Ion pairing effect on the aquation k�netics of [Co(Py)4Cl2]X (X=Cl?, NO 3 ? , IO 4 ? , ClO 4 ? SCN? and N 3 ? ) in different solvent systems; basicity measurement of the counter ion

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Mechanochemistry is maturing as a discipline and continuing to grow, so it is important to continue understanding the rules governing the system. In a mechanochemical reaction, the reactants are added into a vessel along with one or more grinding balls and the vessel is shaken at high speeds to facilitate a chemical reaction. The dielectric constant of the solvent used in liquid-assisted grinding (LAG) and properly chosen counter-ion pairing increases the percentage conversion of stilbenes in a mechanochemical Wittig reaction. Utilizing stepwise addition/evaporation of ethanol in liquid-assisted grinding also allows for the tuning of the diastereoselectivity in the Wittig reaction.


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