Catalytic activity of type Y zeolites in the hydrogenation of ethylene and butenes

Author(s):  
Kh. M. Minachev ◽  
Yu. S. Khodakov ◽  
B. M. Savchenko ◽  
V. K. Nesterov
1987 ◽  
Vol 52 (7) ◽  
pp. 1701-1707 ◽  
Author(s):  
Miloslav Křivánek ◽  
Nguyen Thiet Dung ◽  
Pavel Jírů

The catalytic activity of Na, H-Y zeolite samples with a varying Si/Al ratio (2·5 to 20) in the transformation of methanol was determined. The amounts of formed individual aliphatic hydrocarbons as function of reaction time were correlated with the amount of Bronsted and Lewis centres on the catalysts. The effect of coke formation on the over-all course of the reaction has been demonstrated.


Zeolites ◽  
1988 ◽  
Vol 8 (3) ◽  
pp. 228-231 ◽  
Author(s):  
David Keir ◽  
Edward F.T. Lee ◽  
Lovat V.C. Rees

1995 ◽  
Vol 60 (3) ◽  
pp. 428-442 ◽  
Author(s):  
Jana Nováková ◽  
Libor Brabec ◽  
Ludmila Kubelková

[Pt(NH3)4]2+ ions were exchanged for alkali (Li, Na, K and Cs) in -X and -Y zeolites and decomposed in vacuum. TPR after this decomposition showed that autoreduction accompanying this process reduced roughly 2/3 of all Pt2+ to Pt0. The extent of the autoreduction rose with the ammonia pressure over the zeolite. The decomposition rate increased with increasing electropositivity of the alkali ion and this effect completely overlapped that of the zeolite structure. The CO + NO reaction rate also increased from Li to Cs, but -X zeolites were substantially more active than the -Y ones. Oxygen layer on the resulting Pt catalyst affected positively the reaction rate. The dispersion of Pt particles was relatively low, when compared to that obtained by decomposition of the Pt tetraammine complex in oxygen followed by hydrogen reduction. However, the reaction rate was higher.


1987 ◽  
Vol 40 (1) ◽  
pp. 83-92 ◽  
Author(s):  
Takayuki Komatsu ◽  
Tatsuaki Yashima

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