Catalytic activity of palladium complexes supported on silica gels modified by tertiary amines and quaternary ammonium bases in hydrogenation reactions

Author(s):  
V. Z. Sharf ◽  
M. A. Nesterov ◽  
L. P. Finn ◽  
I. B. Slinyakova
Catalysts ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 656
Author(s):  
Henrietta Kovács ◽  
Krisztina Orosz ◽  
Gábor Papp ◽  
Ferenc Joó ◽  
Henrietta Horváth

Na2[Ir(cod)(emim)(mtppts)] (1) with high catalytic activity in various organic- and aqueous-phase hydrogenation reactions was immobilized on several types of commercially available ion-exchange supports. The resulting heterogeneous catalyst was investigated in batch reactions and in an H-Cube flow reactor in the hydrogenation of phenylacetylene, diphenylacetylene, 1-hexyne, and benzylideneacetone. Under proper conditions, the catalyst was highly selective in the hydrogenation of alkynes to alkenes, and demonstrated excellent selectivity in C=C over C=O hydrogenation; furthermore, it displayed remarkable stability. Activity of 1 in hydrogenation of levulinic acid to γ-valerolactone was also assessed.


1928 ◽  
Vol 50 (11) ◽  
pp. 2872-2878 ◽  
Author(s):  
L. H. Reyerson ◽  
L. E. Swearingen

2016 ◽  
Vol 818 ◽  
pp. 179-184 ◽  
Author(s):  
Liangru Yang ◽  
Xinchi Zhang ◽  
Jinwei Yuan ◽  
Yongmei Xiao ◽  
Pu Mao

Nature ◽  
1972 ◽  
Vol 236 (5345) ◽  
pp. 307-307 ◽  
Author(s):  
WALTER FIDDLER ◽  
JOHN W. PENSABENE ◽  
ROBERT C. DOERR ◽  
AARON E. WASSERMAN

1928 ◽  
Vol 32 (1) ◽  
pp. 113-120 ◽  
Author(s):  
L. E. Swearingen ◽  
L. H. Reyerson

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