New reaction pathways of organosilicon and organogermanium mercury derivatives with cyclopentadienyl and carbonyl complexes of iron, cobalt, and nickel

Author(s):  
E. N. Gladyshev ◽  
A. N. Tatarnikov ◽  
G. A. Abakumov
2021 ◽  
Author(s):  
Wenjing Yang ◽  
Yanhong Dong ◽  
Hongjian Sun ◽  
Xiaoyan Li

The synthesis and characterization of Fe, Co and Ni complexes supported by silylene ligands in recent ten years are summarized. Due to the decrease of electron cloud density on Si...


1969 ◽  
Vol 41 (3) ◽  
pp. 518-522 ◽  
Author(s):  
Jaroslav. Matousek ◽  
Vaclav. Sychra

RSC Advances ◽  
2015 ◽  
Vol 5 (45) ◽  
pp. 35558-35563 ◽  
Author(s):  
Zhong Zhang ◽  
Liang Pu ◽  
Qianshu Li ◽  
R. Bruce King

The Fe(CO)4(SiO), Co(CO)4(BO), and Co(CO)4(BNSiMe3), complexes akin to the well-known Fe(CO)5 are predicted by density functional theory to undergo exothermic oligomerization to give the oligomers containing SinOn/BnOn/B2N2 rings with single bonds.


1959 ◽  
Vol 37 (10) ◽  
pp. 1629-1636 ◽  
Author(s):  
J. R. MacEwan ◽  
J. U. MacEwan ◽  
L. Yaffe

The self-diffusion of nickel and the diffusion of Ni63 into iron, cobalt, and two iron–nickel alloys was studied using the technique of decrease in surface activity, The nickel self-diffusion results are compared to previously reported values. Nickel is found to diffuse more slowly than iron in the iron-rich portion of the iron–nickel system. The rate of nickel diffusion increases with increasing nickel content. A comparison is made between the present results for diffusion of Ni63 into iron, cobalt, and nickel with reported values for diffusion of Co60 and Fe59 in the same metals. In each solvent, the magnitudes of the activation energies, Q, are such that QNi > QCo > QFe.


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