Telomerization of 1-hexene with methyl chloroacetate and methyl propionate

Author(s):  
A. B. Terent'ev ◽  
N. S. Ikonnikov ◽  
V. I. Dostovalova
1979 ◽  
Vol 57 (4) ◽  
pp. 400-403 ◽  
Author(s):  
Anne Le Narvor ◽  
Pierre Saumagne

The ir spectra of mixtures of methyl propionate/water and methyl propionate/Ba2+ in dimethylsulfoxide and in acetonitrile have been recorded in the region of the νCO mode of the ester. Evidence is presented to indicate the presence of different types of complexes; their concentration was determined as a function of the composition of the medium. The spectroscopic results are compared to those from the kinetics of the alkaline hydrolysis in the same conditions. It is demonstrated that the orbital control explains the experimental results better than does the charge density on the carbon of the carbonyl group. [Journal translation]


1971 ◽  
Vol 49 (19) ◽  
pp. 3152-3157 ◽  
Author(s):  
A. W. Mcculloch ◽  
A. G. McInnes

The AlCl3-promoted reactions of 2-methyl- and of 2-phenylfuran with ethyl propiolate afford as major products ethyl 5-hydroxy-2-methyl- and 2-phenylbenzoates (6a, 6b). Also isolated as minor by-products of these reactions are ethyl 3-(2-furyl-5-methyl)acrylate (5a), ethyl 3-(2-furyl-5-phenyl)acrylate (5b), ethyl 3,3-di(2-furyl-5-methyl)propionate (10a), ethyl 3,3-di(2-furyl-5-phenyl)propionate (10b), and ethyl 2-hydroxy-5-methylbenzoate (8a).


Weed Science ◽  
1977 ◽  
Vol 25 (5) ◽  
pp. 382-385 ◽  
Author(s):  
B.G. Todd ◽  
E.H. Stobbe

The selectivity of {2-[4-(2′,4′-dichlorophenoxy) phenoxy] methyl propionate}, (hereinafter referred to as dichlofop methyl), among wheat (Triticum aestivumL. ‘Neepawa’), barley (Hordeum vulgareL. ‘Bonanza’), wild oat (Avena fatuaL.), and green foxtail (Setaria viridis(L.) Beauv.) was investigated. On an ED50basis, barley, wild oat, and green foxtail were 2, 190, and 1,090 times more sensitive, respectively, to foliar-applied dichlofop methyl at the two-leaf stage than was wheat. Selectivity decreased with increasing maturity of the plant material with the ratio of selectivity between barley and wild oat decreasing from 55 at the two-leaf stage to three at the four-leaf-plus-one-tiller stage. Greater spray retention and more rapid penetration of dichlofop methyl partially explained the susceptibility of green foxtail, but did not explain selectivity between wheat, wild oat, and barley. Root uptake of14C-dichlofop methyl by the four species was proportional to the amount of solution absorbed during the treatment period and to the concentration of dichlofop methyl in the treatment solution but was not related to species sensitivity to this herbicide.


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