Stable radicals ? The intermediates in the photochemical chlorination of unsaturated perfluoro compounds

1991 ◽  
Vol 40 (5) ◽  
pp. 1101-1104
Author(s):  
B. L. Tumanskii ◽  
E. G. Ter-Gabri�lyan ◽  
K. N. Makarov ◽  
S. P. Solodovnikov ◽  
N. N. Bubnov
Keyword(s):  
Photochemical Chlorination ◽  
Stable Radicals

scholarly journals sp2 Carbon Stable Radicals

2021 ◽  
Vol 7 (2) ◽  
pp. 31
Author(s):  
Elena F. Sheka
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Black ◽  
Intermolecular Interaction ◽  
Open Shell ◽  
Size And Shape ◽  
Spatially Extended ◽  
Stable Radicals ◽  
The Stability ◽  
Shungite Carbon ◽  
Technological Products

sp2 Nanocarbons such as fullerenes, carbon nanotubes, and graphene molecules are not only open-shell species, but spatially extended, due to which their chemistry is quite specific. Cogently revealed dependence of the final products composition on size and shape of the carbons in use as well as on the chemical prehistory is accumulated in a particular property—the stabilization of the species’ radical efficiency, thus providing the matter of stable radicals. If the feature is highly restricted and rarely available in ordinary chemistry, in the case of sp2 nanocarbons it is just an ordinary event providing, say, tons-in-mass stable radicals when either producing such widely used technological products as carbon black or dealing with deposits of natural sp2 carbons such as anthracite, shungite carbon, and other. Suggested in the paper is the consideration of stable radicals of sp2 nanocarbons from the standpoint of spin-delocalized topochemistry. Characterized in terms of the total and atomically partitioned number of effectively unpaired electrons as well as of the distribution of the latter over carbon atoms and described by selectively determined barriers of different reactions exhibiting topological essence of intermolecular interaction, sp2 nanocarbons reveal a peculiar topokinetics that lays the foundation of the stability of their radical properties.

scholarly journals Engineering stable radicals using photochromic triggers

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Xuanying Chen ◽  
Wandong Zhao ◽  
Gleb Baryshnikov ◽  
Michael L. Steigerwald ◽  
Jian Gu ◽  
...  
Keyword(s):  
Stable Radicals

Designing Stable Radicals with Highly Electrophilic or Nucleophilic Character: Thiadiazinyl as a Case Study

2014 ◽  
Vol 2015 (3) ◽  
pp. 506-513 ◽  
Author(s):  
Freija De Vleeschouwer ◽  
Artiom Chankisjijev ◽  
Paul Geerlings ◽  
Frank De Proft
Keyword(s):  
Stable Radicals

scholarly journals Hereditariness of strong and stable radicals

1982 ◽  
Vol 23 (1) ◽  
pp. 85-90 ◽  
Author(s):  
E. R. Puczyłowski
Keyword(s):  
Stable Radicals

The aim of this paper is to discuss some relations among hereditary, strong and stable radicals. In particular we investigate hereditariness of lower strong and stable radicals. Some facts obtained are related to some results and questions of [2, 6, 7].All rings in the paper are associative. Fundamental definitions and properties of radicals may be found in [9]. Definitions of hereditary and strong radicals are used as in Sands [7]. We say that a radical S is left (right) stable if(ρ): for every ring R and every left (right) ideal I of R it follows S(I)⊆S(R).

Photochemical chlorination of alkanoic acids anchored to a polymeric support

Tetrahedron ◽  
1978 ◽  
Vol 34 (7) ◽  
pp. 947-950 ◽  
Author(s):  
P. Bosch ◽  
J. Font ◽  
A. Moral ◽  
F. Sánchez-Ferrando
Keyword(s):  
Polymeric Support ◽  
Alkanoic Acids ◽  
Photochemical Chlorination
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