Non-equilibrium, metasomatic18O/16O effects in upper mantle mineral assemblages

1986 ◽  
Vol 93 (1) ◽  
pp. 124-135 ◽  
Author(s):  
Robert T. Gregory ◽  
Hugh P. Taylor
Keyword(s):  
Upper Mantle ◽  
Mantle Mineral ◽  
Mineral Assemblages ◽  
Non Equilibrium

Iron oxidation state in lower mantle mineral assemblages

2004 ◽  
Vol 222 (2) ◽  
pp. 435-449 ◽  
Author(s):  
C.A. McCammon ◽  
S. Lauterbach ◽  
F. Seifert ◽  
F. Langenhorst ◽  
P.A. van Aken
Keyword(s):  
Oxidation State ◽  
Lower Mantle ◽  
Iron Oxidation ◽  
Iron Oxidation State ◽  
Mantle Mineral ◽  
Mineral Assemblages

scholarly journals The role of buoyancy in the fate of ultra-high-pressure eclogite

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Timothy Chapman ◽  
Geoffrey L. Clarke ◽  
Nathan R. Daczko
Keyword(s):  
High Pressure ◽  
Continental Crust ◽  
Upper Mantle ◽  
Crustal Rocks ◽  
Ultra High Pressure ◽  
Rock Types ◽  
Mineral Assemblages ◽  
Facies Metamorphism ◽  
Point Of No Return

AbstractEclogite facies metamorphism of the lithosphere forms dense mineral assemblages at high- (1.6–2.4 GPa) to ultra-high-pressure (>2.4–12 GPa: UHP) conditions that drive slab-pull forces during its subduction to lower mantle conditions. The relative densities of mantle and lithospheric components places theoretical limits for the re-exposure, and peak conditions expected, of subducted lithosphere. Exposed eclogite terranes dominated by rock denser than the upper mantle are problematic, as are interpretations of UHP conditions in buoyant rock types. Their subduction and exposure require processes that overcame predicted buoyancy forces. Phase equilibria modelling indicates that depths of 50–60 km (P = 1.4–1.8 GPa) and 85–160 km (P = 2.6–5 GPa) present thresholds for pull force in end-member oceanic and continental lithosphere, respectively. The point of no-return for subducted silicic crustal rocks is between 160 and 260 km (P = 5.5–9 GPa), limiting the likelihood of stishovite–wadeite–K-hollandite-bearing assemblages being preserved in equilibrated assemblages. The subduction of buoyant continental crust requires its anchoring to denser mafic and ultramafic lithosphere in ratios below 1:3 for the continental crust to reach depths of UHP conditions (85–160 km), and above 2:3 for it to reach extreme depths (>160 km). The buoyant escape of continental crust following its detachment from an anchored situation could carry minor proportions of other rocks that are denser than the upper mantle. However, instances of rocks returned from well-beyond these limits require exceptional exhumation dynamics, plausibly coupled with the effects of incomplete metamorphism to retain less dense low-P phases.

The redox state of the mantle during and just after core formation

2008 ◽  
Vol 366 (1883) ◽  
pp. 4315-4337 ◽  
Author(s):  
D.J Frost ◽  
U Mann ◽  
Y Asahara ◽  
D.C Rubie
Keyword(s):  
Oxygen Fugacity ◽  
Oxidation State ◽  
Upper Mantle ◽  
Partition Coefficients ◽  
Metal Loss ◽  
Core Formation ◽  
The Core ◽  
Mantle Mineral ◽  
Metal Silicate ◽  
Siderophile Elements

Siderophile elements are depleted in the Earth's mantle, relative to chondritic meteorites, as a result of equilibration with core-forming Fe-rich metal. Measurements of metal–silicate partition coefficients show that mantle depletions of slightly siderophile elements (e.g. Cr, V) must have occurred at more reducing conditions than those inferred from the current mantle FeO content. This implies that the oxidation state (i.e. FeO content) of the mantle increased with time as accretion proceeded. The oxygen fugacity of the present-day upper mantle is several orders of magnitude higher than the level imposed by equilibrium with core-forming Fe metal. This results from an increase in the Fe 2 O 3 content of the mantle that probably occurred in the first 1 Ga of the Earth's history. Here we explore fractionation mechanisms that could have caused mantle FeO and Fe 2 O 3 contents to increase while the oxidation state of accreting material remained constant (homogeneous accretion). Using measured metal–silicate partition coefficients for O and Si, we have modelled core–mantle equilibration in a magma ocean that became progressively deeper as accretion proceeded. The model indicates that the mantle would have become gradually oxidized as a result of Si entering the core. However, the increase in mantle FeO content and oxygen fugacity is limited by the fact that O also partitions into the core at high temperatures, which lowers the FeO content of the mantle. (Mg,Fe)(Al,Si)O 3 perovskite, the dominant lower mantle mineral, has a strong affinity for Fe 2 O 3 even in the presence of metallic Fe. As the upper mantle would have been poor in Fe 2 O 3 during core formation, FeO would have disproportionated to produce Fe 2 O 3 (in perovskite) and Fe metal. Loss of some disproportionated Fe metal to the core would have enriched the remaining mantle in Fe 2 O 3 and, if the entire mantle was then homogenized, the oxygen fugacity of the upper mantle would have been raised to its present-day level.

scholarly journals The emplacement of peridotites and associated oceanic rocks from the Lizard Complex, southwest England

2002 ◽  
Vol 139 (1) ◽  
pp. 27-45 ◽  
Author(s):  
C. A. COOK ◽  
R. E. HOLDSWORTH ◽  
M. T. STYLES
Keyword(s):  
Upper Mantle ◽  
Mantle Peridotite ◽  
Temperature Deformation ◽  
Crustal Rocks ◽  
Kinematic Indicators ◽  
Pull Apart Basin ◽  
Mantle Peridotites ◽  
Mineral Assemblages ◽  
Metamorphic Assemblage ◽  
Oceanic Rocks

Upper mantle peridotites and associated oceanic rocks from the Lizard Complex, southwest England, preserve evidence for a multistage geological history. Steeply dipping pre-emplacement fabrics record high-temperature (900–1100°C) shearing and exhumation of the mantle peridotites apparently formed during localized NE–SW rifting in a pull-apart basin setting (c. 400–390 Ma). Associated oceanic rocks (Landewednack amphibolites) preserve a pre-emplacement prograde brown amphibole-bearing metamorphic assemblage and steeply dipping fabric thought to have formed as the newly formed oceanic crust was juxtaposed with newly exhumed hot mantle peridotite during NE–SW rifting. In both the peridotites and Landewednack amphibolites, steep pre-emplacement structures are cross-cut by low-angle mylonitic fabrics thought to have formed during the initial phases of emplacement of mantle over crustal rocks in a partially intra-oceanic setting (c. 390–375 Ma). The fabrics in peridotites and amphibolites exhibit retrograde mineral assemblages (c. 500–800°C), with the amphibolites preserving two superimposed assemblages, green amphibole + titanite and colourless magnesio-hornblende, respectively, that are thought to record progressive down-temperature deformation during thrusting. Emplacement-related structures in both the basal peridotites and amphibolites consistently dip at low to moderate angles NW, with down-dip lineations and kinematic indicators showing consistent top-to-the-NW senses of shear. Syn-emplacement magmatism is recorded by intrusions of foliated Kennack Gneiss. Anastomosing serpentine-filled faults mark many existing low-angle contacts between the peridotites and Landewednack amphibolites and appear to represent the final, lowest-temperature (< 250°C) stages of emplacement (c. 370 Ma). This study shows that ‘dynamothermal aureoles’ in ophiolites may preserve evidence for tectonothermal events that pre-date thrust emplacement.

Sign in / Sign up

Export Citation Format

Share Document