Free radical formation in the hydroperoxide oxidation of carbonyl compounds

1989 ◽  
Vol 38 (12) ◽  
pp. 2620-2622
Author(s):  
V. G. Glukhovtsev ◽  
Yu. V. Il'in ◽  
G. I. Nikishin
Keyword(s):  
Free Radical ◽  
Carbonyl Compounds ◽  
Radical Formation ◽  
Free Radical Formation

STUDY ON THE SYNTHESIS OF AMINOALCOHOL VIA REACTION BETWEEN ALDEHYDE AND IMINE BY SAMARIUM (II) IODIDE CATALYST

2020 ◽  
pp. 101-106
Author(s):  
Thuong
Keyword(s):  
Free Radical ◽  
Carbonyl Compounds ◽  
Coupling Reaction ◽  
Radical Formation ◽  
Coupling Reactions ◽  
Pinacol Coupling ◽  
The Common ◽  
Free Radical Formation

Samarium (II) iodide (SmI2) has become one of the common, effective catalysts for coupling reactions between carbonyl compounds to form 1,2-diol by initiating free radical formation. In this paper, we present the results of studying the role of SmI2 catalyst on the aza-pinacol coupling reaction between aldehyde and imine under different mole ratios of SmI2, temperature and solvent conditions. The results showed that, in the THF solvent, at -78 °C, with 2.0 mole equivalent of the SmI2 catalyst, the reaction of pinacol coupling produces 1,2-aminoalcohols with efficiency of up to 91% yield and limited 1,2-diol by product.

In vivo thiyl free radical formation from hemoglobin following administration of hydroperoxides

1990 ◽  
Vol 277 (2) ◽  
pp. 402-409 ◽  
Author(s):  
Kirk R. Maples ◽  
Christopher H. Kennedy ◽  
Sandra J. Jordan ◽  
Ronald P. Mason
Keyword(s):  
Free Radical ◽  
Radical Formation ◽  
Free Radical Formation

scholarly journals Hydralazine-dependent carbon dioxide free radical formation by metabolizing mitochondria.

1988 ◽  
Vol 263 (23) ◽  
pp. 11296-11301 ◽  
Author(s):  
P K Wong ◽  
J L Poyer ◽  
C M DuBose ◽  
R A Floyd
Keyword(s):  
Carbon Dioxide ◽  
Free Radical ◽  
Radical Formation ◽  
Free Radical Formation

Biochemical Mechanisms for Oxygen Free Radical Formation During Exercise

1990 ◽  
Vol 10 (4) ◽  
pp. 236-254 ◽  
Author(s):  
Bertil Sjödin ◽  
Ylva Hellsten Westing ◽  
Fred S. Apple
Keyword(s):  
Free Radical ◽  
Oxygen Free Radical ◽  
Radical Formation ◽  
Biochemical Mechanisms ◽  
Free Radical Formation

Comparison between sonodynamic effect and photodynamic effect with photosensitizers on free radical formation and cell killing

2006 ◽  
Vol 13 (6) ◽  
pp. 535-542 ◽  
Author(s):  
Wakako Hiraoka ◽  
Hidemi Honda ◽  
Loreto B. Feril ◽  
Nobuki Kudo ◽  
Takashi Kondo
Keyword(s):  
Free Radical ◽  
Cell Killing ◽  
Radical Formation ◽  
Photodynamic Effect ◽  
Free Radical Formation
Sign in / Sign up

Export Citation Format

Share Document