Immobilization and nonspecific adsorption of proteins to pyrogeneous highly dispersed silicon dioxide

1987 ◽  
Vol 9 (8) ◽  
pp. 561-566 ◽  
Author(s):  
M. Fusek ◽  
M. Čapka ◽  
J. Turková
2021 ◽  
Vol 2 (446) ◽  
pp. 36-44
Author(s):  
А.О. Zhapekova ◽  
N.N. Mofa ◽  
B. Elouadi ◽  
R.S. Iminova ◽  
А.Е. Bakkara ◽  
...  

In this work, the preparation of colloidal systems with microcrystalline cellulose as a gelling agent and silica powder as a filler was considered. By mechanochemical and ultrasonic treatment of a filler made of silicon dioxide and a colloidal base, varying the constituent ingredients, one can purposefully influence the structure of the system and regulate the properties of the resulting compositions. It is shown that the introduction of a filler made of highly dispersed silicon dioxide into a gel system based on cellulose, modified by ultrasonic treatment (UST) with acid additives, provides both acceleration of the gelation process and stabilization of the state of the obtained colloidal composition. As a result of UST, a nanostructured colloidal homogeneous system is formed.


2014 ◽  
Vol 521 ◽  
pp. 576-580
Author(s):  
Hai Bin Yang ◽  
Wei Rao

Mesoporous titanium dioxide/graphitic carbon microspheres were synthesized by a simple nanocasting route using monodisperse silicon dioxide microspheres as the template. The characterize and the morphology of the titanium dioxide/graphitic carbon microspheres have been analyzed by means of XRD, N2-sorption, SEM, TEM, TG-DTA and EDAX. Indicated by the experimental results and the theoretical analysis, the anatase titanium dioxide nanoparticles of 8-14 nm in diameter were highly dispersed in the graphitic carbon microspheres. The obtained material can be used as catalyst or battery material. Key words: titanium dioxide/graphitic carbon; Microspheres; Nanocasting route;Mesoporous


1993 ◽  
Vol 39 (9) ◽  
pp. 902-905 ◽  
Author(s):  
A. S. Gordienko ◽  
I. V. Zbanatskaya ◽  
I. K. Kurdish

The addition of highly dispersed silicon dioxide to a suspension of Methylomonas rubra cells under defined conditions resulted in an increasing negative charge in the cells. This phenomenon is not explained in terms of the known conceptions of adsorption processes, in spite of the fact that it is probably a consequence of the contact interaction between cells and silicon dioxide particles.Key words: contact interaction, electrosurface property, silicon dioxide, Methylomonas rubra.


2020 ◽  
Vol 64 (10) ◽  
pp. 63-67
Author(s):  
Alexander A. Kimyashov ◽  
◽  
Alexander V. Syromolotov ◽  
Maksim O. Pavlov ◽  
◽  
...  

The enterosorbent "Polysorb" is a highly dispersed powder of silicon dioxide. In medicine, it is used as a detoxifier for poisoning with organic substances and heavy metals. Recently, the direction in pharmaceuticals related to targeted delivery of medicines has begun to develop. One of the carriers of medicinal substances is highly dispersed silicon dioxide. There are explorations that show that with simultaneous oral administration of highly dispersed silicon dioxide and the antibiotic amphotericin, the concentration of the latter in the blood increases significantly. Recently, there have been studies showing that delivering propionic acid to the gut reduces fat accumulation in overweight people. The goal of this work is study the adsorption of aliphatic carboxylic acids, namely: formic, acetic, propionic on the surface of polysorb. Using electron microscopy, it was shown that polysorb powder consists of particles of different sizes and shapes. Their size varies from units to tens of micrometers. Adsorption isotherms of formic, acetic, and propionic acids were constructed at a temperature of 295 K. It is shown that they have an S-shaped character, therefore, adsorption is due to the formation of hydrogen bonds between the silanol groups of the hydrated POLYSORB and the carboxyl groups of acids. It is established that these isotherms are adequately described by the Freundlich model up to the saturation region. With an increase in the hydrocarbon radical, the adsorption capacity of acids decreases. The kinetics of acid adsorption on the polysorb surface was described using pseudo-first and pseudo-second order models. It was found that the adsorption kinetics of carboxylic acids is adequately described by the pseudo-first-order model. The time of onset of adsorption equilibrium is 30 seconds at a temperature of 295 K.


2020 ◽  
Vol 10 (16) ◽  
pp. 5525-5534 ◽  
Author(s):  
Jialiang Gu ◽  
Bingjun Zhu ◽  
Rudi Duan ◽  
Yan Chen ◽  
Shaoxin Wang ◽  
...  

MnOx–FeOx-Loaded silicalite-1 catalysts exhibit high NOx conversion at low temperatures.


Author(s):  
Yaru Li ◽  
Yu-Quan Zhu ◽  
Weili Xin ◽  
Song Hong ◽  
Xiaoying Zhao ◽  
...  

Rationally designing low-content and high-efficiency noble metal nanodots offers opportunities to enhance electrocatalytic performances for water splitting. However, the preparation of highly dispersed nanodots electrocatalysts remains a challenge. Herein, we...


2011 ◽  
Vol 131 (7) ◽  
pp. 235-239 ◽  
Author(s):  
Kaoru Yamashita ◽  
Tomoya Yoshizaki ◽  
Minoru Noda ◽  
Masanori Okuyama

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