Catalytic properties of variable-valence metal oxides in the oxidative dehydration of ethylbenzene

Author(s):  
I. P. Belomestnykh ◽  
G. V. Shakhnovich ◽  
N. N. Rozhdestvenskaya ◽  
G. V. Isagulyants
ChemInform ◽  
1987 ◽  
Vol 18 (50) ◽  
Author(s):  
I. P. BELOMESTNYKH ◽  
G. V. SHAKHNOVICH ◽  
N. N. ROZHDESTVENSKAYA ◽  
G. V. ISAGULYANTS

1974 ◽  
Author(s):  
R. G. Squires ◽  
L. F. Albright ◽  
W. N. Delgass ◽  
R. A. Walton ◽  
N. Winograd

1967 ◽  
Vol 7 (1) ◽  
pp. 23-32 ◽  
Author(s):  
Yoshihiko Moro-Oka ◽  
Yutaka Morikawa ◽  
Atsumu Ozaki

2008 ◽  
Vol 8 (11) ◽  
pp. 5652-5658 ◽  
Author(s):  
Yangang Wang ◽  
Yanqin Wang ◽  
Xiaohui Liu ◽  
Yun Guo ◽  
Yanglong Guo ◽  
...  

Mesoporous metal oxides and mixed oxides, such as NiO, CeO2, Cr2O3, Fe2O3, Mn2O3, NiFe2O4 and CexZr1−xO2 (x = 0.8 and 0.6) have been synthesized by nanocasting from mesoporous cubic (Ia3d) vinyl-functionalized silica (vinylsilica). Their structural properties were characterized by XRD, TEM, N2-sorption and Raman spectra. Thus-prepared mesoporous materials possess a high BET surface area (110–190 m2g−1), high pore volume (0.25–0.40 cm3g−1) and relatively ordered structures. The catalytic properties of Cr2O3 were tested in the oxidation of toluene. The mesoporous Cr2O3 exhibits unusually high catalytic activity in the complete oxidation of toluene as compared with commercial Cr2O3.


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