Enantioselective catalysis by metal complexes. 5. Asymmetric hydrosilylation using the phosphine complex [Rh(COD)Cl]2/(S)-Phephos

1990 ◽  
Vol 39 (9) ◽  
pp. 1771-1774
Author(s):  
E. Yu. Zhorov ◽  
V. A. Pavlov ◽  
Yu. D. Koreshkov ◽  
E. I. Klabunovskii
Keyword(s):  
Metal Complexes ◽  
Enantioselective Catalysis ◽  
Phosphine Complex

Bioinspired enantioselective catalysis: Racemic or achiral metal complexes grafted on mesoporous material functionalized with chiral molecules

2007 ◽  
Vol 8 (3) ◽  
pp. 215-219 ◽  
Author(s):  
Guillaume Cortial ◽  
Frédéric Goettmann ◽  
François Mercier ◽  
Pascal Le Floch ◽  
Clément Sanchez
Keyword(s):  
Metal Complexes ◽  
Mesoporous Material ◽  
Enantioselective Catalysis ◽  
Chiral Molecules

scholarly journals The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis

2019 ◽  
Vol 10 (33) ◽  
pp. 7807-7811 ◽  
Author(s):  
Delphine Pichon ◽  
Michele Soleilhavoup ◽  
Jennifer Morvan ◽  
Glen P. Junor ◽  
Thomas Vives ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Enantioselective Catalysis ◽  
Carbene Ligands ◽  
Asymmetric Transformations

Cyclic (alkyl)(amino)carbene (CAAC) metal complexes can also engage in asymmetric transformations, thereby expanding the toolbox of available chiral carbene ligands.

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