Oxidation of formic acid at a high surface area supported platinum modified by foreign metal adatoms

1988 ◽  
Vol 18 (2) ◽  
pp. 240-244 ◽  
Author(s):  
LJ. V. Minevski ◽  
R. R. Adžić
Keyword(s):  
Formic Acid ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Supported Platinum

scholarly journals Enhancement of Photocatalytic Oxidation of Glucose to Value-Added Chemicals on TiO2 Photocatalysts by A Zeolite (Type Y) Support and Metal Loading

Catalysts ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 423 ◽  
Author(s):  
Kamonchanok Roongraung ◽  
Surawut Chuangchote ◽  
Navadol Laosiripojana
Keyword(s):  
Formic Acid ◽  
Surface Area ◽  
Gluconic Acid ◽  
Photocatalytic Oxidation ◽  
High Surface ◽  
Sol Gel ◽  
High Surface Area ◽  
Value Added ◽  
Incipient Wetness Impregnation ◽  
Microwave Assisted

TiO2-based photocatalysts synthesized by the microwave-assisted sol-gel method was tested in the photocatalytic glucose conversion. Modifications of TiO2 with type-Y zeolite (ZeY) and metals (Ag, Cu, and Ag-Cu) were developed for increasing the dispersion of TiO2 nanoparticles and increasing the photocatalytic activity. Effects of the TiO2 dosage to zeolite ratio (i.e., TiO2/ZeY of 10, 20, 40, and 50 mol %) and the silica to alumina ratio in ZeY (i.e., SiO2:Al2O3 of 10, 100, and 500) were firstly studied. It was found that the specific surface area of TiO2/ZeY was 400–590 m2g−1, which was higher than that of pristine TiO2 (34.38 m2g−1). The good properties of 20%TiO2/ZeY photocatalyst, including smaller particles (13.27 nm) and high surface area, could achieve the highest photocatalytic glucose conversion (75%). Yields of gluconic acid, arabinose, xylitol, and formic acid obtained from 20%TiO2/ZeY were 9%, 26%, 4%, and 35%, respectively. For the effect of the silica to alumina ratio, the highest glucose conversion was obtained from SiO2:Al2O3 ratio of 100. Interestingly, it was found that the SiO2:Al2O3 ratio affected the selectivity of carboxylic products (gluconic acid and formic acid). At a low ratio of silica to alumina (SiO2:Al2O3 = 10), higher selectivity of the carboxylic products (gluconic acid = 29% and formic acid = 32%) was obtained (compared with other higher ratios). TiO2/ZeY was further loaded by metals using the microwave-assisted incipient wetness impregnation technique. The highest glucose conversion of 96.9 % was obtained from 1 wt. % Ag-TiO2 (40%)/ZeY. Furthermore, the bimetallic Ag-Cu-loaded TiO2/ZeY presented the highest xylitol yield of 12.93%.

Rapid and Efficient Synthesis of Platinum Nanodendrites with High Surface Area by Chemical Reduction with Formic Acid

2010 ◽  
Vol 22 (9) ◽  
pp. 2835-2841 ◽  
Author(s):  
Liang Wang ◽  
Hongjing Wang ◽  
Yoshihiro Nemoto ◽  
Yusuke Yamauchi
Keyword(s):  
Formic Acid ◽  
Surface Area ◽  
Chemical Reduction ◽  
High Surface ◽  
High Surface Area ◽  
Efficient Synthesis

Synthesis Design of TiO2 Nanotubes and Nanowires and Photocatalytic Applications in the Degradation of Organic Pollutants in the Presence or not of Microorganisms

2012 ◽  
Vol 1442 ◽  
Author(s):  
Asma Turki ◽  
Pilar Fernández Ibáñez ◽  
Abdelhamid Ghorbel ◽  
Hafedh Kochkar ◽  
Chantal Guillard ◽  
...  
Keyword(s):  
Formic Acid ◽  
Surface Area ◽  
Tio2 Nanotubes ◽  
High Surface ◽  
High Surface Area ◽  
Alkaline Solutions ◽  
Synthesis Design ◽  
Desorption Isotherms ◽  
Adsorption Desorption ◽  
Photocatalytic Applications

ABSTRACT1 D TiO2 nanomaterials (nanotubes, nanowires) were synthesized through hydrothermal treatment of TiO2 powder (P25) in concentrated alkaline solutions (NaOH for nanotubes, KOH for nanowires) followed by calcination at varying temperatures between 400°C and 700°C. Samples were characterized by HRTEM, XRD, Raman spectroscopy, and N2 adsorption-desorption isotherms. High surface area nanotubular TiO2 materials can maintain their 1D morphology up to a temperature of calcination of 400°C while changing their phase from hydrogenotitanate to anatase. The use of KOH leads to a retarded formation of anatase. Photocatalytic results showed that TiO2 anatase nanotubes calcined at 400°C can degrade formic acid with a rate constant four times higher than for P25. A direct correlation between surface area and photocatalytic activity explains the much higher activity of TiO2 anatase nanotubes. On the opposite, for the degradation of phenol, P25 remains more active. In the disinfection of water, contrary to P25, the high surface area of TiO2 nanotubes allows the simultaneous degradation of formic acid and the inactivation of pathogen fungus showing the interest of such materials for the treatment of wastewater.

scholarly journals Surface Centres for CO Adsorption on Supported Platinum

2002 ◽  
Vol 20 (4) ◽  
pp. 347-351 ◽  
Author(s):  
Zenon Sarbak
Keyword(s):  
Surface Area ◽  
High Surface ◽  
Co Adsorption ◽  
High Surface Area ◽  
Supported Platinum ◽  
Platinum Dispersion

Adsorption centres of platinum supported on low- and high-surface area γ-Al2O3 (LSA and HAS, respectively), as well as on SiO2, are described. The interaction between platinum and CO was characterised and the platinum dispersion determined.

Tenacious Mass Transfer Limitations Drive Catalytic Selectivity during Electrochemical Carbon Dioxide Reduction

2019 ◽  
Author(s):  
Kailun Yang ◽  
Recep Kas ◽  
Wilson A. Smith
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Catalyst Layer ◽  
Active Surface ◽  
Active Surface Area ◽  
High Concentration ◽  
Copper Electrodes ◽  
Surface Enhanced ◽  
Local Current

<p>This study evaluated the performance of the commonly used strong buffer electrolytes, i.e. phosphate buffers, during CO<sub>2</sub> electroreduction in neutral pH conditions by using in-situ surface enhanced infrared absorption spectroscopy (SEIRAS). Unfortunately, the buffers break down a lot faster than anticipated which has serious implications on many studies in the literature such as selectivity and kinetic analysis of the electrocatalysts. Increasing electrolyte concentration, surprisingly, did not extend the potential window of the phosphate buffers due to dramatic increase in hydrogen evolution reaction. Even high concentration phosphate buffers (1 M) break down within the potentials (-1 V vs RHE) where hydrocarbons are formed on copper electrodes. We have extended the discussion to high surface area electrodes by evaluating electrodes composed of copper nanowires. We would like highlight that it is not possible to cope with high local current densities on these high surface area electrodes by using high buffer capacity solutions and the CO<sub>2</sub> electrocatalysts are needed to be evaluated by casting thin nanoparticle films onto inert substrates as commonly employed in fuel cell reactions and up to now scarcely employed in CO<sub>2</sub> electroreduction. In addition, we underscore that normalization of the electrocatalytic activity to the electrochemical active surface area is not the ultimate solution due to concentration gradient along the catalyst layer.This will “underestimate” the activity of high surface electrocatalyst and the degree of underestimation will depend on the thickness, porosity and morphology of the catalyst layer. </p> <p> </p>

scholarly journals Rugae-like FeP nanocrystal assembly on a carbon cloth: an exceptionally efficient and stable cathode for hydrogen evolution

Nanoscale ◽  
2015 ◽  
Vol 7 (25) ◽  
pp. 10974-10981 ◽  
Author(s):  
Xiulin Yang ◽  
Ang-Yu Lu ◽  
Yihan Zhu ◽  
Shixiong Min ◽  
Mohamed Nejib Hedhili ◽  
...  
Keyword(s):  
Gas Phase ◽  
Surface Area ◽  
Hydrogen Evolution ◽  
Hydrogen Generation ◽  
High Surface ◽  
High Surface Area ◽  
Catalytic Efficiency ◽  
Carbon Cloth ◽  
Nanocrystal Assembly

High surface area FeP nanosheets on a carbon cloth were prepared by gas phase phosphidation of electroplated FeOOH, which exhibit exceptionally high catalytic efficiency and stability for hydrogen generation.

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