surface remelting experiments were conducted on 304 stainless steel using a 2kW CW Nd: YAG laser, and the effects of laser processing parameters on GBCD and corrosion resistance were investigated in detail under the optimal annealing condition (1220K 28h). The experimental results showed that combination of laser surface remelting and the following annealing treatment could change the GBCD remarkably and improve the IGC resistance of 304 stainless steel. However, there are no obvious effects of laser processing parameters on the final depth of the processed zone, although the depth of the molten pool increases with the increase of the laser output power or the decrease of the scanning velocity, and the subsequent GBCD and corrosion resistance.

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