Ion pairs in radical anions with six-coordinated silicon atoms

Author(s):  
A. I. Prokof'ev ◽  
T. I. Prokof'eva ◽  
N. N. Bubnov ◽  
S. P. Solodovnikov ◽  
I. S. Belostotskaya ◽  
...  
Keyword(s):  
2009 ◽  
Vol 113 (17) ◽  
pp. 7436-7442 ◽  
Author(s):  
Jan S. Jaworski ◽  
Agnieszka Kosson ◽  
Sławomir Filipek ◽  
Dietmar Kuck

1988 ◽  
Vol 43 (10) ◽  
pp. 1240-1246 ◽  
Author(s):  
Hans Bock ◽  
Peter Hänel ◽  
H.-F Herrmann ◽  
Heindirk torn Dieck

The structurally different radical anions M⊖ of peralkylated 1-sila-2,5-diazacyclopentane-3,4-dithione and of tetrakis(isopropylthio)-p-benzoquinone are generated by reduction with potassium/2.2.2-cryptand under aprotic conditions in THF solution. On addition of Li⊕B(C6H5)4⊖, both form hitherto elusive sulfur-containing contact ion pairs, which are characterized by their ESR/ENDOR spectra.


1998 ◽  
Vol 295 (3) ◽  
pp. 230-236 ◽  
Author(s):  
V.A Bagryansky ◽  
V.I Borovkov ◽  
Yu.N Molin ◽  
M.P Egorov ◽  
O.M Nefedov

1980 ◽  
Vol 45 (2) ◽  
pp. 351-359 ◽  
Author(s):  
Stanislav Miertuš ◽  
Ondrej Kyseľ ◽  
Pavol Mach

Some radical anions (glyoxal, fluorenone and nitrobenzene) were investigated by the modified LHP method. The calculated effects of cations (in ion pairs) and the effect of the polarity of the medium on energy ratios, conformation, hyperfine splitting constants and electronic spectra in the systems agree well with the available experimental data. It seems that the proposed modified LHP method can be useful in the study of ion-radical systems derived from larger conjugated molecules.


1976 ◽  
Vol 74 (2) ◽  
pp. 235-238 ◽  
Author(s):  
Jerzy Chodkowski ◽  
Andrzej Chrzanowski ◽  
Marek K. Kalinowski

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