Catalytic reactions of C3-cyclic olefins in the presence of metal complexes. 4. Ni complexes as catalysts for the [2+2]-cyclodimerization of spiro[2,3]hex-1-ene

1990 ◽  
Vol 39 (2) ◽  
pp. 287-290 ◽  
Author(s):  
D. B. Furman ◽  
T. Yu. Rudashevskaya ◽  
A. V. Kudryashev ◽  
A. O. Ivanov ◽  
L. S. Isaeva ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Catalytic Reactions ◽  
Cyclic Olefins

The role of organotransition metal complexes in some catalytic reactions

1968 ◽  
pp. 233-249
Author(s):  
G. E. Coates ◽  
M. L. H. Green ◽  
P. Powell ◽  
K. Wade
Keyword(s):  
Metal Complexes ◽  
Catalytic Reactions

Activation and Catalytic Reactions of Alkanes in Solutions of Metal Complexes

1987 ◽  
Vol 56 (5) ◽  
pp. 442-464 ◽  
Author(s):  
Aleksandr E Shilov ◽  
Georgiy B Shul'pin
Keyword(s):  
Metal Complexes ◽  
Catalytic Reactions

Research inspired by the chemistry of nitrogenase — Novel metal complexes and their reactivity toward dinitrogen, nitriles, and alkynes

2005 ◽  
Vol 83 (4) ◽  
pp. 358-374 ◽  
Author(s):  
Masanobu Hidai ◽  
Yasushi Mizobe
Keyword(s):  
Nitrogen Fixation ◽  
Metal Complexes ◽  
Active Site ◽  
Bond Cleavage ◽  
Catalytic Reactions ◽  
Tertiary Phosphine ◽  
Tertiary Phosphines ◽  
Dinitrogen Complexes ◽  
And Tungsten

Summarized here are our continuous studies of the last three decades concerning syntheses of new types of complexes learned from nitrogenase and their reactivites toward dinitrogen, nitriles, and alkynes. For Mo and W dinitrogen complexes with tertiary phosphine coligands, a variety of their intriguing reactivities have been demonstrated, and novel transformations of the N2 ligands into numerous nitrogen-containing ligands and compounds have been developed. The C≡N bond cleavage of certain nitriles also proceeds on the Mo site surrounded by tertiary phosphines. Stimulated by the sophisticated structure of the active site of nitrogenase, multinuclear metal–sulfur complexes have been synthesized in rational ways. New types of stoichiometric and catalytic reactions of alkynes have been found by using the thiolato-bridged diruthenium complexes and some cubane-type sulfido clusters containing a noble metal.Key words: nitrogen fixation, molybdenum and tungsten dinitrogen complexes, ruthenium thiolato complexes, metal sulfido clusters, nitriles, alkynes.

Metal–Organic Frameworks Stabilize Mono(phosphine)–Metal Complexes for Broad-Scope Catalytic Reactions

2016 ◽  
Vol 138 (31) ◽  
pp. 9783-9786 ◽  
Author(s):  
Takahiro Sawano ◽  
Zekai Lin ◽  
Dean Boures ◽  
Bing An ◽  
Cheng Wang ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Metal Organic Frameworks ◽  
Catalytic Reactions ◽  
Broad Scope ◽  
Metal Organic
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