Study of intermolecular interactions in an equilibrium system in the catalytic transesterification of esters 3. Interaction of tetrabutyl titanate with alcohols from ir and NMR spectroscopic data

1991 ◽  
Vol 40 (9) ◽  
pp. 1767-1773
Author(s):  
L. I. Komarova ◽  
N. N. Lapina ◽  
B. V. Lokshin ◽  
V. I. Bakhmutov ◽  
G. D. Markova ◽  
...  
Keyword(s):  
Intermolecular Interactions ◽  
Spectroscopic Data ◽  
Tetrabutyl Titanate ◽  
Equilibrium System

Diphenyl(2-hydroxy-phenyl)phosphine and its Trimethylsilyl Ether as Ligands for Gold(I) Complexes

1999 ◽  
Vol 54 (1) ◽  
pp. 30-37 ◽  
Author(s):  
Christian Hollatz ◽  
Annette Schier ◽  
Hubert Schmidbaur
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Crystal Structures ◽  
Intermolecular Interactions ◽  
Spectroscopic Data ◽  
Trimethylsilyl Ether ◽  
Chloro Complex

Diphenyl(2-hydroxy-phenyl)phosphine was introduced as a ligand for gold(I) halides and pentafluorophenyl gold(I) in order to probe the interplay of intra- and intermolecular interactions based on aurophilic (Au· · ·Au) and hydrogen bonding. 1:1 complexes of the type Ph2(2-HO-C6H4)P-Au-X with X = Cl, Br, C6F5 have been prepared and characterized by analytical and spectroscopic data. The crystal structure of the chloro complex (1) has been determined. In the lattice the molecules form dimers through O-H· · ·Cl hydrogen bonds. Au· · ·Au contacts are ruled out by steric congestion. Reaction of 1 with triethylamine yields a 1:1 adduct with O-H· · ·NEt3 hydrogen bonding. The trimethylsilyl ether of the title ligand also forms 1:1 complexes with AuCl, AuBr, Aul, and AuC6F5. The crystal structures of the chloro (5) and iodo (7) compound have been determined. In both cases the lattices are built from monomers which show only minor differences in their conformations. The silylether groups are not acting as intra- or intermolecular donor functions to the gold atoms.

Models of Cataclysmic Variables from Photometric and Spectroscopic Data

1979 ◽  
Vol 46 ◽  
pp. 65-74 ◽  
Author(s):  
A.C. Fabian ◽  
J.E. Pringle ◽  
J.A.J. Whelan ◽  
J.A. Bailey
Keyword(s):  
Spectroscopic Data ◽  
Cataclysmic Variables ◽  
System Parameters ◽  
Dwarf Nova ◽  
Spectroscopic Observations ◽  
Photometric And Spectroscopic Observations

Abstract.Recent photometric and spectroscopic observations of the dwarf nova system Z Cha are discussed. Methods for constraining the system parameters are applied and the disc emissivity is deduced as a function of radius. Indications are found that the disc shrinks in size with increasing time after outburst.

Millimetre-wave and infrared spectroscopy of Br13 CN: anharmonic force field of cyanogen bromide from spectroscopic data and ab initio calculations

1997 ◽  
Vol 90 (3) ◽  
pp. 495-497
Author(s):  
CLAUDIO ESPOSTI ◽  
FILIPPO TAMASSIA ◽  
CRISTINA PUZZARINI ◽  
RICCARDO TARRONI ◽  
ZDENEK ZELINGER
Keyword(s):  
Infrared Spectroscopy ◽  
Force Field ◽  
Ab Initio Calculations ◽  
Ab Initio ◽  
Spectroscopic Data ◽  
Cyanogen Bromide ◽  
Millimetre Wave ◽  
Anharmonic Force

KINEMATIC FEATURES OF THE LAPPING PROCESS AND DETERMINATION OF ITS BASIC PARAMETERS

2020 ◽  
Vol 7 (3) ◽  
pp. 23-28
Author(s):  
EZIZ SARVAN SHIRVAN ◽  
Keyword(s):  
Dynamic Properties ◽  
Cutting Speed ◽  
Equilibrium System ◽  
Technological Parameters ◽  
Kinematic Characteristics ◽  
Angular Velocities ◽  
Basic Parameters ◽  
Grinding Tool ◽  
Mathematical Relationships ◽  
Analytical Expressions

This paper discusses the kinematic characteristics of lapping process and the main parameters of the process. It was determined that the influencing degree of technological parameters to the forming surface and processes. It was projected the construction of the lapping head for processing of internal cylindrical surfaces, scheme of the lapping operation and graphic description of the forces influencing. The relationships between the axial, radial and tangential cutting forces and the effect of the combined force thereof are determined in order to ensure the necessary surface pressure. During the analysis geometric and mathematical relationships were obtained. The extracted analytical expressions can be realized by further experimental researches and can be used in engineering calculations of technological parameters of processing by lapping. Angular velocity, friction force, linear velocity, also the length of the tactile curve and the radius of the part can be considered the main kinematic and dynamic parameters of the process that the formation of the surface, also the course of the process depends on these parameters. Depending on the kinematic parameters, the wear nature of the tool changes and this changes the linear and angular velocities, which have a significant impact on the accuracy, quality and productivity of processing. When examining the technological capabilities of the process, the nature of the movement between the part and the grinding tool, also changes in cutting speed are often considered as a main factor. Analytical expressions were obtained to determine the main parameters of the process, taking into account the kinematic characteristics of the friction process. These expressions can be used in engineering calculations and allow to determine the optimal values of the processing mode. In order to obtain the required micrometric surface cleanliness and measurement accuracy, correlation relationships were established between the main parameters of the process, equations of the equilibrium system of shear forces were compiled and analytical expressions were obtained based on the analysis of kinematic and dynamic properties of the system.

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