Stereochemistry of the horner-emmons reaction of 3-functionalized 2-methyl-2-propenylphosphonates with aliphatic aldehydes. 2. Effect of size of the functional substituent in the phosphonate

Author(s):  
G. V. Kryshtal' ◽  
�. P. Serebryakov ◽  
L. M. Suslova ◽  
L. A. Yanovskaya
2014 ◽  
Vol 18 (9) ◽  
pp. 1218-1224 ◽  
Author(s):  
Tomasz Bauer ◽  
Maciej Majdecki ◽  
Slawomir Smolinskia ◽  
Janusz Jurczak
Keyword(s):  

1988 ◽  
Vol 25-26 ◽  
pp. 335-338
Author(s):  
Wilhelm Knoche ◽  
Victoria R. Hanke ◽  
Edward Dutkiewicz

1999 ◽  
Vol 23 (3) ◽  
pp. 176-177
Author(s):  
Garima Goswami ◽  
Seema Kothari ◽  
Kalyan K. Banerji

The oxidation of aliphatic aldehydes by benzyltrimethylammonium tribromide involves the formation of an intermediate complex and its subsequent decomposition in the rate-determining step to the corresponding carboxylic acid.


2016 ◽  
Vol 138 (39) ◽  
pp. 12775-12778 ◽  
Author(s):  
Ke Yang ◽  
Qun Li ◽  
Yongbing Liu ◽  
Guigen Li ◽  
Haibo Ge
Keyword(s):  

1957 ◽  
Vol 29 (11) ◽  
pp. 1676-1678 ◽  
Author(s):  
L. D. Metcalfe ◽  
A. A. Schmitz

1966 ◽  
Vol 44 (1) ◽  
pp. 45-51 ◽  
Author(s):  
R. E. Klinck ◽  
J. B. Stothers

The effects of structure on the shielding of formyl protons of aliphatic aldehydes have been examined. The survey included examples of acyclic, alicyclic, and α, β-unsaturated aldehydes. The potential use of these results as an aid for structural elucidations is discussed, and the limitations are noted.


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