New skeletal regrouping in an aromatizing metallation reaction

1982 ◽  
Vol 31 (8) ◽  
pp. 1707-1707 ◽  
Author(s):  
V. I. Rozenberg ◽  
G. V. Gavrilova ◽  
B. I. Ginzburg ◽  
V. A. Nikanorov ◽  
O. A. Reutov
Keyword(s):  
Metallation Reaction

A new aromatic metallation reaction involving rhodium and iridium; the unusual reactivity of iodobenzene

1985 ◽  
Vol 279 (1-2) ◽  
pp. 115-130 ◽  
Author(s):  
Manuel Gómez ◽  
Paul I.W. Yarrow ◽  
David J. Robinson ◽  
Peter M. Maitlis
Keyword(s):  
Metallation Reaction

Selective ortho-metallation reaction of the phosphine P(o-ClC6H4)Ph2. Synthesis and crystal structure of [Rh2(μ-O2CCH3)3(μ-(ClC6H3)PPh2(OH2)2]·CHCl3

1993 ◽  
Vol 443 (1) ◽  
pp. C14-C15 ◽  
Author(s):  
Pascual Lahuerta ◽  
Jorge Payá ◽  
Santiago García-Granda ◽  
Fermín Gómez-Beltrán ◽  
Adela Anillo
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure ◽  
Metallation Reaction

Metallation reactions. XXV. A re-examination of the metallation reaction of (alkylthio)fluorobenzenes

1999 ◽  
Vol 98 (2) ◽  
pp. 97-106 ◽  
Author(s):  
M.G. Cabiddu ◽  
S. Cabiddu ◽  
E. Cadoni ◽  
C. Fattuoni ◽  
S. Melis
Keyword(s):  
Metallation Reaction

A novel metallation reaction of N-lithio-t-butylaminotrimethylsilane

1967 ◽  
pp. 1270a ◽  
Author(s):  
R. P. Bush ◽  
N. C. Lloyd ◽  
C. A. Pearce
Keyword(s):  
Metallation Reaction

Coordination and Reactions of Diazenes in Trimethylphosphinecobalt(I). Complexes - Syntheses and Structures of Complexes Containing μ2-(N,N′)-Benzo[c]cinnoline and η2-Azobenzene Ligands

1993 ◽  
Vol 48 (6) ◽  
pp. 778-784 ◽  
Author(s):  
Hans-Friedrich Klein ◽  
Michael Helwig ◽  
Udo Koch ◽  
Ulrich Flörke ◽  
Hans-Jürgen Haupt
Keyword(s):  
Crystal Structure ◽  
Coordination Mode ◽  
X Ray ◽  
Structure Determinations ◽  
Metallation Reaction ◽  
Mononuclear Compounds

Mononuclear compounds CpCo(η2-azobenzene)(PMe3) (1) or ortho-metallated (2) are obtained from azobenzene and CpCo(PMe3)2 or CoMe(PMe3)4, respectively. With 4-acetoxo-azobenzene the ortho-metallation reaction gives isomers , (3A) and (3B) in a 1:1 ratio. Carbonylation of 2 gives (4). Benzo[c]cinnoline affords CoCH3(η2-C12H8N2)(PMe3)3 (5) and μ2-(N ,N′)-C12H8N2(CoCp)[CoCp(PMe3)] (6). The coordination mode of the diazene ligands in 1 and 6 has been shown by X-ray crystal structure determinations. Dynamic N M R spectroscopy indicates intramolecular hopping of trimethylphosphine across the CoCo bond in 6.

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