On diffusion slip of a binary gas mixture

1974 ◽  
Vol 6 (4) ◽  
pp. 570-574 ◽  
Author(s):  
I. N. Ivchenko ◽  
Yu. I. Yalamov
Keyword(s):  
Gas Mixture ◽  
Binary Gas Mixture ◽  
Diffusion Slip

scholarly journals Influence of Casting Solvents on CO2/CH4 Separation Using Polysulfone Membranes

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 286
Author(s):  
Roba M. Almuhtaseb ◽  
Ahmed Awadallah-F ◽  
Shaheen A. Al-Muhtaseb ◽  
Majeda Khraisheh
Keyword(s):  
High Efficiency ◽  
In Situ Synthesis ◽  
Separation Process ◽  
Polymeric Membranes ◽  
Gas Mixture ◽  
Manufacturing Cost ◽  
Binary Gas Mixture ◽  
Maximum Permeability ◽  
Polysulfone Membranes

Polysulfone membranes exhibit resistance to high temperature with low manufacturing cost and high efficiency in the separation process. The composition of gases is an important step that estimates the efficiency of separation in membranes. As membrane types are currently becoming in demand for CO2/CH4 segregation, polysulfone will be an advantageous alternative to have in further studies. Therefore, research is undertaken in this study to evaluate two solvents: chloroform (CF) and tetrahydrofuran (THF). These solvents are tested for casting polymeric membranes from polysulfone (PSF) to separate every single component from a binary gas mixture of CO2/CH4. In addition, the effect of gas pressure was conducted from 1 to 10 bar on the behavior of the permeability and selectivity. The results refer to the fact that the maximum permeability of CO2 and CH4 for THF is 62.32 and 2.06 barrer at 1 and 2 bars, respectively. Further, the maximum permeability of CF is 57.59 and 2.12 barrer at 1 and 2 bars, respectively. The outcome selectivity values are 48 and 36 for THF and CF at 1 bar, accordingly. Furthermore, the study declares that with the increase in pressure, the permeability and selectivity values drop for CF and THF. The performance for polysulfone (PSF) membrane that is manufactured with THF is superior to that of CF relative to the Robeson upper bound. Therefore, through the results, it can be deduced that the solvent during in-situ synthesis has a significant influence on the gas separation of a binary mixture of CO2/CH4.

scholarly journals О бародиффузии при медленных течениях газовой смеси

2019 ◽  
Vol 89 (5) ◽  
pp. 646
Author(s):  
В.М. Жданов
Keyword(s):  
Equations Of Motion ◽  
Considerable Effect ◽  
Gas Mixture ◽  
Slip Coefficient ◽  
Knudsen Numbers ◽  
Slow Flows ◽  
Diffusion Slip ◽  
The Mean ◽  
The Individual ◽  
Small Knudsen Numbers

AbstractBarodiffusion in slow flows of a gas mixture is studied with an approximation using hydrodynamic equations of motion for the individual mixture components. It is shown that consideration of the viscous momentum transfer and the contribution of Knudsen layers for the mixture flowing in a channel has a considerable effect on the value of the barodiffusion factor. The relations are obtained for the mean diffusion fluxes of components and for the total flux of the mixture in a circular cylindrical capillary; these relations are valid for moderately small Knudsen numbers used for calculation of the diffusion baroeffect and separation effect when the gas mixture flows in a set of capillaries connecting two volumes. The modification of the relations for the barodiffusion factor (and for the diffusion slip coefficient cross-linked with it) allows interpreting the sign alteration of these effects observed experimentally for some gas mixtures at intermediate Knudsen numbers.

scholarly journals Simulation of a two-dimensional binary gas mixture outflow into vacuum through a thin slit on the basis of direct solution of the Boltzmann kinetic equation

2021 ◽  
Vol 2056 (1) ◽  
pp. 012007
Author(s):  
S S Sitnikov ◽  
F G Tcheremissine ◽  
T A Sazykina
Keyword(s):  
Kinetic Equation ◽  
Boltzmann Kinetic Equation ◽  
Gas Mixture ◽  
Two Dimensional ◽  
Direct Solution ◽  
Steady State Regime ◽  
Collision Integrals ◽  
Flow Formation ◽  
Binary Gas Mixture ◽  
State Regime

Abstract Two-dimensional binary gas mixture outflow from a vessel into vacuum through a thin slit is studied on the basis of direct solution of the Boltzmann kinetic equation. For evaluation of collision integrals in the Boltzmann equation a conservative projection method is used. Numerical simulation of a two-dimensional argon-neon gas mixture outflow from a vessel into vacuum was performed. Graphs of mixture components flow rate dependence on time during the flow formation, as well as fields of molecular density and temperature for steady-state regime, were obtained.

Analysis of slip and temperature jump coefficients in a binary gas mixture

1991 ◽  
Vol 25 (6) ◽  
pp. 937-944 ◽  
Author(s):  
I. V. Volkov ◽  
V. S. Galkin
Keyword(s):  
Temperature Jump ◽  
Gas Mixture ◽  
Binary Gas Mixture
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