The role of the reactor surface in the liquid-phase oxidation of hexafluoropropylene

Author(s):  
S. V. Kartsov ◽  
P. I. Valov ◽  
L. F. Sokolov ◽  
S. V. Sokolov
1998 ◽  
Vol 94 (12) ◽  
pp. 1761-1764 ◽  
Author(s):  
Inès Belkhir ◽  
Alain Germain ◽  
François Fajula ◽  
Eric Fache

2013 ◽  
Vol 53 (3) ◽  
pp. 171-176 ◽  
Author(s):  
V. N. Sapunov ◽  
G. N. Koshel’ ◽  
Yu. B. Rumyantseva ◽  
E. A. Kurganova ◽  
N. D. Kukushkina

1986 ◽  
Vol 51 (11) ◽  
pp. 2574-2581 ◽  
Author(s):  
Gabriela Valehrachová ◽  
Milan Hronec ◽  
Václav Veselý

Liquid phase oxidation of mesitylene to 3,5-dimethylbenzaldehyde has been studied in the presence of cobalt bromide catalysts activated with triethanolamine or pyridine. The selectivity for the aldehyde is affected by the presence of the amine, by solvent, and only little by concentration of the catalyst and its components. The lower value of rate constant of the subsequent oxidation of the aldehyde, k2 = (7.66 ± 0.39) . 10-5 s-1, as compared with that of the oxidation of mesitylene, k1 = (1.66 ± 0.13) . 10-4 s-1 at 60 °C, indicates an important role of the cooxidation reactions in the process of oxidation of mesitylene, which affects the reaction selectivity.


2004 ◽  
Vol 224 (2) ◽  
pp. 314-325 ◽  
Author(s):  
B Kilos ◽  
M Aouine ◽  
I Nowak ◽  
M Ziolek ◽  
J.C Volta

1993 ◽  
Vol 142 (1) ◽  
pp. 237-253 ◽  
Author(s):  
T. Mallat ◽  
Z. Bodnar ◽  
A. Baiker ◽  
O. Greis ◽  
H. Strubig ◽  
...  

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