scholarly journals Dissociation quotients of oxalic acid in aqueous sodium chloride media to 175�C

1991 ◽  
Vol 20 (9) ◽  
pp. 905-927 ◽  
Author(s):  
Richard M. Kettler ◽  
Donald A. Palmer ◽  
David J. Wesolowski
2021 ◽  
Vol 155 (4) ◽  
pp. 044703
Author(s):  
Alessandra Serva ◽  
Laura Scalfi ◽  
Benjamin Rotenberg ◽  
Mathieu Salanne

2015 ◽  
Vol 669 ◽  
pp. 150-157
Author(s):  
Peter Michal ◽  
Alena Vagaská ◽  
Miroslav Gombár

Paper tracks experimentally confirmed relationship between chemical composition of electrolyte and resulting surface finish quality of created oxide layer during the process of anodic oxidation of aluminium. Examined chemical factors were: concentrations of sulphuric acid, oxalic acid, boric acid and sodium chloride. Aggressive effects of electrolyte were chosen as indicator of resulting layer quality – presence and extent of etching of used substrate sample.


CORROSION ◽  
1969 ◽  
Vol 25 (8) ◽  
pp. 342-344 ◽  
Author(s):  
A. TIRMAN ◽  
E. G. HANEY ◽  
PAUL FUGASSI

Abstract The resistance to stress corrosion cracking of AISI 4340 steel foil in 0.6M aqueous sodium chloride, acidified to pH 1.5 with hydrochloric acid, is greatly decreased by prior treatment of the specimens for short periods of time with aqueous and nonaqueous solutions of sulfur, organic and inorganic sulfides, sulfur dioxides, and the inorganic salts of sulfurousand sulfuric acids. It is suggested that this prior treatment produces sulfided areas which are inhibitors of the combination of atomic hydrogen into molecular hydrogen. The decreased resistance to stress corrosion cracking is thus attributed to hydrogen embrittlement. If the stress corrosion cracking test is made in 0.6M aqueous sodium chloride, adjusted to an initial pH of 8, the effect of a prior sulfiding treatment is small. The formation of such sulfided areas in practice result from the exposure of 4340 steels to industrial atmospheres which may contain hydrogen sulfide, sulfur dioxide, and elemental sulfur.


1960 ◽  
Vol 38 (9) ◽  
pp. 1488-1494 ◽  
Author(s):  
E. J. Bounsall ◽  
W. A. E. McBryde

An analytical method is described for the determination of microgram amounts of silver in galena ores, based on the "reversion" of silver dithizonate. Silver is separated from relatively large amounts of lead by extraction as dithizonate into chloroform from an aqueous 1:99 nitric acid solution. Separation from mercury, which is also extracted under these conditions and would, if present, interfere in the analysis, is achieved by reverting the dithizonate solution with a 5% aqueous sodium chloride solution which is also 0.015 molar in hydrochloric acid. Following dilution of this aqueous solution and adjustment of pH, silver is again extracted into chloroform as the dithizonate, and determined absorptiometrically. Analyses of a number of galena ore samples showed a precision of within 3% for a silver content ranging from 0.03 to 0.4%.Some other methods for isolating silver from these samples, which were tried but found unsatisfactory, are discussed.


2017 ◽  
Vol 62 (3) ◽  
pp. 902-912 ◽  
Author(s):  
Jimin Xie ◽  
Min Liu ◽  
Guiqin Liu ◽  
Lixia Yuan ◽  
Dacheng Li ◽  
...  

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