Nitration of aromatic compounds by nitric acid supported on zeolite

Author(s):  
Sh. M. Nagi ◽  
�. A. Zubkov ◽  
V. G. Shubin
1972 ◽  
Vol 50 (20) ◽  
pp. 3367-3372 ◽  
Author(s):  
A. Fischer ◽  
D. R. A. Leonard

Reaction of 3-oxo-1,2,3,7,8,9,10,10a-octahydrocyclohepta[de]naphthalene with nitric acid in acetic anhydride gives two stereoisomeric 4-acetoxy-6a-nitro-3-oxo-1,2,3,4,6a,7,8,9,10,10a-decahydrocyclohepta[de]-naphthalenes as well as the expected nitro substitution products. Formation of these adducts from a substrate containing a meta-directing deactivating substituent shows that the 1,4-addition reaction of acetyl nitrate is more general than previously suspected. 1,4-Acetyl nitrate adducts are also formed from tetralin, benzsuberane, 5,6,7,8-tetrahydrocyclohepta[fg]acenaphthene, and 1,2,3,4,7,8,9,10-octahydrodicyclohepta[de,ij]naphthalene. Decomposition of the last two adducts gives in each case a product with the nitro group substituted into the alicyclic ring.


ChemInform ◽  
2010 ◽  
Vol 32 (43) ◽  
pp. no-no
Author(s):  
Tasneem Tasneem ◽  
M. M. Ali ◽  
K. C. Rajanna ◽  
P. K. Saiparakash

2004 ◽  
Vol 8 (4) ◽  
pp. 568-570 ◽  
Author(s):  
Ashutosh V. Joshi ◽  
Mubeen Baidossi ◽  
Sudip Mukhopadhyay ◽  
Yoel Sasson

2010 ◽  
Vol 28 (3) ◽  
pp. 397-403 ◽  
Author(s):  
Roozbeh Javad Kalbasi ◽  
Ahmad Reza Massah ◽  
Farzad Zamani ◽  
Hamid Javaherian Naghash

1980 ◽  
Vol 11 (37) ◽  
Author(s):  
A. G. MORKOVNIK ◽  
N. M. DOBAEVA ◽  
V. B. PANOV ◽  
O. YU. OKHLOBYSTIN

Sign in / Sign up

Export Citation Format

Share Document