Thermodynamic properties of water/organic systems with small contents of water 1. Limiting partial molal volumes of D2O and H2O in methanol and 2-propanol at various temperatures

1991 ◽  
Vol 40 (2) ◽  
pp. 263-265
Author(s):  
V. I. Grasin ◽  
V. K. Abrosimov
Keyword(s):  
Thermodynamic Properties ◽  
Organic Systems ◽  
Partial Molal Volumes ◽  
Molal Volumes

A note on the application of graph theory to the thermodynamic properties of isomeric alkanes

1980 ◽  
Vol 58 (18) ◽  
pp. 1897-1901 ◽  
Author(s):  
John T. Edward
Keyword(s):  
Graph Theory ◽  
Carbon Tetrachloride ◽  
Thermodynamic Properties ◽  
Mole Fraction ◽  
Methyl Groups ◽  
Partial Molal Volumes ◽  
Molal Volumes

It has been claimed that trends in the thermodynamic properties of alkane isomers follow an ordering based on p2 and p3, the number of paths of length two or three, respectively (M. Randic and C. L. Wilkins. J. Phys. Chem. 83, 1525 (1979)). A possible explanation of the approximate ordering of the partial molal volumes [Formula: see text] of isomers in carbon tetrachloride at 25 °C comes from the ordering, based on p2 and p3, of (a) the number N of methyl groups, and (b) the mole fraction Zg of gauche arrangements in the different isomers. However, N and Zg have opposite effects on [Formula: see text], and specific cases of isomeric heptanes and nonanes are noted in which a reversal in trends in [Formula: see text] may be expected.

Partial Molal Volumes of Aqueous Ions

1957 ◽  
Vol 61 (10) ◽  
pp. 1426-1429 ◽  
Author(s):  
Loren G. Hepler
Keyword(s):  
Partial Molal Volumes ◽  
Aqueous Ions ◽  
Molal Volumes

Partial molal volumes of ions

1970 ◽  
Vol 66 ◽  
pp. 43 ◽  
Author(s):  
G. Curthoys ◽  
J. G. Mathieson
Keyword(s):  
Partial Molal Volumes ◽  
Molal Volumes
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