Interphase surface effect in problems of mixing displacement of multicomponent systems

1987 ◽  
Vol 21 (4) ◽  
pp. 576-583 ◽  
Author(s):  
N. A. Guzhov ◽  
V. S. Mitlin
Keyword(s):  
Surface Effect ◽  
Interphase Surface ◽  
Multicomponent Systems

A standard for transmission electron spectroscopy

1978 ◽  
Vol 36 (1) ◽  
pp. 530-531 ◽  
Author(s):  
Dennis Maher ◽  
David Joy ◽  
Peggy Mochel
Keyword(s):  
Thin Films ◽  
Electron Spectroscopy ◽  
Host Lattice ◽  
Single Element ◽  
Multicomponent Systems ◽  
Transmission Electron ◽  
Major Interest ◽  
Standard Specimens ◽  
Forms Of Carbon ◽  
Electron Energy Loss

A variety of standard specimens is needed in order to systematically investigate the instrumentation, specimen, data reduction and quantitation variables in electron energy-loss spectroscopy (EELS). Pure single element specimens (e.g. various forms of carbon) have received considerable attention to date but certain elements of interest cannot be prepared directly as thin films. Since studies of the first and second row elements in two- or multicomponent systems will be of considerable importance in microanalysis using EELS, there is a need for convenient standards containing these species. For many investigations a standard should contain the desired element, or elements, homogeneously dispersed through a suitable matrix and at an accurately known concentration. These conditions may be met by the technique of implantation.Silicon was chosen as the host lattice since its principal ionization energies, EL23 = 98 eV and Ek = 1843 eV, are well removed from the K-edges of most elements of major interest such as boron (Ek = 188 eV), carbon (Ek = 283 eV), nitrogen (Ek = 400 eV) and oxygen (Ek = 532 eV).

The Effect of Pentosan Polysulphate (SP54) on the Fibrinolytic Enzyme System - A Human Volunteer and Experimental Animal Study

1985 ◽  
Vol 54 (04) ◽  
pp. 833-837 ◽  
Author(s):  
N A Marsh ◽  
P M Peyser ◽  
L J Creighton ◽  
M Mahmoud ◽  
P J Gaffney
Keyword(s):  
Plasminogen Activator ◽  
Surface Effect ◽  
Ex Vivo ◽  
Vena Cava ◽  
Tissue Type ◽  
Similar Response ◽  
Small Contribution ◽  
Thrombosis Model ◽  
Pentosan Polysulphate

SummaryPentosan polysulphate causes an increase in plasminogen activator activity in plasma both after oral ingestion and after subcutaneous injection. The effect is greatest after 3 h and has disappeared by 6 h. Repeat doses by mouth over 5 days elicit a similar response. The recorded increase in activity is due largely to the release of tissue-type plasminogen activator (tPA) from the endothelium according to the antigen assay although there could be a small contribution from Factor XH-related “intrinsic” fibrinolysis induced in vitro. SP54 enhances activity ex vivo by a non-specific surface effect, and this phenomenon may contribute the increased levels of activity seen in vitro. Administration of SP54 to animals elicits a similar increase in activator activity, the intramuscular route being slightly more effective. Results with an inferior vena cava thrombosis model in the rat suggest that pentosan polysulphate may induce a thrombolytic effect.

UJI TARIK HIDRODINAMIKMODEL KAPAL BERSAYAP WiSE DENGAN LAMBUNG DASAR BERSTEP

2013 ◽  
Vol 12 (3) ◽  
Author(s):  
Iskendar Iskendar ◽  
Andi Jamaludin ◽  
Paulus Indiyono
Keyword(s):  
Comparative Study ◽  
Model Test ◽  
Hydrodynamic Model ◽  
Surface Effect ◽  
Center Of Gravity ◽  
Test Results ◽  
Flat Bottom ◽  
Towing Tank ◽  
Test Models ◽  
Wetted Surface Area

This paper describes hydrodynamic model tests of Wing in Surface Effect (WiSE) Craft. These craft  was fitted with  stephull  form in different location on longitudinal flat bottom (stepedhull planning craft) to determine the influences of sticking and porpoising motion performances. These motions are usually occured when the craft start to take-off from water surfaces. The test models with scale of 1 : 7 were comprised of 4 (four) stephull models and 1 (one) non-stephull model  as a comparative study. The hydrodynamic  tests were performed with craft speed of 16 – 32 knots (prototype values) in Towing Tank at UPT. Balai Pengkajian dan Penelitian Hidrodinamika (BPPH), BPPT, Surabaya. The resistance (drag) was measured by dynamo meter and the trim of model (draft changing at fore and aft  of model due to model speed) was measured by trim meter. By knowing the value of model trim, the wetted surface area can be determined. Then, the lift forces were calculated based on these measured values. The model test results were presented on tables and curves.  Test results show that models  with step located far away from center of gravity of the WiSE craft tend to porpoising and sticking condition, except if the step location on the below of these center of gravity. While model without step tends to sticking conditions.

Competitive hydrogenation of olefinic substrates in multicomponent systems

1978 ◽  
Vol 43 (9) ◽  
pp. 2387-2394 ◽  
Author(s):  
Libor Červený ◽  
Dana Plecháčová ◽  
Vlastimil Růžička
Keyword(s):  
Multicomponent Systems ◽  
Competitive Hydrogenation

scholarly journals Applications of Supercritical Anti-Solvent Process in Preparation of Solid Multicomponent Systems

Pharmaceutics ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 475
Author(s):  
Guijin Liu ◽  
Junjian Li ◽  
Shiming Deng
Keyword(s):  
Solid State ◽  
Solid Dispersions ◽  
Crystal Form ◽  
Great Promise ◽  
Computational Techniques ◽  
Large Contribution ◽  
Continuous Manufacturing ◽  
Multicomponent Systems ◽  
On Line ◽  
Underlying Mechanisms

Solid multicomponent systems (SMS) are gaining an increasingly important role in the pharmaceutical industry, to improve the physicochemical properties of active pharmaceutical ingredients (APIs). In recent years, various processes have been employed for SMS manufacturing. Control of the particle solid-state properties, such as size, morphology, and crystal form is required to optimize the SMS formulation. By utilizing the unique and tunable properties of supercritical fluids, supercritical anti-solvent (SAS) process holds great promise for the manipulation of the solid-state properties of APIs. The SAS techniques have been developed from batch to continuous mode. Their applications in SMS preparation are summarized in this review. Many pharmaceutical co-crystals and solid dispersions have been successfully produced via the SAS process, where the solid-state properties of APIs can be well designed by controlling the operating parameters. The underlying mechanisms on the manipulation of solid-state properties are discussed, with the help of on-line monitoring and computational techniques. With continuous researching, SAS process will give a large contribution to the scalable and continuous manufacturing of desired SMS in the near future.

scholarly journals Operando surface science methodology reveals surface effect in charge storage electrodes

2020 ◽  
Author(s):  
Chao Wang ◽  
Yanxiao Ning ◽  
Haibo Huang ◽  
Shiwen Li ◽  
Chuanhai Xiao ◽  
...  
Keyword(s):  
Surface Science ◽  
Electrode Surface ◽  
Surface Effect ◽  
Specific Capacity ◽  
Surface Region ◽  
Charge Storage ◽  
Energy Storage Devices ◽  
Graphite Cathode ◽  
Surface And Interface ◽  
Science Methodology

Abstract Surface and interface play critical roles in energy storage devices, calling for operando characterization techniques to probe the electrified surfaces/interfaces. In this work, surface science methodology including electron spectroscopy and scanning probe microscopy has been successfully applied to visualize electrochemical processes at operating electrode surfaces in an Al/graphite model battery. Intercalation of anions together with cations is directly observed in surface region of the graphite electrode with tens of nanometers thickness, whose concentration is amazingly one order higher than that in bulk. An intercalation pseudocapacitance mechanism and a double specific capacity in the electrode surface region are expected based on the super-dense intercalants and anion/cation co-intercalation, which are in sharp contrast with the battery-like mechanism in the electrode bulk. The distinct electrochemical mechanism at electrode surface is well verified by performance tests of real battery devices, showing that surface-dominant nanometer thick graphite cathode outperforms bulk-dominant micrometer thick graphite cathode. Our findings highlight the important surface effect of working electrodes in charge storage systems.

scholarly journals Effect of Modification on the Fluid Diffusion Coefficient in Silica Nanochannels

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 4030
Author(s):  
Gengbiao Chen ◽  
Zhiwen Liu
Keyword(s):  
Diffusion Coefficient ◽  
Diffusion Coefficients ◽  
Surface Effect ◽  
Bulk Water ◽  
Self Diffusion ◽  
Average Diffusion Coefficient ◽  
Average Diffusion ◽  
Chain Lengths ◽  
Fluid Diffusion ◽  
Self Diffusion Coefficient

The diffusion behavior of fluid water in nanochannels with hydroxylation of silica gel and silanization of different modified chain lengths was simulated by the equilibrium molecular dynamics method. The diffusion coefficient of fluid water was calculated by the Einstein method and the Green–Kubo method, so as to analyze the change rule between the modification degree of nanochannels and the diffusion coefficient of fluid water. The results showed that the diffusion coefficient of fluid water increased with the length of the modified chain. The average diffusion coefficient of fluid water in the hydroxylated nanochannels was 8.01% of the bulk water diffusion coefficient, and the diffusion coefficients of fluid water in the –(CH2)3CH3, –(CH2)7CH3, and –(CH2)11CH3 nanochannels were 44.10%, 49.72%, and 53.80% of the diffusion coefficients of bulk water, respectively. In the above four wall characteristic models, the diffusion coefficients in the z direction were smaller than those in the other directions. However, with an increase in the silylation degree, the increased self-diffusion coefficient due to the surface effect could basically offset the decreased self-diffusion coefficient owing to the scale effect. In the four nanochannels, when the local diffusion coefficient of fluid water was in the range of 8 Å close to the wall, Dz was greater than Dxy, and beyond the range of 8 Å of the wall, the Dz was smaller than Dxy.

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